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Stereolithography additive manufacturing of photoaligned liquid crystal elastomers

Patent ·
OSTI ID:2293779
A method of forming a three-dimensional structure of liquid crystal (LC) elastomers includes contacting a resin layer of LC oligomers with a layer of photoalignment material, and exposing a portion of photoalignment material to light for aligning the portion of photoalignment material in a first orientation. The LC oligomers adjacent the illuminated portion of photoalignment material align to the first orientation of the illuminated portion. The portion of aligned LC oligomers of the resin layer are cured. Operations for forming additional layers include creating a relative movement of the resin layer away from the photoalignment material, contacting another resin layer with the photoalignment material, and exposing another portion of photoalignment material to light for aligning the photoalignment material in a different orientation. The LC oligomers adjacent the illuminated portion of photoalignment material align to the different orientation, and the portion of aligned LC oligomers of the resin layer are cured.
Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-07NA27344
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Number(s):
11,794,406
Application Number:
17/848,309
OSTI ID:
2293779
Country of Publication:
United States
Language:
English

References (23)

Photoalignment of an Azobenzene-Based Chromonic Liquid Crystal Dispersed in Triacetyl Cellulose: Single-Layer Alignment Films with an Exceptionally High Order Parameter journal May 2015
4D Printed Actuators with Soft-Robotic Functions journal December 2017
3D Printable and Reconfigurable Liquid Crystal Elastomers with Light‐Induced Shape Memory via Dynamic Bond Exchange journal October 2019
Synthesis and alignment of liquid crystalline elastomers journal September 2021
Voxelated liquid crystal elastomers journal February 2015
Voxelated soft matter via multimaterial multinozzle 3D printing journal November 2019
3D Printing of Liquid Crystal Elastomeric Actuators with Spatially Programed Nematic Order journal January 2018
Orientation kinetics of thermotropic main-chain liquid-crystalline polymers in a magnetic field journal January 1991
Remotely Controlled, Reversible, On-Demand Assembly and Reconfiguration of 3D Mesostructures via Liquid Crystal Elastomer Platforms journal February 2021
Designing bioinspired composite reinforcement architectures via 3D magnetic printing journal October 2015
In situ, spatially variable photoalignment of liquid crystals inside a glass cell using brilliant yellow conference May 2022
4D-Printable Liquid Metal–Liquid Crystal Elastomer Composites journal December 2020
Multiresponsive polymeric microstructures with encoded predetermined and self-regulated deformability journal December 2018
4D Printing of a Liquid Crystal Elastomer with a Controllable Orientation Gradient journal November 2019
3D Microstructures of Liquid Crystal Networks with Programmed Voxelated Director Fields journal August 2020
Ultralight, ultrastiff mechanical metamaterials journal June 2014
Liquid-induced topological transformations of cellular microstructures journal April 2021
Voxelated Molecular Patterning in Three-Dimensional Freeforms journal July 2019
Molecularly-Engineered, 4D-Printed Liquid Crystal Elastomer Actuators journal November 2018
Liquid Crystalline Elastomers as Actuators and Sensors journal May 2010
Printing ferromagnetic domains for untethered fast-transforming soft materials journal June 2018
Liquid crystal elastomers, networks and gels: advanced smart materials journal January 2005
Liquid‐Crystal‐Elastomer‐Based Dissipative Structures by Digital Light Processing 3D Printing journal June 2020

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