Enhanced magnetic susceptibility in Ti 3 C 2 T x MXene with Co and Ni incorporation

Yang, Yizhou; Anayee, Mark; Pattammattel, Ajith; Shekhirev, Mikhail; Wang, Ruocun (John); Huang, Xiaojing; Chu, Yong S.; Gogotsi, Yury; May, Steven J.

doi:10.1039/D3NR05685F

Title: Enhanced magnetic susceptibility in Ti ₃ C ₂ T _x MXene with Co and Ni incorporation

Journal Article · Thu Mar 14 00:00:00 EDT 2024 · Nanoscale

DOI:https://doi.org/10.1039/D3NR05685F· OSTI ID:2315070

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Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania 19014, USA
Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania 19014, USA, A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, Pennsylvania 19104, USA
Brookhaven National Laboratory, National Synchrotron Light Source II, Upton, New York, 11973, USA

Magnetic nanomaterials are sought to provide new functionalities for applications ranging from information processing and storage to energy generation and biomedical imaging. MXenes are a rapidly growing family of two-dimensional transition metal carbides and nitrides with versatile chemical and structural diversity, resulting in a variety of interesting electronic and optical properties. However, strategies for producing MXenes with tailored magnetic responses remain underdeveloped and challenging. Herein, we incorporate elemental Ni and Co into Ti₃C₂T_x MXene by mixing with dilute metal chloride solutions. We achieve a uniform distribution of Ni and Co, confirmed by X-ray fluorescence (XRF) mapping with nanometer resolution, with Ni and Co concentrations of approximately 2 and 7 at% relative to the Ti concentration. The magnetic susceptibility of these Ni- and Co-incorporated Ti₃C₂T_x MXenes is one to two orders of magnitude larger than pristine Ti₃C₂T_x, illustrating the potential for dilute metal incorporation to enhance linear magnetic responses at room temperature.

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Research Organization:: Drexel Univ., Philadelphia, PA (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Science Foundation Graduate Research Fellowship

Grant/Contract Number:: SC0018618; SC0012704; DGE-1646737

OSTI ID:: 2315070

Alternate ID(s):: OSTI ID: 2324572; OSTI ID: 2336580

Report Number(s):: BNL-225475-2024-JAAM; NANOHL

Journal Information:: Nanoscale, Journal Name: Nanoscale Vol. 16 Journal Issue: 11; ISSN 2040-3364

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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