On-surface magnetocaloric effect for a van der Waals Gd( iii ) 2D MOF grown on Si

Kumar, Subodh; Riera, Guillem Gabarró; Arauzo, Ana; Hrubý, Jakub; Hill, Stephen; Bogani, Lapo; Rubio-Zuazo, Juan; Jover, Jesús; Bartolomé, Elena; Sañudo, E. Carolina

doi:10.1039/D3TA06648G

Title: On-surface magnetocaloric effect for a van der Waals Gd( iii ) 2D MOF grown on Si

Journal Article · Tue Mar 12 00:00:00 EDT 2024 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/D3TA06648G· OSTI ID:2311225

Kumar, Subodh ^[1];

^[1];

^[2]; Hrubý, Jakub ^[3];

^[4];

^[5]; Rubio-Zuazo, Juan ^[6];

^[7];

^[8];

^[1]

Institut de Nanociències i Nanotecnologia, Universitat de Barcelona (IN2UB), 08028 Barcelona, Spain, Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, C/Martí i Franqués 1-11, 08028, Barcelona, Spain
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Departamento de Física de la Materia Condensada, 50009 Zaragoza, Spain
National High Magnetic Field Laboratory, Tallahassee, FL 32310, USA
National High Magnetic Field Laboratory, Tallahassee, FL 32310, USA, Department of Physics, Florida State University, Tallahassee, FL 32306, USA
Department of Materials, University of Oxford, 16 Parks Road, OX1 3PH, Oxford, UK
BM25-SpLine Beamline at the ESRF, 71 Avenue des Martyrs, 38043, Grenoble, France, Instituto de Ciencia de Materiales de Madrid-CSIC, Sor Juana Inés de la Cruz, 3, Cantoblanco, 28049 Madrid, Spain
Institut de Nanociències i Nanotecnologia, Universitat de Barcelona (IN2UB), 08028 Barcelona, Spain, Institut de Química Teórica i Computacional (IQTC), Department of Inorganic and Organic Chemistry, Faculty of Chemistry, University of Barcelona, Spain
Institut de Ciència de Materials de Barcelona (ICMAB), CSIC, Campus UAB, 08193 Barcelona, Spain

[Gd(MeCOO)(PhCOO) ₂ ], a 2D MOF is reported and characterized, the material shows a magnetocaloric effect both in bulk and chemisorbed on a Silicon substrate. This opens up the possibilities for on-surface cooling devices.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0020260

OSTI ID:: 2311225

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Vol. 12 Journal Issue: 11; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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