P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries

Yuan, Siqi; Yu, Lei; Qian, Guannan; Xie, Yingying; Guo, Penghui; Cui, Guijia; Ma, Jun; Ren, Xiangyu; Xu, Zhixin; Lee, Sang-Jun; Lee, Jun-Sik; Liu, Yijin; Ren, Yang; Li, Linsen; Tan, Guoqiang; Liao, Xiaozhen

doi:10.1021/acs.nanolett.2c04465

P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries

Journal Article · Wed Feb 22 00:00:00 EST 2023 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.2c04465· OSTI ID:2310287

Yuan, Siqi ^[1]; Yu, Lei ^[2]; ^[3]; Xie, Yingying ^[4]; Guo, Penghui ^[5]; Cui, Guijia ^[6]; Ma, Jun ^[1]; Ren, Xiangyu ^[1]; Xu, Zhixin ^[1]; ^[3]; ^[3]; ^[3]; ^[7]; ^[1]; ^[5]; ^[1]

Shanghai Jiao Tong Univ. (China)
Nanjing Univ. of Information Science and Technology (China). Key Lab. for Soft Chemistry and Functional Materials
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Beijing Institute of Technology (China)
Shanghai SodaEn New Energy Technology (China)
City Univ. of Hong Kong, Kowloon (Hong Kong)

P2-Na_0.67Ni_0.33Mn_0.67O₂ represents a promising cathode for Na-ion batteries, but it suffers from severe structural degradation upon storing in a humid atmosphere and cycling at a high cutoff voltage. Here we propose an in situ construction to achieve simultaneous material synthesis and Mg/Sn cosubstitution of Na_0.67Ni_0.33Mn_0.67O₂ via one-pot solid-state sintering. Here, the materials exhibit superior structural reversibility and moisture insensitivity. In-operando XRD reveals an essential correlation between cycling stability and phase reversibility, whereas Mg substitution suppressed the P2–O2 phase transition by forming a new Z phase, and Mg/Sn cosubstitution enhanced the P2–Z transition reversibility benefiting from strong Sn–O bonds. DFT calculations disclosed high chemical tolerance to moisture, as the adsorption energy to H₂O was lower than that of the pure Na_0.67Ni_0.33Mn_0.67O₂. A representative Na_0.67Ni_0.23Mg_0.1Mn_0.65Sn_0.02O₂ cathode exhibits high reversible capacities of 123 mAh g^–1 (10 mA g^–1), 110 mAh g^–1 (200 mA g^–1), and 100 mAh g^–1 (500 mA g^–1) and a high capacity retention of 80% (500 mA g^–1, 500 cycles).

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC02-76SF00515

OSTI ID:: 2310287

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 5 Vol. 23; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
P2-type cathode
cosubstitution
reversible phase transition
sodium-ion batteries
solid-state synthesis

P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries

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