New M{sub (2 + δ1)}X{sub (2 + δ2)} Superstructure of Ordered Nanocrystalline Titanium Monoxide and the Problem of Transition States
- Institute of Mathematics and Mechanics, Ural Branch, Russian Academy of Sciences (Russian Federation)
The results of experiments on the vacancy ordering in nanocrystalline nonstoichiometric titanium monoxide TiO{sub y} (space group Fm 3-bar m), which is accompanied by the formation of the orthorhombic Ti{sub 9}O{sub 10} phase (space group Immm), are considered. The vacancy distribution in the ordered phase is described by a two-sublattice-ordering M{sub (2 + δ1)}X{sub (2 + δ2)} superstructure. The disorder–order (TiO{sub y}–Ti{sub (2 + δ1)}O{sub (2 + δ2)}) phase transition is accompanied by symmetry distortions along non-Lifshitz star {k_4}. When ordering, vacancies concentrate in every third (110) plane of the basic B1-type structure. The deviation of stoichiometry is caused by different vacancy concentrations in the defect planes in the metallic and nonmetallic sublattices (parameters δ{sub 1} and δ{sub 2}, respectively). The new class of M{sub (n + δ1)}X{sub (n + δ2)} superstructures is shown to generate numerous order–disorder transition state models, which cannot be described in terms of the mean-field approximation. At δ{sub 1} = δ{sub 2} = 0.5, the orthorhombic M{sub (2 + δ1)}X{sub (2 + δ2)} structure is a particular case of the partly disordered monoclinic M{sub 5}X{sub 5} superstructure (space group C2/m(A2/m)), which is characteristic of a coarse-grained state.
- OSTI ID:
- 22917762
- Journal Information:
- Journal of Experimental and Theoretical Physics, Journal Name: Journal of Experimental and Theoretical Physics Journal Issue: 4 Vol. 128; ISSN JTPHES; ISSN 1063-7761
- Country of Publication:
- United States
- Language:
- English
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