Nuclear Magnetic Resonance Relaxation Pathways in Electrolytes for Energy Storage

Fraenza, Carla C.; Greenbaum, Steve G.; Suarez, Sophia N.

doi:10.3390/ijms241210373

Nuclear Magnetic Resonance Relaxation Pathways in Electrolytes for Energy Storage

Journal Article · Tue Jun 20 00:00:00 EDT 2023 · International Journal of Molecular Sciences (Online)

DOI:https://doi.org/10.3390/ijms241210373· OSTI ID:2311094

^[1]; ^[2]; ^[3]

Hunter College, City University of New York, NY (United States); Case Western Reserve University
Hunter College, City University of New York, NY (United States); The Graduate Center, City University of New York, NY (United States)
The Graduate Center, City University of New York, NY (United States); Brooklyn College, City University of New York, NY (United States)

Nuclear Magnetic Resonance (NMR) spin relaxation times have been an instrumental tool in deciphering the local environment of ionic species, the various interactions they engender and the effect of these interactions on their dynamics in conducting media. Of particular importance has been their application in studying the wide range of electrolytes for energy storage, on which this review is based. Here we highlight some of the research carried out on electrolytes in recent years using NMR relaxometry techniques. Specifically, we highlight studies on liquid electrolytes, such as ionic liquids and organic solvents; on semi-solid-state electrolytes, such as ionogels and polymer gels; and on solid electrolytes such as glasses, glass ceramics and polymers. Although this review focuses on a small selection of materials, we believe they demonstrate the breadth of application and the invaluable nature of NMR relaxometry.

View Accepted Manuscript (DOE)

Research Organization:: Case Western Reserve University, Cleveland, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019409

OSTI ID:: 2311094

Journal Information:: International Journal of Molecular Sciences (Online), Journal Name: International Journal of Molecular Sciences (Online) Journal Issue: 12 Vol. 24; ISSN 1422-0067

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

References (181)

Flexible Composite Solid Electrolyte Facilitating Highly Stable “Soft Contacting” Li-Electrolyte Interface for Solid State Lithium-Ion Batteries Yang, Luyi; Wang, Zijian; Feng, Yancong Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701437	journal	September 2017
Gel Polymer Electrolytes for Electrochemical Energy Storage Cheng, Xunliang; Pan, Jian; Zhao, Yang Advanced Energy Materials, Vol. 8, Issue 7 https://doi.org/10.1002/aenm.201702184	journal	November 2017
Ionogel Electrolytes for High-Performance Lithium Batteries: A Review Chen, Nan; Zhang, Haiqin; Li, Li Advanced Energy Materials, Vol. 8, Issue 12 https://doi.org/10.1002/aenm.201702675	journal	January 2018
High‐Voltage Supercapacitors Based on Aqueous Electrolytes Zang, Xining; Shen, Caiwei; Sanghadasa, Mohan ChemElectroChem, Vol. 6, Issue 4 https://doi.org/10.1002/celc.201801225	journal	November 2018
Li-S Battery Analyzed by UV/Vis in Operando Mode Patel, Manu U. M.; Demir-Cakan, Rezan; Morcrette, Mathieu ChemSusChem, Vol. 6, Issue 7 https://doi.org/10.1002/cssc.201300142	journal	June 2013
All-Solid-State Lithium-Ion Batteries with Grafted Ceramic Nanoparticles Dispersed in Solid Polymer Electrolytes Lago, Nerea; Garcia-Calvo, Oihane; Lopez del Amo, Juan Miguel ChemSusChem, Vol. 8, Issue 18 https://doi.org/10.1002/cssc.201500783	journal	August 2015
Nuclear magnetic relaxation and diffusion study of the ionic liquids 1-ethyl- and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide confined in porous glass Ordikhani Seyedlar, Amin; Stapf, Siegfried; Mattea, Carlos Magnetic Resonance in Chemistry, Vol. 57, Issue 10 https://doi.org/10.1002/mrc.4852	journal	March 2019
Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density Placke, Tobias; Kloepsch, Richard; Dühnen, Simon Journal of Solid State Electrochemistry, Vol. 21, Issue 7 https://doi.org/10.1007/s10008-017-3610-7	journal	May 2017
Influence of cellulose gel matrix on BMIMCl ionic liquid dynamics and conductivity Kaszyńska, J.; Rachocki, A.; Bielejewski, M. Cellulose, Vol. 24, Issue 4 https://doi.org/10.1007/s10570-017-1223-z	journal	February 2017
Ionic liquid dynamics and electrical conductivity under confinement within micro and nanocellulose ionogels Kowalczuk, Joanna; Bielejewski, Michał; Tritt-Goc, Jadwiga Cellulose, Vol. 30, Issue 6 https://doi.org/10.1007/s10570-023-05091-1	journal	February 2023
A review of polymer electrolytes: fundamental, approaches and applications Ngai, Koh Sing; Ramesh, S.; Ramesh, K. Ionics, Vol. 22, Issue 8 https://doi.org/10.1007/s11581-016-1756-4	journal	June 2016
Automotive Li-Ion Batteries: Current Status and Future Perspectives Ding, Yuanli; Cano, Zachary P.; Yu, Aiping Electrochemical Energy Reviews, Vol. 2, Issue 1 https://doi.org/10.1007/s41918-018-0022-z	journal	January 2019
Behavior of transport characteristics in several one-dimensional disordered systems Oshanin, G.; Burlatsky, S. F.; Moreau, M. Chemical Physics, Vol. 177, Issue 3 https://doi.org/10.1016/0301-0104(93)85043-8	journal	December 1993
Deep eutectic solvents for the production and application of new materials Tomé, Luciana I. N.; Baião, Vanessa; da Silva, Wanderson Applied Materials Today, Vol. 10 https://doi.org/10.1016/j.apmt.2017.11.005	journal	March 2018
A highly ion-conductive three-dimensional LLZAO-PEO/LiTFSI solid electrolyte for high-performance solid-state batteries Cai, Dan; Wang, Donghuang; Chen, Yongjie Chemical Engineering Journal, Vol. 394 https://doi.org/10.1016/j.cej.2020.124993	journal	August 2020
Solid polymer electrolytes based on the composite of PEO–LiFSI and organic ionic plastic crystal Wang, Wanwan; Fang, Zhiqiang; Zhao, Ming Chemical Physics Letters, Vol. 747 https://doi.org/10.1016/j.cplett.2020.137335	journal	May 2020
A comparison of single-wall carbon nanotube electrochemical capacitor electrode fabrication methods Ervin, Matthew H.; Miller, Benjamin S.; Hanrahan, Brendan Electrochimica Acta, Vol. 65 https://doi.org/10.1016/j.electacta.2012.01.060	journal	March 2012
Ionic mobility in ternary polymer electrolytes for lithium-ion batteries Joost, Mario; Kunze, Miriam; Jeong, Sangsik Electrochimica Acta, Vol. 86 https://doi.org/10.1016/j.electacta.2012.03.084	journal	December 2012
Properties of sodium-based ionic liquid electrolytes for sodium secondary battery applications Mohd Noor, Siti Aminah; Howlett, Patrick C.; MacFarlane, Douglas R. Electrochimica Acta, Vol. 114 https://doi.org/10.1016/j.electacta.2013.09.115	journal	December 2013
Thermal Properties, Conductivity, and Spin-lattice Relaxation of Gel Electrolyte Based on Low Molecular Weight Gelator and Solution of High Temperature Ionic Liquid Bielejewski, Michał; Puszkarska, Anna; Tritt-Goc, Jadwiga Electrochimica Acta, Vol. 165 https://doi.org/10.1016/j.electacta.2015.03.009	journal	May 2015
7Li nuclear magnetic resonance studies of dynamics in a ternary gel polymer electrolyte based on polymeric ionic liquids Gouverneur, Martin; Jeremias, Sebastian; Schönhoff, Monika Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.026	journal	September 2015
Recent Advances in Innovative Polymer Electrolytes based on Poly(ionic liquid)s Shaplov, Alexander S.; Marcilla, Rebeca; Mecerreyes, David Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.038	journal	September 2015
Sodium ion dynamics in a sulfonate based ionomer system studied by 23Na solid-state nuclear magnetic resonance and impedance spectroscopy Pope, Cameron R.; Romanenko, Konstantin; MacFarlane, Douglas R. Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.131	journal	September 2015
Polymer effect on lithium ion dynamics in gel polymer electrolytes: Cationic versus acrylate polymer Bhandary, Rajesh; Schönhoff, Monika Electrochimica Acta, Vol. 174 https://doi.org/10.1016/j.electacta.2015.05.145	journal	August 2015
A fluorinated polycarbonate based all solid state polymer electrolyte for lithium metal batteries Wang, Qinglei; Liu, Xiaochen; Cui, Zili Electrochimica Acta, Vol. 337 https://doi.org/10.1016/j.electacta.2020.135843	journal	March 2020
Predominantly chain segmental relaxation dependent ionic conductivity of multiphase semicrystalline PVDF/PEO/LiClO4 solid polymer electrolytes Sengwa, R. J.; Dhatarwal, Priyanka Electrochimica Acta, Vol. 338 https://doi.org/10.1016/j.electacta.2020.135890	journal	April 2020
Ionic liquid-based gel polymer electrolyte containing zwitterion for lithium-oxygen batteries Woo, Hyun-Sik; Son, Hyebeen; Min, Ji-Yun Electrochimica Acta, Vol. 345 https://doi.org/10.1016/j.electacta.2020.136248	journal	June 2020
Status and perspectives on 100% renewable energy systems Hansen, Kenneth; Breyer, Christian; Lund, Henrik Energy, Vol. 175 https://doi.org/10.1016/j.energy.2019.03.092	journal	May 2019
All solid-state polymer electrolytes for high-performance lithium ion batteries Yue, Liping; Ma, Jun; Zhang, Jianjun Energy Storage Materials, Vol. 5 https://doi.org/10.1016/j.ensm.2016.07.003	journal	October 2016
Thermal runaway mechanism of lithium ion battery for electric vehicles: A review Feng, Xuning; Ouyang, Minggao; Liu, Xiang Energy Storage Materials, Vol. 10 https://doi.org/10.1016/j.ensm.2017.05.013	journal	January 2018
Of renewable energy, energy democracy, and sustainable development: A roadmap to accelerate the energy transition in developing countries Vanegas Cantarero, Maria Mercedes Energy Research & Social Science, Vol. 70 https://doi.org/10.1016/j.erss.2020.101716	journal	December 2020
Translational dynamics of ionic liquid imidazolium cations at solid/liquid interface in gel polymer electrolyte Rachocki, Adam; Andrzejewska, Ewa; Dembna, Agata European Polymer Journal, Vol. 71 https://doi.org/10.1016/j.eurpolymj.2015.08.001	journal	October 2015
Short range order characterization of the Na2S + SiS2 glass system using Raman, infrared and 29Si magic angle spinning nuclear magnetic resonance spectroscopies Watson, Deborah E.; Martin, Steve W. Journal of Non-Crystalline Solids, Vol. 471 https://doi.org/10.1016/j.jnoncrysol.2017.04.032	journal	September 2017
Patternable, Solution-Processed Ionogels for Thin-Film Lithium-Ion Electrolytes Ashby, David S.; DeBlock, Ryan H.; Lai, Chun-Han Joule, Vol. 1, Issue 2 https://doi.org/10.1016/j.joule.2017.08.012	journal	October 2017
Solvent-free, PYR1ATFSI ionic liquid-based ternary polymer electrolyte systems Kim, Guk-Tae; Appetecchi, Giovanni B.; Alessandrini, Fabrizio Journal of Power Sources, Vol. 171, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.07.020	journal	September 2007
NaFSA–C1C3pyrFSA ionic liquids for sodium secondary battery operating over a wide temperature range Ding, Changsheng; Nohira, Toshiyuki; Kuroda, Keisuke Journal of Power Sources, Vol. 238 https://doi.org/10.1016/j.jpowsour.2013.03.089	journal	September 2013
Ionic liquid based electrolytes for sodium-ion batteries: Na+ solvation and ionic conductivity Monti, Damien; Jónsson, Erlendur; Palacín, M. Rosa Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.06.153	journal	January 2014
Na[FSA]-[C3C1pyrr][FSA] ionic liquids as electrolytes for sodium secondary batteries: Effects of Na ion concentration and operation temperature Ding, Changsheng; Nohira, Toshiyuki; Hagiwara, Rika Journal of Power Sources, Vol. 269 https://doi.org/10.1016/j.jpowsour.2014.06.033	journal	December 2014
Survey of the transport properties of sodium superionic conductor materials for use in sodium batteries Guin, M.; Tietz, F. Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.137	journal	January 2015
Challenges and issues facing lithium metal for solid-state rechargeable batteries Mauger, A.; Armand, M.; Julien, C. M. Journal of Power Sources, Vol. 353 https://doi.org/10.1016/j.jpowsour.2017.04.018	journal	June 2017
Multinuclear magnetic resonance investigation of cation-anion and anion-solvent interactions in carbonate electrolytes Peng, Jing; Gobet, Mallory; Devany, Matthew Journal of Power Sources, Vol. 399 https://doi.org/10.1016/j.jpowsour.2018.07.095	journal	September 2018
High Li-ion conductive composite polymer electrolytes for all-solid-state Li-metal batteries Zhou, Qiongyu; Li, Qinghui; Liu, Songli Journal of Power Sources, Vol. 482 https://doi.org/10.1016/j.jpowsour.2020.228929	journal	January 2021
Improved ion dissociation and amorphous region of PEO based solid polymer electrolyte by incorporating tetracyanoethylene Polu, Anji Reddy; Singh, Pramod K. Materials Today: Proceedings, Vol. 49 https://doi.org/10.1016/j.matpr.2020.10.950	journal	January 2022
New polymerized ionic liquid (PIL) gel electrolyte membranes based on tetraalkylammonium cations for lithium ion batteries Li, Mingtao; Yang, Bolun; Wang, Lu Journal of Membrane Science, Vol. 447 https://doi.org/10.1016/j.memsci.2013.07.007	journal	November 2013
Zinc (II) chloride-based deep eutectic solvents for application as electrolytes: Preparation and characterization Ghareh Bagh, Fatemeh S.; Shahbaz, Kaveh; Mjalli, Farouq S. Journal of Molecular Liquids, Vol. 204 https://doi.org/10.1016/j.molliq.2015.01.025	journal	April 2015
Structural characterization of the [CnC1im][C4F9SO3] ionic liquid series: Alkyl versus perfluoroalkyl side chains Shimizu, Karina; Freitas, Adilson A.; Canongia Lopes, José N. Journal of Molecular Liquids, Vol. 226 https://doi.org/10.1016/j.molliq.2016.08.014	journal	January 2017
Density, viscosity and electrical conductivity of AlCl 3 -amide ionic liquid analogues Liu, Chengyuan; Chen, Wenting; Wu, Zimo Journal of Molecular Liquids, Vol. 247 https://doi.org/10.1016/j.molliq.2017.09.091	journal	December 2017
Aluminum ions speciation and transport in acidic deep eutectic AlCl3 amide electrolytes Paterno, Domenec; Rock, Emma; Forbes, Andrew Journal of Molecular Liquids, Vol. 319 https://doi.org/10.1016/j.molliq.2020.114118	journal	December 2020
Probing relaxation models by means of Fast Field-Cycling relaxometry, NMR spectroscopy and molecular dynamics simulations: Detailed insight into the translational and rotational dynamics of a protic ionic liquid Overbeck, Viviane; Golub, Benjamin; Schröder, Henning Journal of Molecular Liquids, Vol. 319 https://doi.org/10.1016/j.molliq.2020.114207	journal	December 2020
Rotational correlation times, diffusion coefficients and quadrupolar peaks of the protic ionic liquid ethylammonium nitrate by means of 1H fast field cycling NMR relaxometry Overbeck, Viviane; Appelhagen, Andreas; Rößler, Ronja Journal of Molecular Liquids, Vol. 322 https://doi.org/10.1016/j.molliq.2020.114983	journal	January 2021
Molecular-level insights into structure and dynamics in ionic liquids and polymer gel electrolytes Garaga, Mounesha N.; Jayakody, Nishani; Fraenza, Carla C. Journal of Molecular Liquids, Vol. 329 https://doi.org/10.1016/j.molliq.2021.115454	journal	May 2021
Ionic liquids with hydrogenated and perfluorinated chains: Structural study of the [P6,6,6,14][FnCOO] n = 7, 9, 11. Checking the existence of polar – hydrogenated – perfluorinated triphilic continuity Silva, Gonçalo M. C.; Beira, Maria J.; Morgado, Pedro Journal of Molecular Liquids, Vol. 367 https://doi.org/10.1016/j.molliq.2022.120506	journal	December 2022
Field-cycling NMR relaxometry Kimmich, Rainer; Anoardo, Esteban Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 44, Issue 3-4 https://doi.org/10.1016/j.pnmrs.2004.03.002	journal	July 2004
NMR self diffusion and relaxation time measurements for poly (vinylidene fluoride) (PVDF) based polymer gel electrolytes containing LiBF and propylene carbonate Richardson, P. M.; Voice, A. M.; Ward, I. M. Polymer, Vol. 97 https://doi.org/10.1016/j.polymer.2016.03.074	journal	August 2016
Beyond PEO—Alternative host materials for Li + -conducting solid polymer electrolytes Mindemark, Jonas; Lacey, Matthew J.; Bowden, Tim Progress in Polymer Science, Vol. 81 https://doi.org/10.1016/j.progpolymsci.2017.12.004	journal	June 2018
The lithium-ion battery: State of the art and future perspectives Zubi, Ghassan; Dufo-López, Rodolfo; Carvalho, Monica Renewable and Sustainable Energy Reviews, Vol. 89 https://doi.org/10.1016/j.rser.2018.03.002	journal	June 2018
New promising NASICON material as solid electrolyte for sodium-ion batteries: Correlation between composition, crystal structure and ionic conductivity of Na3+xSc2SixP3−xO12 Guin, M.; Tietz, F.; Guillon, O. Solid State Ionics, Vol. 293 https://doi.org/10.1016/j.ssi.2016.06.005	journal	October 2016
Na 3 Zr 2 (SiO 4 ) 2 (PO 4 ) prepared by a solution-assisted solid state reaction Naqash, Sahir; Ma, Qianli; Tietz, Frank Solid State Ionics, Vol. 302 https://doi.org/10.1016/j.ssi.2016.11.004	journal	April 2017
Gel polymer electrolytes for lithium ion batteries: Fabrication, characterization and performance Liang, Shishuo; Yan, Wenqi; Wu, Xu Solid State Ionics, Vol. 318 https://doi.org/10.1016/j.ssi.2017.12.023	journal	May 2018
23Na nuclear magnetic resonance study of yNa2S + (1 − y)[xSiS2 + (1 − x)PS5/2] glassy solid electrolytes Shastri, Ananda; Watson, Deborah; Ding, Qing-Ping Solid State Ionics, Vol. 340 https://doi.org/10.1016/j.ssi.2019.115013	journal	November 2019
Na+ ion mobility in Na3+Sc2(SiO4) (PO4)3− (0.1 < x < 0.8) observed by 23Na NMR spectroscopy Zinkevich, Tatiana; Fiedler, Andy; Guin, Marie Solid State Ionics, Vol. 348 https://doi.org/10.1016/j.ssi.2020.115277	journal	May 2020
Lithium ion dynamics in Li2S+GeS2+GeO2 glasses studied using 7Li NMR field-cycling relaxometry and line-shape analysis Gabriel, Jan; Petrov, Oleg V.; Kim, Youngsik Solid State Nuclear Magnetic Resonance, Vol. 70 https://doi.org/10.1016/j.ssnmr.2015.06.004	journal	September 2015
NMR Studies of Translational Motion Price, William S. https://doi.org/10.1017/CBO9780511770487		January 2009
Deciphering the Ethylene Carbonate–Propylene Carbonate Mystery in Li-Ion Batteries Xing, Lidan; Zheng, Xiongwen; Schroeder, Marshall Accounts of Chemical Research, Vol. 51, Issue 2 https://doi.org/10.1021/acs.accounts.7b00474	journal	January 2018
Insights into the Transport of Alkali Metal Ions Doped into a Plastic Crystal Electrolyte Chen, Fangfang; Pringle, Jennifer M.; Forsyth, Maria Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/acs.chemmater.5b00538	journal	March 2015
Scandium-Substituted Na ₃ Zr ₂ (SiO ₄ ) ₂ (PO ₄ ) Prepared by a Solution-Assisted Solid-State Reaction Method as Sodium-Ion Conductors Ma, Qianli; Guin, Marie; Naqash, Sahir Chemistry of Materials, Vol. 28, Issue 13 https://doi.org/10.1021/acs.chemmater.6b02059	journal	June 2016
Thermal Decomposition of the Solid Electrolyte Interphase (SEI) on Silicon Electrodes for Lithium Ion Batteries Yoon, Taeho; Milien, Mickdy S.; Parimalam, Bharathy S. Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.7b00454	journal	March 2017
Structural and Spectroscopic Characterizations of Amide–AlCl ₃ -Based Ionic Liquid Analogues Hu, Pengcheng; Zhang, Rui; Meng, Xianghai Inorganic Chemistry, Vol. 55, Issue 5 https://doi.org/10.1021/acs.inorgchem.5b02744	journal	February 2016
Densities, Viscosities, and Conductivities of the Imidazolium Ionic Liquids [Emim][Ac], [Emim][FAP], [Bmim][BETI], [Bmim][FSI], [Hmim][TFSI], and [Omim][TFSI] Nazet, Andreas; Sokolov, Sophia; Sonnleitner, Thomas Journal of Chemical & Engineering Data, Vol. 60, Issue 8 https://doi.org/10.1021/acs.jced.5b00285	journal	July 2015
Temperature and Density Dependence of the Transport Properties of the Ionic Liquid Triethylpentylphosphonium Bis(trifluoromethanesulfonyl)amide, [P_222,5][Tf₂N] Harris, Kenneth R.; Kanakubo, Mitsuhiro; Kodama, Daisuke Journal of Chemical & Engineering Data, Vol. 63, Issue 6 https://doi.org/10.1021/acs.jced.8b00011	journal	May 2018
Anions as Dynamic Probes for Ionic Liquid Mixtures Di Pietro, Maria Enrica; Castiglione, Franca; Mele, Andrea The Journal of Physical Chemistry B, Vol. 124, Issue 14 https://doi.org/10.1021/acs.jpcb.0c00026	journal	March 2020
NMR Relaxometry and Diffusometry Analysis of Dynamics in Ionic Liquids and Ionogels for Use in Lithium-Ion Batteries Jayakody, Nishani Kanchana; Fraenza, Carla C.; Greenbaum, Steven G. The Journal of Physical Chemistry B, Vol. 124, Issue 31 https://doi.org/10.1021/acs.jpcb.0c02755	journal	July 2020
Heterogeneous Structures of Ionic Liquids as Probed by CO Rotation with Nuclear Magnetic Resonance Relaxation Analysis and Molecular Dynamics Simulations Endo, Takatsugu; Sumida, Hiroki; Fujii, Kaori The Journal of Physical Chemistry B, Vol. 124, Issue 46 https://doi.org/10.1021/acs.jpcb.0c08030	journal	November 2020
Solvation Dynamics of Wet Ethaline: Water is the Magic Component Alfurayj, Ibrahim; Fraenza, Carla Cecilia; Zhang, Yong The Journal of Physical Chemistry B, Vol. 125, Issue 31 https://doi.org/10.1021/acs.jpcb.1c04629	journal	August 2021
Dynamics of Glyceline and Interactions of Constituents: A Multitechnique NMR Study Fraenza, Carla C.; Elgammal, Ramez A.; Garaga, Mounesha N. The Journal of Physical Chemistry B, Vol. 126, Issue 4 https://doi.org/10.1021/acs.jpcb.1c09227	journal	January 2022
Stability of the Liquid State of Imidazolium-Based Ionic Liquids under High Pressure at Room Temperature Yoshimura, Yukihiro; Shigemi, Machiko; Takaku, Mayumi The Journal of Physical Chemistry B, Vol. 119, Issue 25 https://doi.org/10.1021/acs.jpcb.5b03476	journal	June 2015
Composition Dependence of the Na ⁺ Ion Conductivity in 0.5Na ₂ S + 0.5[ x GeS ₂ + (1 – x )PS _5/2 ] Mixed Glass Former Glasses: A Structural Interpretation of a Negative Mixed Glass Former Effect Martin, Steve W.; Bischoff, Christian; Schuller, Katherine The Journal of Physical Chemistry B, Vol. 119, Issue 51 https://doi.org/10.1021/acs.jpcb.5b07383	journal	December 2015
Do TFSA Anions Slither? Pressure Exposes the Role of TFSA Conformational Exchange in Self-Diffusion Suarez, Sophia N.; Rúa, Armando; Cuffari, David The Journal of Physical Chemistry B, Vol. 119, Issue 46 https://doi.org/10.1021/acs.jpcb.5b08658	journal	November 2015
Polarity and Nonpolarity of Ionic Liquids Viewed from the Rotational Dynamics of Carbon Monoxide Yasaka, Y.; Kimura, Y. The Journal of Physical Chemistry B, Vol. 119, Issue 50 https://doi.org/10.1021/acs.jpcb.5b09745	journal	December 2015
Positive and Negative Mixed Glass Former Effects in Sodium Borosilicate and Borophosphate Glasses Studied by ²³ Na NMR Storek, Michael; Adjei-Acheamfour, Mischa; Christensen, Randilynn The Journal of Physical Chemistry B, Vol. 120, Issue 19 https://doi.org/10.1021/acs.jpcb.6b00482	journal	May 2016
Rotational Dynamics in Ionic Liquids from NMR Relaxation Experiments and Simulations: Benzene and 1-Ethyl-3-Methylimidazolium Rumble, Christopher A.; Kaintz, Anne; Yadav, Sharad K. The Journal of Physical Chemistry B, Vol. 120, Issue 35 https://doi.org/10.1021/acs.jpcb.6b06715	journal	August 2016
¹ H NMR Relaxometry and Diffusometry Study of Magnetic and Nonmagnetic Ionic Liquid-Based Solutions: Cosolvent and Temperature Effects Beira, Maria; Daniel, Carla I.; Almeida, Pedro L. The Journal of Physical Chemistry B, Vol. 121, Issue 51 https://doi.org/10.1021/acs.jpcb.7b07929	journal	December 2017
Trends in Na-Ion Solvation with Alkyl-Carbonate Electrolytes for Sodium-Ion Batteries: Insights from First-Principles Calculations Shakourian-Fard, Mehdi; Kamath, Ganesh; Smith, Kassiopeia The Journal of Physical Chemistry C, Vol. 119, Issue 40 https://doi.org/10.1021/acs.jpcc.5b04706	journal	September 2015
Unique Behavior of Dimethoxyethane (DME)/Mg(N(SO ₂ CF ₃ ) ₂ ) ₂ Solutions Salama, Michael; Shterenberg, Ivgeni; Gizbar, Haim The Journal of Physical Chemistry C, Vol. 120, Issue 35 https://doi.org/10.1021/acs.jpcc.6b07733	journal	August 2016
Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF ₆ Parimalam, Bharathy S.; MacIntosh, Alex D.; Kadam, Rahul The Journal of Physical Chemistry C, Vol. 121, Issue 41 https://doi.org/10.1021/acs.jpcc.7b08433	journal	October 2017
Solvation of Mg ²⁺ Ions in Mg(TFSI) ₂ –Dimethoxyethane Electrolytes—A View from Molecular Dynamics Simulations Kubisiak, Piotr; Eilmes, Andrzej The Journal of Physical Chemistry C, Vol. 122, Issue 24 https://doi.org/10.1021/acs.jpcc.8b02460	journal	May 2018
Influence of Cationic Poly(ionic liquid) Architecture on the Ion Dynamics in Polymer Gel Electrolytes Brinkkötter, Marc; Lozinskaya, Elena I.; Ponkratov, Denis O. The Journal of Physical Chemistry C, Vol. 123, Issue 21 https://doi.org/10.1021/acs.jpcc.9b03089	journal	May 2019
Understanding the Nature of Nuclear Magnetic Resonance Relaxation by Means of Fast-Field-Cycling Relaxometry and Molecular Dynamics Simulations—The Validity of Relaxation Models Honegger, Philipp; Overbeck, Viviane; Strate, Anne The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00087	journal	February 2020
Ion Pairing and Redissociaton in Low-Permittivity Electrolytes for Multivalent Battery Applications Self, Julian; Hahn, Nathan T.; Fong, Kara D. The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00334	journal	February 2020
Role of Solvent Rearrangement on Mg ²⁺ Solvation Structures in Dimethoxyethane Solutions using Multimodal NMR Analysis Chen, Ying; Jaegers, Nicholas R.; Wang, Hui The Journal of Physical Chemistry Letters, Vol. 11, Issue 15 https://doi.org/10.1021/acs.jpclett.0c01447	journal	July 2020
Probing the Fast Lithium-Ion Transport in Small-Molecule Solid Polymer Electrolytes by Solid-State NMR Fu, Xiaobin; Liu, Yiyang; Wang, Wei Macromolecules, Vol. 53, Issue 22 https://doi.org/10.1021/acs.macromol.0c01521	journal	November 2020
Atomistic Description of Ionic Diffusion in PEO–LiTFSI: Effect of Temperature, Molecular Weight, and Ionic Concentration Brooks, Daniel J.; Merinov, Boris V.; Goddard, William A. Macromolecules, Vol. 51, Issue 21 https://doi.org/10.1021/acs.macromol.8b01753	journal	October 2018
From Local to Diffusive Dynamics in Polymer Electrolytes: NMR Studies on Coupling of Polymer and Ion Dynamics across Length and Time Scales Becher, Manuel; Becker, Simon; Hecht, Lukas Macromolecules, Vol. 52, Issue 23 https://doi.org/10.1021/acs.macromol.9b01400	journal	November 2019
High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide) Lin, Dingchang; Liu, Wei; Liu, Yayuan Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04117	journal	December 2015
Effect of Hydrofluoroether Cosolvent Addition on Li Solvation in Acetonitrile-Based Solvate Electrolytes and Its Influence on S Reduction in a Li–S Battery See, Kimberly A.; Wu, Heng-Liang; Lau, Kah Chun ACS Applied Materials & Interfaces, Vol. 8, Issue 50 https://doi.org/10.1021/acsami.6b11358	journal	December 2016
Effect of the Hydrofluoroether Cosolvent Structure in Acetonitrile-Based Solvate Electrolytes on the Li ⁺ Solvation Structure and Li–S Battery Performance Shin, Minjeong; Wu, Heng-Liang; Narayanan, Badri ACS Applied Materials & Interfaces, Vol. 9, Issue 45 https://doi.org/10.1021/acsami.7b11566	journal	November 2017
A Nuclear Magnetic Resonance Study of Cation and Anion Dynamics in Polymer–Ceramic Composite Solid Electrolytes Peng, Jing; Xiao, Ye; Clarkson, David A. ACS Applied Polymer Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsapm.9b01068	journal	March 2020
Directing the Lithium–Sulfur Reaction Pathway via Sparingly Solvating Electrolytes for High Energy Density Batteries Lee, Chang-Wook; Pang, Quan; Ha, Seungbum ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00123	journal	May 2017
Sparingly Solvating Electrolytes for High Energy Density Lithium–Sulfur Batteries Cheng, Lei; Curtiss, Larry A.; Zavadil, Kevin R. ACS Energy Letters, Vol. 1, Issue 3 https://doi.org/10.1021/acsenergylett.6b00194	journal	August 2016
Relationship between Segmental Dynamics Measured by Quasi-Elastic Neutron Scattering and Conductivity in Polymer Electrolytes Mongcopa, Katrina Irene S.; Tyagi, Madhusudan; Mailoa, Jonathan P. ACS Macro Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsmacrolett.8b00159	journal	March 2018
Lithium Salt Effects on the Liquid Structure of Choline Chloride–Urea Deep Eutectic Solvent Di Pietro, Maria Enrica; Goloviznina, Kateryna; van den Bruinhorst, Adriaan ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 36 https://doi.org/10.1021/acssuschemeng.2c02460	journal	August 2022
Role of the LiPF ₆ Salt for the Long-Term Stability of Silicon Electrodes in Li-Ion Batteries – A Photoelectron Spectroscopy Study Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303399v	journal	January 2013
Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase Shi, Siqi; Lu, Peng; Liu, Zhongyi Journal of the American Chemical Society, Vol. 134, Issue 37 https://doi.org/10.1021/ja305366r	journal	September 2012
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046 https://doi.org/10.1021/ja412807w	journal	March 2014
Ab Initio Structure Search and in Situ ⁷ Li NMR Studies of Discharge Products in the Li–S Battery System See, Kimberly A.; Leskes, Michal; Griffin, John M. Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja508982p	journal	November 2014
Solvation Sheath of Li ⁺ in Nonaqueous Electrolytes and Its Implication of Graphite/Electrolyte Interface Chemistry Xu, Kang; Lam, Yiufai; Zhang, Sheng S. The Journal of Physical Chemistry C, Vol. 111, Issue 20 https://doi.org/10.1021/jp068691u	journal	May 2007
Measuring Molecular Dynamics and Activation Energies for Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids Using ¹⁴N NMR Spectroscopy Alam, Todd M.; Dreyer, Daniel R.; Bielwaski, Christopher W. The Journal of Physical Chemistry A, Vol. 115, Issue 17 https://doi.org/10.1021/jp200630k	journal	April 2011
Defect Thermodynamics and Diffusion Mechanisms in Li ₂ CO ₃ and Implications for the Solid Electrolyte Interphase in Li-Ion Batteries Shi, Siqi; Qi, Yue; Li, Hong The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp310591u	journal	March 2013
Pyrazolium- versus Imidazolium-Based Ionic Liquids: Structure, Dynamics and Physicochemical Properties Chiappe, Cinzia; Sanzone, Angelo; Mendola, Daniele The Journal of Physical Chemistry B, Vol. 117, Issue 2 https://doi.org/10.1021/jp3107793	journal	January 2013
Combined Measurement of Translational and Rotational Diffusion in Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids Alam, Todd M.; Dreyer, Daniel R.; Bielawski, Christopher W. The Journal of Physical Chemistry B, Vol. 117, Issue 6 https://doi.org/10.1021/jp3111953	journal	February 2013
Pyrrolidinium-Based Ionic Liquids Doped with Lithium Salts: How Does Li ⁺ Coordination Affect Its Diffusivity? Castiglione, Franca; Famulari, Antonino; Raos, Guido The Journal of Physical Chemistry B, Vol. 118, Issue 47 https://doi.org/10.1021/jp509387r	journal	September 2014
Ionic Liquid–Solute Interactions Studied by 2D NOE NMR Spectroscopy Khatun, Sufia; Castner, Edward W. The Journal of Physical Chemistry B, Vol. 119, Issue 29 https://doi.org/10.1021/jp509861g	journal	September 2014
Supercapacitor Devices Based on Graphene Materials Wang, Yan; Shi, Zhiqiang; Huang, Yi The Journal of Physical Chemistry C, Vol. 113, Issue 30 https://doi.org/10.1021/jp902214f	journal	July 2009
From Simple Liquid to Polymer Melt. Glassy and Polymer Dynamics Studied by Fast Field Cycling NMR Relaxometry: Rouse Regime Kariyo, S.; Brodin, A.; Gainaru, C. Macromolecules, Vol. 41, Issue 14 https://doi.org/10.1021/ma702758j	journal	July 2008
Graphene-Based Ultracapacitors Stoller, Meryl D.; Park, Sungjin; Zhu, Yanwu Nano Letters, Vol. 8, Issue 10 https://doi.org/10.1021/nl802558y	journal	October 2008
A strategic approach to recharging lithium-sulphur batteries for long cycle life Su, Yu-Sheng; Fu, Yongzhu; Cochell, Thomas Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3985	journal	December 2013
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes Li, Kaikai; Zhang, Jun; Lin, Dongmei Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08506-5	journal	February 2019
Fundamentals of inorganic solid-state electrolytes for batteries Famprikis, Theodosios; Canepa, Pieremanuele; Dawson, James A. Nature Materials, Vol. 18, Issue 12 https://doi.org/10.1038/s41563-019-0431-3	journal	August 2019
Field-cycling NMR Relaxometry: Instrumentation, Model Theories and Applications Kimmich, Rainer New Developments in NMR https://doi.org/10.1039/9781788012966	book	January 2018
Fast Li-ion conduction in poly(ethylene carbonate)-based electrolytes and composites filled with TiO ₂ nanoparticles Tominaga, Yoichi; Yamazaki, Kenta Chem. Commun., Vol. 50, Issue 34 https://doi.org/10.1039/C3CC49588D	journal	January 2014
Electrochemical stability of non-aqueous electrolytes for sodium-ion batteries and their compatibility with Na _0.7 CoO ₂ Bhide, Amrtha; Hofmann, Jonas; Katharina Dürr, Anna Phys. Chem. Chem. Phys., Vol. 16, Issue 5 https://doi.org/10.1039/C3CP53077A	journal	January 2014
Dynamics of the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulphonyl)imide studied by nuclear magnetic resonance dispersion and diffusion Ordikhani Seyedlar, Amin; Stapf, Siegfried; Mattea, Carlos Physical Chemistry Chemical Physics, Vol. 17, Issue 3 https://doi.org/10.1039/C4CP04178J	journal	January 2015
Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D. Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00372A	journal	January 2014
Self-diffusion, velocity cross-correlation, distinct diffusion and resistance coefficients of the ionic liquid [BMIM][Tf ₂ N] at high pressure Harris, Kenneth R.; Kanakubo, Mitsuhiro Physical Chemistry Chemical Physics, Vol. 17, Issue 37 https://doi.org/10.1039/C5CP04277A	journal	January 2015
A review of electrolyte materials and compositions for electrochemical supercapacitors Zhong, Cheng; Deng, Yida; Hu, Wenbin Chemical Society Reviews, Vol. 44, Issue 21 https://doi.org/10.1039/C5CS00303B	journal	January 2015
Enhancement of lithium transport by controlling the mesoporosity of silica monoliths filled by ionic liquids Guyomard-Lack, Aurélie; Said, Bilel; Dupré, Nicolas New Journal of Chemistry, Vol. 40, Issue 5 https://doi.org/10.1039/C5NJ03318G	journal	January 2016
Local coordination and dynamics of a protic ammonium based ionic liquid immobilized in nano-porous silica micro-particles probed by Raman and NMR spectroscopy Garaga, Mounesha N.; Persson, Michael; Yaghini, Negin Soft Matter, Vol. 12, Issue 9 https://doi.org/10.1039/C5SM02736E	journal	January 2016
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries Xue, Zhigang; He, Dan; Xie, Xiaolin Journal of Materials Chemistry A, Vol. 3, Issue 38 https://doi.org/10.1039/C5TA03471J	journal	January 2015
Dynamics of ionic liquids in bulk and in confinement by means of ¹ H NMR relaxometry – BMIM-OcSO ₄ in an SiO ₂ matrix as an example Kruk, Danuta; Wojciechowski, Milosz; Brym, Szczepan Physical Chemistry Chemical Physics, Vol. 18, Issue 33 https://doi.org/10.1039/C6CP02377K	journal	January 2016
Solvation behavior of carbonate-based electrolytes in sodium ion batteries Cresce, Arthur V.; Russell, Selena M.; Borodin, Oleg Physical Chemistry Chemical Physics, Vol. 19, Issue 1 https://doi.org/10.1039/C6CP07215A	journal	January 2017
Achieving enhanced ionic mobility in nanoporous silica by controlled surface interactions Garaga, Mounesha Nagendrachar; Aguilera, Luis; Yaghini, Negin Physical Chemistry Chemical Physics, Vol. 19, Issue 8 https://doi.org/10.1039/C6CP07351D	journal	January 2017
Spin relaxation studies of Li ⁺ ion dynamics in polymer gel electrolytes Brinkkötter, M.; Gouverneur, M.; Sebastião, P. J. Physical Chemistry Chemical Physics, Vol. 19, Issue 10 https://doi.org/10.1039/C6CP08756F	journal	January 2017
A ceramic/polymer composite solid electrolyte for sodium batteries Zhang, Zhizhen; Zhang, Qiangqiang; Ren, Cheng Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/C6TA07590H	journal	January 2016
Room temperature spin valve effect in the NiFe/Gr–hBN/Co magnetic tunnel junction Iqbal, Muhammad Zahir; Siddique, Salma; Hussain, Ghulam Journal of Materials Chemistry C, Vol. 4, Issue 37 https://doi.org/10.1039/C6TC03425J	journal	January 2016
Molecular dynamics of 1-ethyl-3-methylimidazolium triflate ionic liquid studied by ¹H and ¹⁹F nuclear magnetic resonances Wencka, Magdalena; Apih, Tomaž; Korošec, Romana Cerc Physical Chemistry Chemical Physics, Vol. 19, Issue 23 https://doi.org/10.1039/C7CP01045A	journal	January 2017
Dynamical properties of EMIM-SCN confined in a SiO ₂ matrix by means of ¹ H NMR relaxometry Kruk, Danuta; Wojciechowski, Milosz; Verma, Yogendra Lal Physical Chemistry Chemical Physics, Vol. 19, Issue 48 https://doi.org/10.1039/C7CP06174A	journal	January 2017
The gelation influence on diffusion and conductivity enhancement effect in renewable ionic gels based on a LMWG Bielejewski, M.; Rachocki, A.; Kaszyńska, J. Physical Chemistry Chemical Physics, Vol. 20, Issue 8 https://doi.org/10.1039/C7CP07740H	journal	January 2018
Linking the structures, free volumes, and properties of ionic liquid mixtures Brooks, Nicholas J.; Castiglione, Franca; Doherty, Cara M. Chemical Science, Vol. 8, Issue 9 https://doi.org/10.1039/C7SC01407D	journal	January 2017
Preparation and characterization of gel polymer electrolytes using poly(ionic liquids) and high lithium salt concentration ionic liquids Wang, Xiaoen; Zhu, Haijin; Girard, Gaetan M. A. Journal of Materials Chemistry A, Vol. 5, Issue 45 https://doi.org/10.1039/C7TA08233A	journal	January 2017
Single-ion conducting gel polymer electrolytes: design, preparation and application Deng, Kuirong; Zeng, Qingguang; Wang, Da Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/C9TA11178F	journal	January 2020
Insights into the translational and rotational dynamics of cations and anions in protic ionic liquids by means of NMR fast-field-cycling relaxometry Overbeck, Viviane; Schröder, Henning; Bonsa, Anne-Marie Physical Chemistry Chemical Physics, Vol. 23, Issue 4 https://doi.org/10.1039/D0CP05440B	journal	January 2021
Challenges in the development of advanced Li-ion batteries: a review Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01598b	journal	January 2011
In search of an optimized electrolyte for Na-ion batteries Ponrouch, Alexandre; Marchante, Elena; Courty, Matthieu Energy & Environmental Science, Vol. 5, Issue 9 https://doi.org/10.1039/c2ee22258b	journal	January 2012
Mechanistic insights into operational lithium–sulfur batteries by in situ X-ray diffraction and absorption spectroscopy Lowe, Michael A.; Gao, Jie; Abruña, Héctor D. RSC Advances, Vol. 4, Issue 35 https://doi.org/10.1039/c4ra01388c	journal	January 2014
Calcul des densités spectrales résultant d'un mouvement aléatoire de translation en relaxation par interaction dipolaire magnétique dans les liquides Ayant, Y.; Belorizky, E.; Aluzon, J. Journal de Physique, Vol. 36, Issue 10 https://doi.org/10.1051/jphys:019750036010099100	journal	January 1975
Supercapacitors: Review of Materials and Fabrication Methods Vangari, Manisha; Pryor, Tonya; Jiang, Li Journal of Energy Engineering, Vol. 139, Issue 2 https://doi.org/10.1061/(ASCE)EY.1943-7897.0000102	journal	June 2013
Spin Relaxation Processes in a Two‐Proton System Undergoing Anisotropic Reorientation Woessner, D. E. The Journal of Chemical Physics, Vol. 36, Issue 1 https://doi.org/10.1063/1.1732274	journal	January 1962
The Principles of Nuclear Magnetism Abragam, A.; Carr, H. Y. Physics Today, Vol. 14, Issue 11 https://doi.org/10.1063/1.3057238	journal	November 1961
Dynamic effects of pair correlation functions on spin relaxation by translational diffusion in liquids Hwang, Lian-Pin; Freed, Jack H. The Journal of Chemical Physics, Vol. 63, Issue 9 https://doi.org/10.1063/1.431841	journal	January 1975
Dynamic effects of pair correlation functions on spin relaxation by translational diffusion in liquids. II. Finite jumps and independent T ₁ processes Freed, Jack H. The Journal of Chemical Physics, Vol. 68, Issue 9 https://doi.org/10.1063/1.436302	journal	May 1978
The anomalous adsorbate dynamics at surfaces in porous media studied by nuclear magnetic resonance methods. The orientational structure factor and Lévy walks Zavada, Tatiana; Kimmich, Rainer The Journal of Chemical Physics, Vol. 109, Issue 16 https://doi.org/10.1063/1.477260	journal	October 1998
Determining diffusion coefficients of ionic liquids by means of field cycling nuclear magnetic resonance relaxometry Kruk, D.; Meier, R.; Rachocki, A. The Journal of Chemical Physics, Vol. 140, Issue 24 https://doi.org/10.1063/1.4882064	journal	June 2014
Rotational and translational dynamics and their relation to hydrogen bond lifetimes in an ionic liquid by means of NMR relaxation time experiments and molecular dynamics simulation Strate, Anne; Neumann, Jan; Overbeck, Viviane The Journal of Chemical Physics, Vol. 148, Issue 19 https://doi.org/10.1063/1.5011804	journal	May 2018
Structural analysis of ionic liquids with symmetric and asymmetric fluorinated anions Zhao, Man; Wu, Boning; Lall-Ramnarine, Sharon I. The Journal of Chemical Physics, Vol. 151, Issue 7 https://doi.org/10.1063/1.5111643	journal	August 2019
Liquid structure and dynamics in the choline acetate:urea 1:2 deep eutectic solvent Triolo, Alessandro; Di Pietro, Maria Enrica; Mele, Andrea The Journal of Chemical Physics, Vol. 154, Issue 24 https://doi.org/10.1063/5.0054048	journal	June 2021
High Coulombic efficiency aluminum-ion battery using an AlCl ₃ -urea ionic liquid analog electrolyte Angell, Michael; Pan, Chun-Jern; Rong, Youmin Proceedings of the National Academy of Sciences, Vol. 114, Issue 5 https://doi.org/10.1073/pnas.1619795114	journal	January 2017
Nuclear spin relaxation by translational diffusion in liquids and solids: high- and low-frequency limits Sholl, C. A. Journal of Physics C: Solid State Physics, Vol. 14, Issue 4 https://doi.org/10.1088/0022-3719/14/4/018	journal	February 1981
Relaxation Effects in Nuclear Magnetic Resonance Absorption Bloembergen, N.; Purcell, E. M.; Pound, R. V. Physical Review, Vol. 73, Issue 7 https://doi.org/10.1103/PhysRev.73.679	journal	April 1948
Nuclear Spin Relaxation by Translational Diffusion Torrey, H. C. Physical Review, Vol. 92, Issue 4 https://doi.org/10.1103/PhysRev.92.962	journal	November 1953
Relation of short-range and long-range lithium ion dynamics in glass-ceramics: Insights from Li 7 NMR field-cycling and field-gradient studies Haaks, Michael; Martin, Steve W.; Vogel, Michael Physical Review B, Vol. 96, Issue 10 https://doi.org/10.1103/PhysRevB.96.104301	journal	September 2017
Graphene as the electrode material in supercapacitors Wu, H. P.; He, D. W.; Wang, Y. S. 2010 8th International Vacuum Electron Sources Conference and Nanocarbon https://doi.org/10.1109/IVESC.2010.5644267	conference	October 2010
Calculation of Activation Energy of Ionic Conductivity in Silica Glasses by Classical Methods Anderson, O. L.; Stuart, D. A. Journal of the American Ceramic Society, Vol. 37, Issue 12 https://doi.org/10.1111/j.1151-2916.1954.tb13991.x	journal	December 1954
Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L. Science Advances, Vol. 2, Issue 7 https://doi.org/10.1126/sciadv.1600320	journal	July 2016
MATERIALS SCIENCE: Electrochemical Capacitors for Energy Management Miller, J. R.; Simon, P. Science, Vol. 321, Issue 5889 https://doi.org/10.1126/science.1158736	journal	August 2008
Poly(ionic liquid)s: Synthesis, properties, and application Shaplov, A. S.; Ponkratov, D. O.; Vygodskii, Y. S. Polymer Science Series B, Vol. 58, Issue 2 https://doi.org/10.1134/S156009041602007X	journal	March 2016
The Limiting Behavior of a One-Dimensional Random Walk in a Random Medium Sinai, Ya. G. Theory of Probability & Its Applications, Vol. 27, Issue 2 https://doi.org/10.1137/1127028	journal	January 1983
Aluminum Ion Species Transport in Pure and Additive Modulated Deep Eutectic Solvents (DES) Electrolytes Paterno, Domenec; Suarez, Sophia ECS Transactions, Vol. 98, Issue 10 https://doi.org/10.1149/09810.0401ecst	journal	September 2020
The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries Aurbach, Doron Journal of The Electrochemical Society, Vol. 142, Issue 9 https://doi.org/10.1149/1.2048658	journal	January 1995
Reduction Reactions of Carbonate Solvents for Lithium Ion Batteries Seo, D. M.; Chalasani, D.; Parimalam, B. S. ECS Electrochemistry Letters, Vol. 3, Issue 9 https://doi.org/10.1149/2.0021409eel	journal	January 2014
Supercapacitor Electrodes Produced through Evaporative Consolidation of Graphene Oxide-Water-Ionic Liquid Gels Pope, Michael A.; Korkut, Sibel; Punckt, Christian Journal of The Electrochemical Society, Vol. 160, Issue 10 https://doi.org/10.1149/2.017310jes	journal	January 2013
The Development and Future of Lithium Ion Batteries Blomgren, George E. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0251701jes	journal	December 2016
Investigation of Dynamics in BMIM TFSA Ionic Liquid through Variable Temperature and Pressure NMR Relaxometry and Diffusometry Pilar, Kartik; Rua, Armando; Suarez, Sophia N. Journal of The Electrochemical Society, Vol. 164, Issue 8 https://doi.org/10.1149/2.0301708jes	journal	January 2017
Insights into the Properties of Deep Eutectic Solvent Based on Reline for Ga-Controllable CIGS Solar Cell in One-Step Electrodeposition Zhang, Yongzheng; Han, Junfeng; Liao, Cheng Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0611613jes	journal	January 2016
Analysis of Degradation of Si/Carbon\|\|LiNi _0.5 Mn _0.3 Co _0.2 O ₂ Full Cells: Effect of Prelithiation Rezqita, Arlavinda; Kathribail, Anish-Raj; Kahr, Jürgen Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0671903jes	journal	January 2019
Exploring the Role of Phosphate Structural Distortions on the Sodium Jump Dynamics in NASICON Phases Alam, Todd M.; Bell, Nelson; Wheeler, Jill MRS Proceedings, Vol. 1773 https://doi.org/10.1557/opl.2015.522	journal	January 2015
Microscopic Structural and Dynamic Features in Triphilic Room Temperature Ionic Liquids Lo Celso, Fabrizio; Appetecchi, Giovanni B.; Simonetti, Elisabetta Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00285	journal	May 2019
High Lithium-Ion-Conducting NASICON-Type Li1+xAlxGeyTi2−x−y(PO4)3 Solid Electrolyte Xuefu, Shang; Nemori, Hiroyoshi; Mitsuoka, Shigehi Frontiers in Energy Research, Vol. 4 https://doi.org/10.3389/fenrg.2016.00012	journal	April 2016
Relationship between Translational and Rotational Dynamics of Alkyltriethylammonium-Based Ionic Liquids Kruk, Danuta; Masiewicz, Elzbieta; Lotarska, Sylwia International Journal of Molecular Sciences, Vol. 23, Issue 3 https://doi.org/10.3390/ijms23031688	journal	February 2022
Dynamics of Ionic Liquids in Confinement by Means of NMR Relaxometry—EMIM-FSI in a Silica Matrix as an Example Kruk, Danuta; Wojciechowski, Milosz; Florek-Wojciechowska, Malgorzata Materials, Vol. 13, Issue 19 https://doi.org/10.3390/ma13194351	journal	September 2020
Insights into the Effect of Lithium Doping on the Deep Eutectic Solvent Choline Chloride:Urea de Araujo Lima e. Souza, Giselle; Di Pietro, Maria Enrica; Castiglione, Franca Materials, Vol. 15, Issue 21 https://doi.org/10.3390/ma15217459	journal	October 2022

Similar Records

Broadband NMR relaxometry of electrolytes for energy storage

Journal Article · Thu Feb 17 23:00:00 EST 2022 · Chemical Physics Reviews · OSTI ID:1860623

Molecular-level insights into structure and dynamics in ionic liquids and polymer gel electrolytes

Journal Article · Fri Jan 22 23:00:00 EST 2021 · Journal of Molecular Liquids · OSTI ID:1853227

Related Subjects

25 ENERGY STORAGE
NMR fast field cycling (FFC)
NMR spin-lattice relaxation time
electrolytes

Nuclear Magnetic Resonance Relaxation Pathways in Electrolytes for Energy Storage

Citation Formats

References (181)

Similar Records

Related Subjects