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Reduced Graphene Oxide–Cadmium Zinc Sulfide Nanocomposite with Controlled Band Gap for Large-Area Thin-Film Optoelectronic Device Application

Journal Article · · Journal of Materials Engineering and Performance
;  [1];  [2];  [1]
  1. Vidyasagar University, Department of Physics and Technophysics (India)
  2. Midnapore College, Department of Physics (India)

Herein, we report the one pot single step solvothermal synthesis of reduced grapheme oxide–cadmium zinc sulfide (RGO–Cd{sub 0.5}Zn{sub 0.5}S) composite. The reduction in graphene oxide (GO), synthesis of Cd{sub 0.5}Zn{sub 0.5}S (mentioned as CdZnS in the text) nanorod and decoration of CdZnS nanorods onto RGO sheet were done simultaneously. The structural, morphological and optical properties were studied thoroughly by different techniques, such as XRD, TEM, UV–Vis and PL. The PL intensity of CdZnS nanorods quenches significantly after the attachment of RGO, which confirms photoinduced charge transformation from CdZnS nanorods to RGO sheet through the interface of RGO–CdZnS. An excellent photocurrent generation in RGO–CdZnS thin-film device has been observed under simulated solar light irradiation. The photocurrent as well as photosensitivity increases linearly with the solar light intensity for all the composites. Our study establishes that the synergistic effect of RGO and CdZnS in the composite is capable of getting promising applications in the field of optoelectronic devising.

OSTI ID:
22860486
Journal Information:
Journal of Materials Engineering and Performance, Journal Name: Journal of Materials Engineering and Performance Journal Issue: 6 Vol. 27; ISSN 1059-9495; ISSN JMEPEG
Country of Publication:
United States
Language:
English