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Title: Evaluation of packed-bed and fluidized-bed cell technology for the destruction and removal of contaminants in alkaline waste solutions. Final report

Technical Report ·
DOI:https://doi.org/10.2172/231308· OSTI ID:231308
 [1]; ;  [2]
  1. Westinghouse Savannah River Co., Aiken, SC (United States)
  2. Texas A&M Univ., College Station, TX (United States). Surface Electrochemistry Laboratory

Disposing of the large quantity of nuclear waste that has been produced within the DOE complex is an area of active research and development. Electrochemical processes have been reported for the treatment of alkaline wastes including the destruction of nitrate and nitrite and the removal of metals such as Tc and Ru. Electrolytic recovery of metals from dilute solution has been reported using conventional porous electrodes such as felt electrode and reticulated electrode, but use of such electrodes is limited. The pores of such electrodes become blocked as a consequence of metal deposition. If an attempt is made to regenerate these electrodes by dissolution of the deposited metals, oxygen evolution on the matrix competes with dissolution of metals deposited within the pores. On the other hand, the use of three dimensional packed-bed and fluidized-bed electrodes having large surface area per unit volume would offer an improvement on felt or reticulated system because of the greater ease of regeneration.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-89SR18035
OSTI ID:
231308
Report Number(s):
WSRC-TR-95-0310; ON: DE96005799
Resource Relation:
Other Information: PBD: [1995]
Country of Publication:
United States
Language:
English