NO Reduction with CO on Low‐loaded Platinum‐group Metals (Rh, Ru, Pd, Pt, and Ir) Atomically Dispersed on Ceria

Tian, Jinshu; Khivantsev, Konstantin; Lu, Yubing; Xue, Sichuang; Zhang, Zihao; Szanyi, János; Wang, Yong

doi:10.1002/cctc.202301227

NO Reduction with CO on Low‐loaded Platinum‐group Metals (Rh, Ru, Pd, Pt, and Ir) Atomically Dispersed on Ceria

Journal Article · Thu Feb 08 04:00:00 EST 2024 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.202301227· OSTI ID:2294133

Tian, Jinshu ^[1]; ^[2]; ^[2]; ^[2]; Zhang, Zihao ^[3]; ^[2]; Wang, Yong ^[3]

Pacific Northwest National Laboratory Richland Washington 99354 United States, Present address: College of Chemical Engineering Zhejiang University of Technology Hangzhou Zhejiang 310014 China
Pacific Northwest National Laboratory Richland Washington 99354 United States
Pacific Northwest National Laboratory Richland Washington 99354 United States, The Gene and Linda Voiland School of Chemical Engineering and Bioengineering Washington State University Pullman Washington 99164 United States

Abstract

Low‐loaded platinum‐group single‐atom catalysts on CeO ₂ (M ₁ /CeO ₂ ) were synthesized via high‐temperature atom trapping (AT) and tested for the NO+CO reaction under dry and wet conditions. The activity of these catalysts for NO+CO reaction follows the order Rh>Pd≈Ru>Pt>Ir. For Rh, Ru, and Pd single‐atom catalysts, the N ₂ O byproduct is formed but not clearly observed in Ir and Pt cases, which may result from the higher reaction temperature (>200 °C) required for Pt and Ir catalysts. The presence of water can promote the activity of these M ₁ /CeO ₂ catalysts for the NO+CO reaction. Under wet conditions, significant NH ₃ formation occurred during the reaction, which is due to the co‐existence of water‐gas‐shift reaction on these catalysts. Compared with Pt, Pd and Ir, the Rh and Ru single‐atom catalysts show higher selectivity to NH ₃ species, resulting from the hydride species on the surface. Among all tested catalysts, Ru ₁ /CeO ₂ shows the highest production of ammonia and highest CO conversion due to excellent water‐gas‐shift activity, whereas Pd ₁ /CeO ₂ shows lowest ammonia production. Rh ₁ /CeO ₂ shows the best low temperature NO reduction activity among all tested catalysts.

View Journal Article

Sponsoring Organization:: USDOE

OSTI ID:: 2294133

Alternate ID(s):: OSTI ID: 2335939

Journal Information:: ChemCatChem, Journal Name: ChemCatChem Journal Issue: 7 Vol. 16; ISSN 1867-3880

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (38)

Maximum Noble-Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum Bruix, Albert; Lykhach, Yaroslava; Matolínová, Iva Angewandte Chemie International Edition, Vol. 53, Issue 39 https://doi.org/10.1002/anie.201402342	journal	June 2014
Economizing on Precious Metals in Three‐Way Catalysts: Thermally Stable and Highly Active Single‐Atom Rhodium on Ceria for NO Abatement under Dry and Industrially Relevant Conditions** Khivantsev, Konstantin; Vargas, Carlos Garcia; Tian, Jinshu Angewandte Chemie International Edition, Vol. 60, Issue 1 https://doi.org/10.1002/anie.202010815	journal	October 2020
C−N Coupling through Hydroaminoalkylation on a Single‐Atom Rh Heterogeneous Catalyst Li, Yuting; Tang, Yu; Tao, Franklin (Feng) Angewandte Chemie International Edition, Vol. 62, Issue 15 https://doi.org/10.1002/anie.202214332	journal	March 2023
Stability of kinetic parameters of Co₃O₄/CeO₂ catalyzed methane combustion Nasr, Somaye; Hayes, Robert E.; Semagina, Natalia The Canadian Journal of Chemical Engineering, Vol. 99, Issue 12 https://doi.org/10.1002/cjce.24054	journal	March 2021
Ionic Dispersion of Pt and Pd on CeO2 by Combustion Method: Effect of Metal–Ceria Interaction on Catalytic Activities for NO Reduction and CO and Hydrocarbon Oxidation Bera, Parthasarathi; Patil, K. C.; Jayaram, V. Journal of Catalysis, Vol. 196, Issue 2 https://doi.org/10.1006/jcat.2000.3048	journal	December 2000
NO Reduction Over Noble Metal Ionic Catalysts Bera, Parthasarathi; Hegde, M. S. Catalysis Surveys from Asia, Vol. 15, Issue 3 https://doi.org/10.1007/s10563-011-9120-1	journal	April 2011
Single-atom site catalysts for environmental catalysis Zhang, Ningqiang; Ye, Chenliang; Yan, Han Nano Research, Vol. 13, Issue 12 https://doi.org/10.1007/s12274-020-2994-3	journal	August 2020
The catalytic chemistry of nitric oxide Kobylinski, Thaddeus P.; Taylor, Brian W. Journal of Catalysis, Vol. 33, Issue 3 https://doi.org/10.1016/0021-9517(74)90284-X	journal	June 1974
High rates of NO and N2O reduction by CO, CO and hydrocarbon oxidation by O2 over nano crystalline Ce0.98Pd0.02O2−δ: Catalytic and kinetic studies Roy, Sounak; Marimuthu, A.; Hegde, M. S. Applied Catalysis B: Environmental, Vol. 71, Issue 1-2 https://doi.org/10.1016/j.apcatb.2006.08.005	journal	February 2007
Atomically Dispersed Dopants for Stabilizing Ceria Surface Area Alcala, Ryan; DeLaRiva, Andrew; Peterson, Eric J. Applied Catalysis B: Environmental, Vol. 284 https://doi.org/10.1016/j.apcatb.2020.119722	journal	May 2021
Co-existence of atomically dispersed Ru and Ce3+ sites is responsible for excellent low temperature N2O reduction activity of Ru/CeO2 Song, Inhak; Wang, Yong; Szanyi, János Applied Catalysis B: Environmental, Vol. 343 https://doi.org/10.1016/j.apcatb.2023.123487	journal	April 2024
Pd ion substituted CeO2: A superior de-NO catalyst to Pt or Rh metal ion doped ceria Roy, Sounak; Hegde, M. S. Catalysis Communications, Vol. 9, Issue 5 https://doi.org/10.1016/j.catcom.2007.09.019	journal	March 2008
Promotive effects of Ba addition on lean NOx reduction by CO over IrRu/Al2O3 catalyst Song, Ji Hwan; Park, Dong Chan; You, Young-Woo Chemical Engineering Journal, Vol. 452 https://doi.org/10.1016/j.cej.2022.139331	journal	January 2023
Pd and Pd-Pt catalysts supported on SnO2 and γ-Al2O3: Kinetic studies of wet lean methane combustion Kumar, Roshni Sajiv; Hayes, Robert E.; Semagina, Natalia Chemical Engineering Science, Vol. 269 https://doi.org/10.1016/j.ces.2023.118488	journal	April 2023
Enhanced selective cleavage of aryl C-O bond by atomically dispersed Pt on α-MoC for hydrodeoxygenation of anisole Lin, Hongqiao; Sun, Ping; Xu, Yuanjie Molecular Catalysis, Vol. 531 https://doi.org/10.1016/j.mcat.2022.112652	journal	October 2022
Oscillatory behavior of Ni/TiO2 catalyst during partial oxidation of methane: Understanding the role of strong metal-support interaction Yang, Hua; An, Zemin; Xu, Yuanjie Molecular Catalysis, Vol. 547 https://doi.org/10.1016/j.mcat.2023.113374	journal	August 2023
Elucidation of the Active Sites in Single-Atom Pd ₁ /CeO ₂ Catalysts for Low-Temperature CO Oxidation Jiang, Dong; Wan, Gang; García-Vargas, Carlos E. ACS Catalysis, Vol. 10, Issue 19 https://doi.org/10.1021/acscatal.0c02480	journal	August 2020
Improved Pd/CeO₂ Catalysts for Low-Temperature NO Reduction: Activation of CeO₂ Lattice Oxygen by Fe Doping Zhang, Long; Spezzati, Giulia; Muravev, Valery ACS Catalysis, Vol. 11, Issue 9 https://doi.org/10.1021/acscatal.1c00564	journal	April 2021
Mechanistic Aspects of the Water–Gas Shift Reaction on Isolated and Clustered Au Atoms on CeO ₂ (110): A Density Functional Theory Study Song, Weiyu; Hensen, Emiel J. M. ACS Catalysis, Vol. 4, Issue 6 https://doi.org/10.1021/cs401206e	journal	April 2014
Remarkable Performance of Ir ₁ /FeO _x Single-Atom Catalyst in Water Gas Shift Reaction Lin, Jian; Wang, Aiqin; Qiao, Botao Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja408574m	journal	October 2013
Single Ru(II) Ions on Ceria as a Highly Active Catalyst for Abatement of NO Khivantsev, Konstantin; Jaegers, Nicholas R.; Aleksandrov, Hristiyan A. Journal of the American Chemical Society, Vol. 145, Issue 9 https://doi.org/10.1021/jacs.2c09873	journal	February 2023
Higher Catalytic Activity of Nano-Ce_1-_x_-_yTi_xPd_yO_2-_δCompared to Nano-Ce_1-_xPd_xO_2-_δfor CO Oxidation and N₂O and NO Reduction by CO: Role of Oxide Ion Vacancy Baidya, Tinku; Marimuthu, A.; Hegde, M. S. The Journal of Physical Chemistry C, Vol. 111, Issue 2 https://doi.org/10.1021/jp064565e	journal	November 2006
CO Oxidation and NO Reduction on Metal Surfaces: Density Functional Theory Investigations Liu, Zhi-Pan; Hu, P. Topics in Catalysis, Vol. 28, Issue 1-4 https://doi.org/10.1023/B:TOCA.0000024335.88459.81	journal	April 2004
Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen Pereira-Hernández, Xavier Isidro; DeLaRiva, Andrew; Muravev, Valery Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09308-5	journal	March 2019
Towards dense single-atom catalysts for future automotive applications Beniya, Atsushi; Higashi, Shougo Nature Catalysis, Vol. 2, Issue 7 https://doi.org/10.1038/s41929-019-0282-y	journal	July 2019
The impact of automotive catalysis on the United Nations sustainable development goals Wang, Aiyong; Olsson, Louise Nature Catalysis, Vol. 2, Issue 7 https://doi.org/10.1038/s41929-019-0318-3	journal	July 2019
Highly durable metal ensemble catalysts with full dispersion for automotive applications beyond single-atom catalysts Jeong, Hojin; Kwon, Ohmin; Kim, Beom-Sik Nature Catalysis, Vol. 3, Issue 4 https://doi.org/10.1038/s41929-020-0427-z	journal	February 2020
Reaction product-driven restructuring and assisted stabilization of a highly dispersed Rh-on-ceria catalyst Yan, George; Tang, Yu; Li, Yuting Nature Catalysis, Vol. 5, Issue 2 https://doi.org/10.1038/s41929-022-00741-2	journal	February 2022
Nanophase-separated Ni₃Nb as an automobile exhaust catalyst Tanabe, Toyokazu; Imai, Tsubasa; Tokunaga, Tomoharu Chemical Science, Vol. 8, Issue 5 https://doi.org/10.1039/C6SC05473K	journal	January 2017
Bringing attention to metal (un)availability in encapsulated catalysts Habibi, A. H.; Hayes, R. E.; Semagina, N. Catalysis Science & Technology, Vol. 8, Issue 3 https://doi.org/10.1039/C7CY01919J	journal	January 2018
Design of Pd-based pseudo-binary alloy catalysts for highly active and selective NO reduction Jeon, Jaewan; Kon, Ken-ichi; Toyao, Takashi Chemical Science, Vol. 10, Issue 15 https://doi.org/10.1039/C8SC05496G	journal	January 2019
A Cu–Pd single-atom alloy catalyst for highly efficient NO reduction Xing, Feilong; Jeon, Jaewan; Toyao, Takashi Chemical Science, Vol. 10, Issue 36 https://doi.org/10.1039/C9SC03172C	journal	January 2019
Strong metal–support interactions in Pd/Co₃O₄ catalyst in wet methane combustion: in situ X-ray absorption study Barrett, William; Nasr, Somaye; Shen, Jing Catalysis Science & Technology, Vol. 10, Issue 13 https://doi.org/10.1039/D0CY00465K	journal	January 2020
Ligand-coordinated Ir single-atom catalysts stabilized on oxide supports for ethylene hydrogenation and their evolution under a reductive atmosphere Chen, Linxiao; Ali, Iyad S.; Sterbinsky, George E. Catalysis Science & Technology, Vol. 11, Issue 6 https://doi.org/10.1039/D0CY01132K	journal	January 2021
Why Rhodium in Automotive Three-Way Catalysts? Shelef, M.; Graham, G. W. Catalysis Reviews, Vol. 36, Issue 3 https://doi.org/10.1080/01614949408009468	journal	August 1994
Activation of surface lattice oxygen in single-atom Pt/CeO ₂ for low-temperature CO oxidation Nie, Lei; Mei, Donghai; Xiong, Haifeng Science, Vol. 358, Issue 6369 https://doi.org/10.1126/science.aao2109	journal	December 2017
Recent advances in gasoline three-way catalyst formulation: A review Rood, Shawn; Eslava, Salvador; Manigrasso, Alexis Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering https://doi.org/10.1177/0954407019859822	journal	June 2019
Identifying the Metallic State of Rh Catalyst on Boron Nitride during Partial Oxidation of Methane by Using the Product Molecule as the Infrared Probe Yao, Jikang; Xu, Yuanjie; Yang, Hua Catalysts, Vol. 12, Issue 10 https://doi.org/10.3390/catal12101146	journal	September 2022

Similar Records

Economizing on Precious Metals in Three‐Way Catalysts: Thermally Stable and Highly Active Single‐Atom Rhodium on Ceria for NO Abatement under Dry and Industrially Relevant Conditions**

Journal Article · Wed Oct 28 00:00:00 EDT 2020 · Angewandte Chemie · OSTI ID:1786159

Economizing on Precious Metals in Three‐Way Catalysts: Thermally Stable and Highly Active Single‐Atom Rhodium on Ceria for NO Abatement under Dry and Industrially Relevant Conditions**

Journal Article · Wed Oct 28 00:00:00 EDT 2020 · Angewandte Chemie (International Edition) · OSTI ID:1786202

NO Reduction with CO on Low‐loaded Platinum‐group Metals (Rh, Ru, Pd, Pt, and Ir) Atomically Dispersed on Ceria

Citation Formats

References (38)

Similar Records

Related Subjects