Large adiabatic temperature change and magnetic frustration in triangular lattice antiferromagnet Dy2IrSi3

Chakraborty, Sudip; Gupta, Shuvankar; Pakhira, Santanu; Dan, Shovan; Biswas, Anis; Mudryk, Yaroslav; Mazumdar, Chandan

doi:10.1016/j.jallcom.2024.173652

Large adiabatic temperature change and magnetic frustration in triangular lattice antiferromagnet Dy₂IrSi₃

Journal Article · Wed Jan 24 00:00:00 EST 2024 · Journal of Alloys and Compounds

DOI:https://doi.org/10.1016/j.jallcom.2024.173652· OSTI ID:2299900

Chakraborty, Sudip ^[1]; Gupta, Shuvankar ^[1]; Pakhira, Santanu ^[2]; Dan, Shovan ^[3]; Biswas, Anis ^[2]; Mudryk, Yaroslav ^[2]; Mazumdar, Chandan ^[1]

Saha Institute of Nuclear Physics, Kolkata (India)
Ames Laboratory, and Iowa State University, Ames, IA (United States)
Tata Institute of Fundamental Research, Bombay (India)

While previous studies reveal that the formation of polycrystalline R₂TX₃ (R = rare-earth, T = transition metal, X = p-block element) type compounds with T = Ir and Co is not achievable without deliberate introduction of atomic vacancies of Ir/Co and Si, here we report successful synthesis of Dy₂IrSi₃ with fully stoichiometric ratio of constituent elements. An antiferromagnetic transition is manifested in the compound at 6.6 K where only about 50 % of Dy spins take part, while the rest remain in highly frustrated state due to edge-sharing triangular lattice geometry. The magnetic frustration is conclusively probed through magnetization, heat capacity and magnetocaloric study and the frustration parameter (f = |θ_p|/T_N, θ_p, T_N being Curie-Weiss and Néel temperatures, respectively) in this case is as large as ~ 3. An additional cluster-glass type transition at ~2.8 K observed in this system has likely been originated due to this magnetic frustration. The magnetocaloric effect reveals an adiabatic temperature change of ~7.5 K for 70 kOe magnetic field, which is one of the largest values reported in intermetallic compounds.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2299900

Alternate ID(s):: OSTI ID: 2369842

Report Number(s):: IS-J--11,262

Journal Information:: Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Vol. 981; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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