Highly Efficient Separation/Recycling Palladium(II) Ions from Aqueous Solutions by Silica Gel-Coated Graphene Oxide Modified with Mercapto Groups

Journal Article · Sun Dec 15 04:00:00 EST 2019 · Metallurgical and Materials Transactions. B, Process Metallurgy and Materials Processing Science

DOI:https://doi.org/10.1007/S11663-019-01697-8· OSTI ID:22933410

Li, Min; Tang, Si; Feng, Jian ^[1]; Huang, Kun ^[2]; Meng, Xiaojing ^[1]; Gao, Feng ^[3]; Jiang, Songshan ^[1]

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1. Chongqing University of Science and Technology, Department of Chemical Engineering (China)
2. Chinese Academy of Sciences, Shenyang National Laboratory for Materials Science, Institute of Metal Research (China)
3. Guangxi University, School of Resources, Environment and Materials (China)

The separation and recovery of precious metals from secondary resources is an extremely important and challenging task. Herein, a novel sorbent is successfully prepared by chemical grafting and utilized for the extraction and separation of Pd(II) ions from aqueous solutions. Various characterization techniques, including Fourier transform infrared spectroscopy, scanning electron microscopy, Brunauer–Emmett–Teller, X-ray photoelectron spectroscopy, and element analysis, are employed to study the structure, morphology, porous nature, and chemical composition of the as-prepared SiO{sub 2}@GO-SH nanocomposites. The adsorption of Pd(II) ions on the SiO{sub 2}@GO-SH can be described by the pseudo-second-order model and Langmuir isotherm model. The adsorption equilibrium has been attained within 90 min and the maximum adsorption capacity of 423.2 mg g{sup −1} was attained at pH 3.5 and T = 308 K. The results reveal that SiO{sub 2}@GO-SH exhibits an excellent adsorption performance towards Pd(II) ions. In addition, we have proposed the adsorption mechanism for Pd(II) ions on the SiO{sub 2}@GO-SH surface. The adsorption of Pd(II) in SiO{sub 2}@GO-SH is a chemisorption process, where partial adsorbed Pd(II) ions are reduced to Pd(0) by functional groups (-SH) in the SiO{sub 2}@GO-SH. The results indicate that SiO{sub 2}@GO-SH can serve as a promising sorbent for the efficient separation and recovery of palladium from the palladium-containing secondary resources.

• OSTI ID: 22933410
• Journal Information: Metallurgical and Materials Transactions. B, Process Metallurgy and Materials Processing Science, Journal Name: Metallurgical and Materials Transactions. B, Process Metallurgy and Materials Processing Science Journal Issue: 6 Vol. 50; ISSN 1073-5615; ISSN MTBSEO
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ADSORPTION
AQUEOUS SOLUTIONS
CHEMICAL COMPOSITION
CHEMISORPTION
EXTRACTION
FOURIER TRANSFORM SPECTROMETERS
GRAPHENE
ISOTHERMS
MATERIALS RECOVERY
MORPHOLOGY
NANOCOMPOSITES
PALLADIUM
PALLADIUM IONS
PERFORMANCE
PH VALUE
RECYCLING
SCANNING ELECTRON MICROSCOPY
SILICA GEL
SILICON OXIDES
SURFACES
X-RAY PHOTOELECTRON SPECTROSCOPY