Separation of Actinides from Lanthanides in Molten Fluorides by the Modulated-Current Electrolysis

Journal Article · Sat Jul 01 04:00:00 EDT 2017 · Transactions of the American Nuclear Society

OSTI ID:23047374

Straka, Martin; Szatmary, Lorant ^[1]

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1. UJV Rez, a.s. Husinec-Rez 130, CZ-25068, Czech Republic (Czech Republic)

Recently, the Molten Salt Reactor (MSR) is taking a renewed attraction as one of the reactor systems highlighted by the Generation IV International Forum. It is a non-classical (liquid fuel) system which can be operated as a breeder within the {sup 232}Th-{sup 233}U fuel cycle with the very interesting breeding factor. The necessary precondition for its proper functionality is the online reprocessing within the MSR's fuel cycle. A lot of effort is given to the development of the on-line pyrochemical reprocessing technology. Among the processes considered to be suitable for this process, the electrochemical separations are highlighted. Within this context, it is necessary to study electrochemical behavior of both fissile material and fission products in the molten salt systems and to develop the processes of their extraction from the system at various stages of the whole cycle. In this contribution, the study of the electrochemical separation of U from Gd in the LiF-CaF{sub 2} molten system by the modulated current electrolysis is presented. The study of MSR-related electrochemistry will continue as a part of the new Czech MSR R and D program. The knowledge of the electrochemical behavior of actinides and lanthanides in molten fluorides is necessary to the development of any electrochemical separation process. In our previous work, electrochemical characteristics of uranium, thorium, as well as that of several lanthanides, were measured in LiF-BeF{sub 2} (the basic melt considered for the MSR concept) and Be-free melts (LiF-NaFKF, LiF-NaF, LiF-CaF{sub 2}), and added to available literature data. If the fluoride carrier melt is electrochemically stable enough, it is possible to deposit the element of interest in its basic, metallic state (e.g. uranium in all types of fluoride melts tested) by the electrolysis. In the case of insufficient electrochemical stability of the fluoride melt in which the actinides and lanthanides are dissolved for the experiments, it is possible to use a reactive working electrode made of a material which creates alloys with the element to be deposited. An alloying reaction can shift the deposition potential in a favorable direction and therefore achieve the separation of an element from the system. The use of reactive electrode can also improve the adhesion of the deposit. When two or more electroactive species are present in the system at the same time, the efficiency of their separation by an electrolysis depends on how different the deposition potentials of these two species are. If we input certain modulation to the electrolytic current, we can improve overall result of an electrolytic experiment.

• OSTI ID: 23047374
• Journal Information: Transactions of the American Nuclear Society, Journal Name: Transactions of the American Nuclear Society Vol. 116; ISSN 0003-018X
• Country of Publication: United States
• Language: English

Related Subjects

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
BERYLLIUM FLUORIDES
CALCIUM FLUORIDES
DEPOSITION
DEPOSITS
ELECTROCHEMISTRY
ELECTROLYSIS
FISSILE MATERIALS
FISSION PRODUCTS
FUEL CYCLE
FUEL SYSTEMS
LIQUID FUELS
LITHIUM FLUORIDES
MODULATION
MOLTEN SALT REACTORS
MOLTEN SALTS
PYROCHEMICAL REPROCESSING
RARE EARTHS
SODIUM FLUORIDES
THORIUM
URANIUM