Mercury derivatives of polyhedral boranes, carboranes, and metallacarboranes
Journal Article
·
· Russian Chemical Bulletin
- Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
The review concerns the synthesis, structure, and chemical transformations of mercury derivatives of various polyhedral boron hydrides (carboranes, metallacarboranes, and boranes) and covers a period of time since the pioneering studies of Prof. V. I. Bregadze on chemistry of C- and B-substituted derivatives of icosahedral carboranes C{sub 2}B{sub 10}H{sub 12} up to date. The emphasis is placed on recent results obtained in this field, in particular, Hg-promoted substitution in nido-carboranes as well as the synthesis and properties of mercury derivatives of monocarbon carborane anion [CB{sub 11}H{sub 12}]{sup –}.
- OSTI ID:
- 22943297
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 2 Vol. 68; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
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