Synthesis, structure, and magnetic properties of a Yb{sup III} complex with the iminopyridine radical-anionic ligand
Journal Article
·
· Russian Chemical Bulletin
- Russian Academy of Sciences, G. A. Razuvaev Institute of Organometallic Chemistry (Russian Federation)
- Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
The reaction of equimolar amounts of ytterbocene (C{sub 5}Me{sub 4}H){sub 2}Yb(THF){sub 2} and iminopyridine 2,6-Pr{sup i}{sub 2}C{sub 6}H{sub 3}N=CH(C{sub 5}H{sub 4}N) accompanied by the one-electron oxidation of the ytterbium ion produced the unique lanthanide complex (C{sub 5}Me{sub 4}H){sub 2}Yb{sup III}[2,6-Pr{sup i}{sub 2}-C{sub 6}H{sub 3}NCH(C{sub 5}H{sub 4}N)]–• with the iminopyridine radical-anionic ligand. The structure of the complex in the crystalline state was established by X-ray diffraction and its magnetic properties were studied in the temperature range of 1.8—300 K.
- OSTI ID:
- 22863401
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 1 Vol. 67; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and molecular structures of Yb{sup II} and Ca bis(amidinate) complexes containing the tridentate amidinate ligand [2,6-Pr{sup i}{sub 2}C{sub 6}H{sub 3}NC(But)NC{sub 6}H{sub 4}OMe-2]
Reactions of vinyl amido ligands in Tp`(CO){sub 2}W[N(R`)CH=CHR] complexes prepared from addition of primary amines to coordinated alkynes
A sulphur and uranium fiesta! Synthesis, structure, and characterization of neutral terminal uranium(VI) monosulphide, uranium(VI) η2-disulphide, and uranium(IV) phosphine sulphide complexes
Journal Article
·
Thu Mar 15 00:00:00 EDT 2018
· Russian Chemical Bulletin
·
OSTI ID:22863362
Reactions of vinyl amido ligands in Tp`(CO){sub 2}W[N(R`)CH=CHR] complexes prepared from addition of primary amines to coordinated alkynes
Journal Article
·
Tue Oct 31 23:00:00 EST 1995
· Organometallics
·
OSTI ID:171520
A sulphur and uranium fiesta! Synthesis, structure, and characterization of neutral terminal uranium(VI) monosulphide, uranium(VI) η2-disulphide, and uranium(IV) phosphine sulphide complexes
Journal Article
·
Wed Sep 26 00:00:00 EDT 2018
· Dalton Transactions
·
OSTI ID:1477702