Synthesis and structure of 6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine and its N-nitro derivatives

Journal Article · Mon Oct 15 04:00:00 EDT 2018 · Russian Chemical Bulletin

DOI:https://doi.org/10.1007/S11172-018-2303-4· OSTI ID:22943436

Shastin, A. V.; Lagodzinskaya, G. V.; Shilov, G. V.; Korchagin, D. V.; Glushakova, N. M.; Malygina, V. S.; Kosilko, V. P.; Lodygina, V. P.; Aldoshin, S. M. ^[1]

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1. Russian Academy of Sciences, Institute of Problems of Chemical Physics (Russian Federation)

Methods were developed for the synthesis of 6-azido-2,4-bis(2,2,2-trinitroethylamino)- 1,3,5-triazine and its N-nitro derivatives (6-azido-2,4-bis(2,2,2-trinitroethyl)nitramino-1,3,5-triazine and 6-azido-2-(2,2,2-trinitroethylamino)-4-(2,2,2-trinitroethyl)nitramino-1,3,5-triazine) containing combinations of azido, trinitroethyl, and nitramine groups. These compounds are of interest as components of energetic composites. The molecular and crystal structures of 6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine and 6-azido-2,4-bis(2,2,2-trinitroethyl) nitramino-1,3,5-triazine were studied by X-ray diffraction and NMR spectroscopy.

• OSTI ID: 22943436
• Journal Information: Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 10 Vol. 67; ISSN RCBUEY; ISSN 1066-5285
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CRYSTAL STRUCTURE
NITRATION
NUCLEAR MAGNETIC RESONANCE
SPECTROSCOPY
SYNTHESIS
TRIAZINES
X-RAY DIFFRACTION