Volatile lanthanide complexes with fluorinated heptadentate ligands

Zgrabik, Joshua C.; Bhuniya, Balaka; Branstad Phillips, Thomas; Barroso, Jorge; Vlaisavljevich, Bess; Daly, Scott R.

doi:10.1039/D3DT04198K

Volatile lanthanide complexes with fluorinated heptadentate ligands

Journal Article · Mon Feb 12 23:00:00 EST 2024 · Dalton Transactions

DOI:https://doi.org/10.1039/D3DT04198K· OSTI ID:2282677

Zgrabik, Joshua C. ^[1]; Bhuniya, Balaka ^[1]; Branstad Phillips, Thomas ^[1]; ^[2]; ^[2]; ^[1]

Department of Chemistry, The University of Iowa, E331 Chemistry Building, Iowa City, Iowa 52242, USA
Department of Chemistry, The University of South Dakota, 414 E Clark St, Vermillion, SD, 57069, USA

Here we describe the synthesis, structures, and volatility of lanthanide complexes containing N ₄ O ₃ ligands decorated with different fluoroalkyl substituents. The results show how ligand fluorination does not necessarily enhance complex volatility.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0019426

OSTI ID:: 2282677

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 7 Vol. 53; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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