Y(III) Sorption at the Orthoclase (001) Surface Measured by X-ray Reflectivity

Neumann, Julia; Lessing, Jessica; Lee, Sang Soo; Stubbs, Joanne E.; Eng, Peter J.; Demnitz, Maximilian; Fenter, Paul A.; Schmidt, Moritz

doi:10.1021/acs.est.2c06703

Y(III) Sorption at the Orthoclase (001) Surface Measured by X-ray Reflectivity

Journal Article · Fri Dec 23 00:00:00 EST 2022 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.2c06703· OSTI ID:2290267

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Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); Argonne National Laboratory (ANL), Argonne, IL (United States)
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Univ. of Chicago, IL (United States)
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources (CARS)

Interactions of heavy metals with charged mineral surfaces control their mobility in the environment. Here, we investigate the adsorption of Y(III) onto the orthoclase (001) basal plane, the former as a representative of rare earth elements and an analogue of trivalent actinides and the latter as a representative of naturally abundant K-feldspar minerals. In this study, we apply in situ high-resolution X-ray reflectivity to determine the sorption capacity and molecular distribution of adsorbed Y species as a function of the Y³⁺ concentration, [Y³⁺], at pH 7 and 5. With [Y³⁺] ≥ 1 mM at pH 7, we observe an inner-sphere (IS) sorption complex at a distance of ~1.5 Å from the surface and an outer-sphere (OS) complex at 3–4 Å. Based on the adsorption height of the IS complex, a bidentate, binuclear binding mode, in which Y³⁺ binds to two terminal oxygens, is proposed. In contrast, mostly OS sorption is observed at pH 5. The observed maximum Y coverage is ~1.3 Y³⁺/A_UC (A_UC: area of the unit cell = 111.4 Å²) for all the investigated pH values and Y concentrations, which is in the expected range based on the estimated surface charge of orthoclase (001).

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357; SC0019108

OSTI ID:: 2290267

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 1 Vol. 57; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (80)

GeoSoilEnviroCARS (Sector 13) at the Advanced Photon Source: a comprehensive synchrotron radiation facility for Earth science research at ambient and extreme conditions Sutton, S. R.; Rivers, M. L.; Chariton, S. Physics and Chemistry of Minerals, Vol. 49, Issue 8 https://doi.org/10.1007/s00269-022-01207-4	journal	July 2022
State of rare earth elements in different environmental components in mining areas of China Liang, Tao; Li, Kexin; Wang, Lingqing Environmental Monitoring and Assessment, Vol. 186, Issue 3 https://doi.org/10.1007/s10661-013-3469-8	journal	October 2013
Evaluation of water quality in surface water and shallow groundwater: a case study of a rare earth mining area in southern Jiangxi Province, China Hao, Xiuzhen; Wang, Dengjun; Wang, Peiran Environmental Monitoring and Assessment, Vol. 188, Issue 1 https://doi.org/10.1007/s10661-015-5025-1	journal	December 2015
Origin of middle rare earth element enrichment in acid mine drainage-impacted areas Grawunder, Anja; Merten, Dirk; Büchel, Georg Environmental Science and Pollution Research, Vol. 21, Issue 11 https://doi.org/10.1007/s11356-013-2107-x	journal	January 2014
Effects of colloidal particle size on the geochemical characteristics of REE in the water in southern Jiangxi province, China Luo, Jianmei; Huo, Yongwei; Shen, Yanjun Environmental Earth Sciences, Vol. 75, Issue 1 https://doi.org/10.1007/s12665-015-4870-0	journal	December 2015
Effects of rare earth elements on the environment and human health: A literature review Rim, Kyung-Taek Toxicology and Environmental Health Sciences, Vol. 8, Issue 3 https://doi.org/10.1007/s13530-016-0276-y	journal	September 2016
Association behaviour of 241Am(III) on SiO2(amorphous) and SiO2(quartz) colloids Degueldre, C.; Wernli, B. Journal of Environmental Radioactivity, Vol. 20, Issue 3 https://doi.org/10.1016/0265-931X(93)90007-T	journal	January 1993
Atomic-scale structure of the orthoclase (001)–water interface measured with high-resolution X-ray reflectivity Fenter, P.; Teng, H.; Geissbühler, P. Geochimica et Cosmochimica Acta, Vol. 64, Issue 21 https://doi.org/10.1016/S0016-7037(00)00455-5	journal	November 2000
Resolving orthoclase dissolution processes with atomic force microscopy and X-ray reflectivity Teng, H. Henry; Fenter, Paul; Cheng, Likwan Geochimica et Cosmochimica Acta, Vol. 65, Issue 20 https://doi.org/10.1016/S0016-7037(01)00665-2	journal	October 2001
Orthoclase dissolution kinetics probed by in situ X-ray reflectivity: effects of temperature, pH, and crystal orientation Fenter, P.; Park, C.; Cheng, L. Geochimica et Cosmochimica Acta, Vol. 67, Issue 2 https://doi.org/10.1016/S0016-7037(02)01084-0	journal	January 2003
Structure of the orthoclase (001)- and (010)-water interfaces by high-resolution X-ray reflectivity Fenter, P.; Cheng, L.; Park, C. Geochimica et Cosmochimica Acta, Vol. 67, Issue 22 https://doi.org/10.1016/S0016-7037(03)00374-0	journal	November 2003
Kinetics of feldspar and quartz dissolution at 70–80°C and near-neutral pH: effects of organic acids and NaCl Blake, R. E.; Walter, L. M. Geochimica et Cosmochimica Acta, Vol. 63, Issue 13-14 https://doi.org/10.1016/S0016-7037(99)00072-1	journal	July 1999
PILATUS: a two-dimensional X-ray detector for macromolecular crystallography Eikenberry, E. F.; Brönnimann, Ch; Hülsen, G. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 501, Issue 1 https://doi.org/10.1016/S0168-9002(02)02044-2	journal	March 2003
Influence of etch pit development on the surface area and dissolution kinetics of the orthoclase (001) surface Pollet-Villard, Marion; Daval, Damien; Fritz, Bertrand Chemical Geology, Vol. 447 https://doi.org/10.1016/j.chemgeo.2016.09.038	journal	December 2016
Smart Kd-values, their uncertainties and sensitivities - Applying a new approach for realistic distribution coefficients in geochemical modeling of complex systems Stockmann, M.; Schikora, J.; Becker, D. -A. Chemosphere, Vol. 187 https://doi.org/10.1016/j.chemosphere.2017.08.115	journal	November 2017
Water, sediment and agricultural soil contamination from an ion-adsorption rare earth mining area Liu, Wen-Shen; Guo, Mei-Na; Liu, Chang Chemosphere, Vol. 216 https://doi.org/10.1016/j.chemosphere.2018.10.109	journal	February 2019
Sorption of Eu(III) on quartz at high salt concentrations García, David; Lützenkirchen, Johannes; Petrov, Vladimir Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 578 https://doi.org/10.1016/j.colsurfa.2019.123610	journal	October 2019
Reactions of feldspar surfaces with aqueous solutions Chardon, Emmanuelle S.; Livens, Francis R.; Vaughan, David J. Earth-Science Reviews, Vol. 78, Issue 1-2 https://doi.org/10.1016/j.earscirev.2006.03.002	journal	September 2006
Health effects and toxicity mechanisms of rare earth elements—Knowledge gaps and research prospects Pagano, Giovanni; Guida, Marco; Tommasi, Franca Ecotoxicology and Environmental Safety, Vol. 115 https://doi.org/10.1016/j.ecoenv.2015.01.030	journal	May 2015
Effect of four lanthanides onto the viability of two mammalian kidney cell lines Heller, Anne; Barkleit, Astrid; Bok, Frank Ecotoxicology and Environmental Safety, Vol. 173 https://doi.org/10.1016/j.ecoenv.2019.02.013	journal	May 2019
Structure and reactivity of environmental interfaces: Application of grazing angle X-ray spectroscopy and long-period X-ray standing waves Trainor, Thomas P.; Templeton, Alexis S.; Eng, Peter J. Journal of Electron Spectroscopy and Related Phenomena, Vol. 150, Issue 2-3 https://doi.org/10.1016/j.elspec.2005.04.011	journal	February 2006
Influence of orthoclase phenocrysts on point load strength of granitic rocks Fener, M.; Ince, I. Engineering Geology, Vol. 141-142 https://doi.org/10.1016/j.enggeo.2012.05.003	journal	July 2012
Cation sorption on the muscovite (001) surface in chloride solutions using high-resolution X-ray reflectivity Schlegel, Michel L.; Nagy, Kathryn. L.; Fenter, Paul Geochimica et Cosmochimica Acta, Vol. 70, Issue 14 https://doi.org/10.1016/j.gca.2006.04.011	journal	July 2006
Molecular dynamics simulations of the orthoclase (001)- and (010)-water interfaces Kerisit, Sebastien; Liu, Chongxuan; Ilton, Eugene S. Geochimica et Cosmochimica Acta, Vol. 72, Issue 6 https://doi.org/10.1016/j.gca.2007.12.014	journal	March 2008
Adsorption of Rb+ and Sr2+ at the orthoclase (001)–solution interface Fenter, P.; Park, C.; Sturchio, N. C. Geochimica et Cosmochimica Acta, Vol. 72, Issue 7 https://doi.org/10.1016/j.gca.2007.12.016	journal	April 2008
Interaction of muscovite (001) with Pu3+ bearing solutions at pH 3 through ex-situ observations Fenter, P.; Lee, S. S.; Park, C. Geochimica et Cosmochimica Acta, Vol. 74, Issue 24 https://doi.org/10.1016/j.gca.2010.09.025	journal	December 2010
Sorption of tetravalent thorium on muscovite Schmidt, M.; Lee, S. S.; Wilson, R. E. Geochimica et Cosmochimica Acta, Vol. 88 https://doi.org/10.1016/j.gca.2012.04.001	journal	July 2012
Macroscopic and spectroscopic characterization of uranium(VI) sorption onto orthoclase and muscovite and the influence of competing Ca2+ Richter, Constanze; Müller, Katharina; Drobot, Björn Geochimica et Cosmochimica Acta, Vol. 189 https://doi.org/10.1016/j.gca.2016.05.045	journal	September 2016
An EXAFS and TRLFS investigation on uranium(VI) sorption to pristine and leached albite surfaces Walter, Marcus; Arnold, Thuro; Geipel, Gerhard Journal of Colloid and Interface Science, Vol. 282, Issue 2 https://doi.org/10.1016/j.jcis.2004.08.133	journal	February 2005
Immobilization of trivalent actinides by sorption onto quartz and incorporation into siliceous bulk: Investigations by TRLFS Stumpf, S.; Stumpf, Th.; Lützenkirchen, J. Journal of Colloid and Interface Science, Vol. 318, Issue 1 https://doi.org/10.1016/j.jcis.2007.09.080	journal	February 2008
In situ structural study of the surface complexation of lead(II) on the chemically mechanically polished hematite ( 1 1 ¯ 02 ) surface Qiu, Canrong; Majs, Frantisek; Eng, Peter J. Journal of Colloid and Interface Science, Vol. 524 https://doi.org/10.1016/j.jcis.2018.04.005	journal	August 2018
A comprehensive study of the sorption mechanism and thermodynamics of f-element sorption onto K-feldspar Neumann, J.; Brinkmann, H.; Britz, S. Journal of Colloid and Interface Science, Vol. 591 https://doi.org/10.1016/j.jcis.2020.11.041	journal	June 2021
A review of the beneficiation of rare earth element bearing minerals Jordens, Adam; Cheng, Ying Ping; Waters, Kristian E. Minerals Engineering, Vol. 41 https://doi.org/10.1016/j.mineng.2012.10.017	journal	February 2013
Mechanistic understanding of Curium(III) sorption on natural K-feldspar surfaces Demnitz, Maximilian; Schymura, Stefan; Neumann, Julia Science of The Total Environment, Vol. 843 https://doi.org/10.1016/j.scitotenv.2022.156920	journal	October 2022
Model-independent X-ray imaging of adsorbed cations at the crystal–water interface Zhang, Z.; Fenter, P.; Cheng, L. Surface Science, Vol. 554, Issue 2-3 https://doi.org/10.1016/j.susc.2003.11.047	journal	April 2004
Resonant anomalous X-ray reflectivity as a probe of ion adsorption at solid–liquid interfaces Fenter, Paul; Park, Changyong; Nagy, Kathryn L. Thin Solid Films, Vol. 515, Issue 14 https://doi.org/10.1016/j.tsf.2006.12.118	journal	May 2007
Rare earth elements and critical metal content of extracted landfilled material and potential recovery opportunities Gutiérrez-Gutiérrez, Silvia C.; Coulon, Frédéric; Jiang, Ying Waste Management, Vol. 42 https://doi.org/10.1016/j.wasman.2015.04.024	journal	August 2015
Detection of anthropogenic gadolinium in treated wastewater in South East Queensland, Australia Lawrence, Michael G.; Ort, Christoph; Keller, Jurg Water Research, Vol. 43, Issue 14 https://doi.org/10.1016/j.watres.2009.04.033	journal	August 2009
Combining batch experiments and spectroscopy for realistic surface complexation modelling of the sorption of americium, curium, and europium onto muscovite Bezzina, James P.; Neumann, Julia; Brendler, Vinzenz Water Research, Vol. 223 https://doi.org/10.1016/j.watres.2022.119032	journal	September 2022
Heterogeneous Sorption of Radionuclides Predicted by Crystal Surface Nanoroughness Yuan, Tao; Schymura, Stefan; Bollermann, Till Environmental Science & Technology, Vol. 55, Issue 23 https://doi.org/10.1021/acs.est.1c04413	journal	November 2021
Plutonium(IV) and (V) Sorption to Goethite at Sub-Femtomolar to Micromolar Concentrations: Redox Transformations and Surface Precipitation Zhao, Pihong; Begg, James D.; Zavarin, Mavrik Environmental Science & Technology, Vol. 50, Issue 13 https://doi.org/10.1021/acs.est.6b00605	journal	June 2016
Recovery of Rare Earth Elements and Yttrium from Passive-Remediation Systems of Acid Mine Drainage Ayora, Carlos; Macías, Francisco; Torres, Ester Environmental Science & Technology, Vol. 50, Issue 15 https://doi.org/10.1021/acs.est.6b02084	journal	July 2016
In Situ Structural Study of Sb(V) Adsorption on Hematite (11̅02) Using X-ray Surface Scattering Qiu, Canrong; Majs, Frantisek; Douglas, Thomas A. Environmental Science & Technology, Vol. 52, Issue 19 https://doi.org/10.1021/acs.est.8b03903	journal	September 2018
Surface Hydration and Hydroxyl Configurations of Gibbsite and Boehmite Nanoplates Sassi, Michel; Wang, Zheming; Walter, Eric D. The Journal of Physical Chemistry C, Vol. 124, Issue 9 https://doi.org/10.1021/acs.jpcc.0c00659	journal	February 2020
Effect of Background Electrolyte Composition on the Interfacial Formation of Th(IV) Nanoparticles on the Muscovite (001) Basal Plane Neumann, J.; Qiu, C.; Eng, P. The Journal of Physical Chemistry C, Vol. 125, Issue 30 https://doi.org/10.1021/acs.jpcc.1c03997	journal	July 2021
Impact of Ion–Ion Correlations on the Adsorption of M(III) (M = Am, Eu, Y) onto Muscovite (001) in the Presence of Sulfate Neumann, Julia; Lee, Sang Soo; Brinkmann, Hannes The Journal of Physical Chemistry C, Vol. 126, Issue 3 https://doi.org/10.1021/acs.jpcc.1c09561	journal	January 2022
Surface Charge of the Calcite (104) Terrace Measured by Rb ⁺ Adsorption in Aqueous Solutions Using Resonant Anomalous X-ray Reflectivity Lee, Sang Soo; Heberling, Frank; Sturchio, Neil C. The Journal of Physical Chemistry C, Vol. 120, Issue 28 https://doi.org/10.1021/acs.jpcc.6b04364	journal	July 2016
Epitaxial Growth of Gibbsite Sheets on the Basal Surface of Muscovite Mica Stubbs, Joanne E.; Legg, Benjamin A.; Lee, Sang Soo The Journal of Physical Chemistry C, Vol. 123, Issue 45 https://doi.org/10.1021/acs.jpcc.9b08219	journal	October 2019
A Comparison of Adsorption, Reduction, and Polymerization of the Plutonyl(VI) and Uranyl(VI) Ions from Solution onto the Muscovite Basal Plane Hellebrandt, Stefan; Lee, Sang Soo; Knope, Karah E. Langmuir, Vol. 32, Issue 41 https://doi.org/10.1021/acs.langmuir.6b02513	journal	October 2016
Molecular Dynamics Simulation of Ion Adsorption and Ligand Exchange on an Orthoclase Surface Liu, Qian; Zhang, Xuan; Jiang, Binbin ACS Omega, Vol. 6, Issue 23 https://doi.org/10.1021/acsomega.1c00826	journal	June 2021
Mineral–Water Interface Reactions of Actinides Geckeis, Horst; Lützenkirchen, Johannes; Polly, Robert Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300370h	journal	October 2012
Mass Action Expressions for Bidentate Adsorption in Surface Complexation Modeling: Theory and Practice Wang, Zimeng; Giammar, Daniel E. Environmental Science & Technology, Vol. 47, Issue 9 https://doi.org/10.1021/es305180e	journal	April 2013
Surface-Mediated Formation of Pu(IV) Nanoparticles at the Muscovite-Electrolyte Interface Schmidt, Moritz; Lee, Sang Soo; Wilson, Richard E. Environmental Science & Technology, Vol. 47, Issue 24 https://doi.org/10.1021/es4037258	journal	November 2013
Molecular Dynamics Simulations of Uranyl and Uranyl Carbonate Adsorption at Aluminosilicate Surfaces Kerisit, Sebastien; Liu, Chongxuan Environmental Science & Technology, Vol. 48, Issue 7 https://doi.org/10.1021/es405387c	journal	March 2014
Hospital Effluents as a Source of Gadolinium in the Aquatic Environment Kümmerer, Klaus; Helmers, Eckard Environmental Science & Technology, Vol. 34, Issue 4 https://doi.org/10.1021/es990633h	journal	January 2000
Investigation of Structure, Adsorption Free Energy, and Overcharging Behavior of Trivalent Yttrium Adsorbed at the Muscovite (001)–Water Interface Lee, Sang Soo; Schmidt, Moritz; Laanait, Nouamane The Journal of Physical Chemistry C, Vol. 117, Issue 45 https://doi.org/10.1021/jp407693x	journal	October 2013
Rb ⁺ Adsorption at the Quartz(101)–Aqueous Interface: Comparison of Resonant Anomalous X-ray Reflectivity with ab Initio Calculations Bellucci, Francesco; Lee, Sang Soo; Kubicki, James D. The Journal of Physical Chemistry C, Vol. 119, Issue 9 https://doi.org/10.1021/jp510139t	journal	February 2015
Hydrated Cation Speciation at the Muscovite (001)−Water Interface Lee, Sang Soo; Fenter, Paul; Park, Changyong Langmuir, Vol. 26, Issue 22 https://doi.org/10.1021/la1032866	journal	November 2010
Monovalent Ion Adsorption at the Muscovite (001)–Solution Interface: Relationships among Ion Coverage and Speciation, Interfacial Water Structure, and Substrate Relaxation Lee, Sang Soo; Fenter, Paul; Nagy, Kathryn L. Langmuir, Vol. 28, Issue 23 https://doi.org/10.1021/la300032h	journal	May 2012
Thermodynamics, Interfacial Structure, and pH Hysteresis of Rb ⁺ and Sr ²⁺ Adsorption at the Muscovite (001)−Solution Interface Park, Changyong; Fenter, Paul A.; Sturchio, Neil C. Langmuir, Vol. 24, Issue 24 https://doi.org/10.1021/la802446m	journal	December 2008
The influence of natural mineral coatings on feldspar weathering Nugent, M. A.; Brantley, S. L.; Pantano, C. G. Nature, Vol. 395, Issue 6702 https://doi.org/10.1038/26951	journal	October 1998
Hydration and ion pair formation in aqueous Y ³⁺ –salt solutions Rudolph, Wolfram W.; Irmer, Gert Dalton Transactions, Vol. 44, Issue 42 https://doi.org/10.1039/c5dt02586a	journal	January 2015
A novel greenish yellow-orange red Ba₃Y₄O₉:Bi³⁺,Eu³⁺ phosphor with efficient energy transfer for UV-LEDs Li, Kai; Lian, Hongzhou; Shang, Mengmeng Dalton Transactions, Vol. 44, Issue 47 https://doi.org/10.1039/c5dt03565a	journal	January 2015
Surface X-ray diffraction Robinson, I. K.; Tweet, D. J. Reports on Progress in Physics, Vol. 55, Issue 5 https://doi.org/10.1088/0034-4885/55/5/002	journal	May 1992
Effect of pH and Chemical Composition of Solution on Sorption and Retention of Cesium by Feldspar, Illite, and Zeolite as Cesium Sorbent From Landfill Leachate Ishikawa, Nao K.; Kuwata, Mai; Ito, Ayumi Soil Science, Vol. 182, Issue 2 https://doi.org/10.1097/ss.0000000000000194	journal	February 2017
Crystal truncation rods and surface roughness Robinson, I. K. Physical Review B, Vol. 33, Issue 6 https://doi.org/10.1103/PhysRevB.33.3830	journal	March 1986
Inclusion of local structure effects in theoretical x-ray resonant scattering amplitudes using ab initio x-ray-absorption spectra calculations Cross, J. O.; Newville, M.; Rehr, J. J. Physical Review B, Vol. 58, Issue 17 https://doi.org/10.1103/PhysRevB.58.11215	journal	November 1998
Phasing of resonant anomalous X-ray reflectivity spectra and direct Fourier synthesis of element-specific partial structures at buried interfaces Park, Changyong; Fenter, Paul A. Journal of Applied Crystallography, Vol. 40, Issue 2 https://doi.org/10.1107/S0021889806053131	journal	March 2007
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
The crystal structures of orthoclase and sanidinized orthoclase Cole, W. F.; Sörum, H.; Kennard, O. Acta Crystallographica, Vol. 2, Issue 5 https://doi.org/10.1107/s0365110x49000734	journal	October 1949
Data publication: Y(III) sorption at the orthoclase (001) surface measured by X-ray reflectivity Neumann, J.; Lessing, Jessica; Lee, S. S. Rodare https://doi.org/10.14278/rodare.2000	dataset	January 2022
Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature Li, Ping; Wu, Hanyu; Liang, Jianjun Radiochimica Acta, Vol. 105, Issue 12 https://doi.org/10.1515/ract-2017-2797	journal	June 2017
Sorption of Cm(III) onto different Feldspar surfaces: a TRLFS study Stumpf, Silvia; Stumpf, Th.; Walther, C. Radiochimica Acta, Vol. 94, Issue 5 https://doi.org/10.1524/ract.2006.94.5.243	journal	May 2006
Exploitation of the sorptive properties of mica for the preparation of higher-resolution alpha-spectroscopy samples Wilson, Richard E.; Schwindt, Oliver; Fenter, Paul Radiochimica Acta, Vol. 98, Issue 7 https://doi.org/10.1524/ract.2010.1736	journal	July 2010
Environmental impacts of rare earth production Zapp, Petra; Schreiber, Andrea; Marx, Josefine MRS Bulletin, Vol. 47, Issue 3 https://doi.org/10.1557/s43577-022-00286-6	journal	March 2022
Rare Earth Elements: Minerals, Mines, Magnets (and More) Chakhmouradian, A. R.; Wall, F. Elements, Vol. 8, Issue 5 https://doi.org/10.2113/gselements.8.5.333	journal	October 2012
X-ray Reflectivity as a Probe of Mineral-Fluid Interfaces: A User Guide Fenter, P. A. Reviews in Mineralogy and Geochemistry, Vol. 49, Issue 1 https://doi.org/10.2138/gsrmg.49.1.149	journal	January 2002
Influence of Muscovite (001) Surface Nanotopography on Radionuclide Adsorption Studied by Kinetic Monte Carlo Simulations Schabernack, Jonas; Kurganskaya, Inna; Fischer, Cornelius Minerals, Vol. 11, Issue 5 https://doi.org/10.3390/min11050468	journal	April 2021
Sorption Speciation of Lanthanides/Actinides on Minerals by TRLFS, EXAFS and DFT Studies: A Review Tan, Xiaoli; Fang, Ming; Wang, Xiangke Molecules, Vol. 15, Issue 11 https://doi.org/10.3390/molecules15118431	journal	November 2010
Experimental deformation of K-feldspar single crystals Willaime, Christian; Christie, John McDougall; Kovacs, Marie-Paule Bulletin de Minéralogie, Vol. 102, Issue 2 https://doi.org/10.3406/bulmi.1979.7272	journal	January 1979

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Y(III) Sorption at the Orthoclase (001) Surface Measured by X-ray Reflectivity

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