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Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction

Patent ·
OSTI ID:2293840

Single-stage and multi-stage systems and methods for the recovery of critical elements in substantially pure form from lithium ion batteries are provided. The systems and methods include supported membrane solvent extraction using an immobilized organic phase within the pores of permeable hollow fibers. The permeable hollow fibers are contacted by a feed solution on one side, and a strip solution on another side, to provide the simultaneous extraction and stripping of elements from dissolved lithium ion cathode materials, while rejecting other elements from the feed solution. The single- and multi-stage systems and methods can selectively recover cobalt, manganese, nickel, lithium, aluminum and other elements from spent battery cathodes and are not limited by equilibrium constraints as compared to traditional solvent extraction processes.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
Assignee:
UT-Battelle, LLC (Oak Ridge, TN)
Patent Number(s):
11,811,035
Application Number:
16/884,189
OSTI ID:
2293840
Country of Publication:
United States
Language:
English

References (2)

Lithium Recovery from Aqueous Resources and Batteries: A Brief Review journal April 2018
Separation of Co(II) and Li(I) with Cyanex 272 using hollow fiber supported liquid membrane: A comparison with flat sheet supported liquid membrane and dispersive solvent extraction process journal July 2015

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