A Chemistry Based Criticality Safety Evaluation of the HM-Process Mixer Settlers

Journal Article · Wed Jun 15 04:00:00 EDT 2016 · Transactions of the American Nuclear Society

OSTI ID:22991941

Stover, Tracy; Kessler, Stephen ^[1]

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1. Savannah River Nuclear Solutions, LLC, Savannah River Site, Aiken, SC 29803 (United States)

The criticality safety of Savannah River Site's H Canyon two cycle uranium extraction and purification process, called the HM process, is examined. Explicit Monte Carlo models of the multi-stage mixer-settlers are generated for the first time using the KENO-VI module of the SCALE 6.1 code package and spanning normal operating conditions and a wide range of potential upset conditions with stagewise compositions based directly on SEPHIS Mod-4 chemistry models of the same conditions. To achieve industrial scale processing, mixer-settlers are often not geometrically favorable to prevent criticality so other means must be used for criticality safety, namely control of fissile concentration and mass. Historically, the worst case upset is a reflux condition resulting from a stream flow rate, temperature, or composition that is off from the normal operating conditions. A reflux is considered to be the state in which the fissile material is not proceeding in the desired direction, i.e. is stripping rather than extracting or vice versa. The criticality safety analyses which set the current operational limits were conducted many years ago with less sophisticated codes and only loosely tied criticality to chemistry. Those analyses conservatively assumed that a reflux changed the behavior of the mixer-settler such that the fissile content collected continuously in only three stages of the mixer-settler, at a rate based on the SEPHIS modeling, until criticality occurred. This implies that under some condition the distribution coefficient of the fissile material either goes to infinity or zero, which is not physically achievable. In such a scenario, the operator would have some amount of time to react and correct the problem before sufficient fissile material built up in the mixer-settler and caused a criticality. In reality, an upset in a stream would cause the process to transition to a new, though undesired, equilibrium state of operation. The distribution coefficients would change, but would not diverge. In this work, aqueous and organic streams are modeled for both the mixer and the settler region of each stage of each bank using chemical distribution data from SEPHIS and solving the chemical equations for a wide range of operational parameters spanning normal and upset conditions. Conservative assumptions are made regarding enrichment and reflection and the whole bank multiplication factor is evaluated using discrete stage-wise compositions. (authors)

• OSTI ID: 22991941
• Journal Information: Transactions of the American Nuclear Society, Journal Name: Transactions of the American Nuclear Society Journal Issue: 1 Vol. 114; ISSN 0003-018X
• Country of Publication: United States
• Language: English

Related Subjects

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
42 ENGINEERING
CRITICALITY
EXTRACTION
FISSILE MATERIALS
MIXER-SETTLERS
MONTE CARLO METHOD
MULTIPLICATION FACTORS
SAFETY ANALYSIS
URANIUM