Tracking radioactivity content in the spent fuel pool in PWRS - 15150
- DW James Consulting, LLC (United States)
- Pacific Gas and Electric Co (United States)
- Exelon Corporation (United States)
- DW James Consulting LLC (United States)
Over the last decade, significant progress has been made in managing radioisotopes generated in the PWR primary systems. These include limiting the use of cobalt containing materials, along with improved fuel performance and zinc injection to passivate the corrosion layers to limit the accumulation of Co-58 and Co-60 on primary coolant surfaces. Attention here is directed to the spent fuel pool where accumulation of spent fuel and activated material represents a growing source of mobile radioactivity supplemented with periodic exchanges of water from the reactor cooling system. Characterization of this source is increasingly important to effective management of disposal options. This paper examines the radioactive resin source term as determined from routine sampling of the coolant and fuel pool liquids. Targeted resin stream sampling and radiochemical analyses conducted at Diablo Canyon serve to inform and provide context for this examination. This examination is supplemented with computer modelling using the DW James Consulting computer program, 3R-SCAN. At most operating plants daily reactor coolant samples are counted using gamma spectroscopy and recorded. These samples serve to track fuel performance and maintain water chemistry. A secondary use for this data is to maintain a day to day tracking of releases of radioisotopes important to waste disposal. Given the coolant concentrations, plant operating history, and corroborative mathematical models and sampling, accumulation of these radioisotopes in coolant cleanup system ion-exchangers can be predicted. Fuel pool sampling is less frequent, but at the same time, things change more slowly there. The fuel pool contains about ten times the volume of the reactor coolant but its cleanup system process rate is comparable to reactor coolant letdown, i.e. 5.047 - 8.833 liters per second [lps] (80-140 gallons per minute [gpm]). A spent fuel pool clean-up demineralizer flow rate is typically about 5.047 lps (80 gpm). Concentrations of longer lived radioisotopes in the spent fuel pool can be comparable to those in reactor coolant. Releases of corrosion products and fission products from the stored fuel occur at a low rate but given the overall inventory can be significant. Recognized scaling factor ratios, particularly those to Co-60, are skewed by the aging of the material in the pool. An additional consideration stems from refueling operations themselves. Prior to refueling, it is common practice to conduct a forced oxidation of the corrosion films within the reactor. This spikes the activity within the reactor coolant. Most of this activity is removed by the reactor coolant purification system prior to removing the reactor head. This paper examines the accumulation of activity in the fuel pool purification ion exchange resins and how it impacts the overall classification of those ion exchange resins. The following discussion focuses on the transport of nickel and cobalt isotopes particularly as it relates to determination of Ni-63 which has become increasingly prominent in disposal classification. (authors)
- Research Organization:
- WM Symposia, Inc., PO Box 27646, 85285-7646 Tempe, AZ (United States)
- OSTI ID:
- 22822701
- Report Number(s):
- INIS-US-19-WM-15150; TRN: US19V0691067616
- Resource Relation:
- Conference: WM2015: Annual Waste Management Symposium, Phoenix, AZ (United States), 15-19 Mar 2015; Other Information: Country of input: France; 4 refs.; Available online at: http://archive.wmsym.org/2015/index.html
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
AGING
COBALT 58
COBALT 60
COMPUTERIZED SIMULATION
CONCENTRATION RATIO
COOLANT CLEANUP SYSTEMS
CORROSION
CORROSION PRODUCTS
DEMINERALIZERS
FISSION PRODUCTS
FLOW RATE
FUEL STORAGE POOLS
GAMMA SPECTROSCOPY
INVENTORIES
ION EXCHANGE
MATHEMATICAL MODELS
NICKEL 63
PWR TYPE REACTORS
RADIOACTIVITY
RADIOCHEMICAL ANALYSIS
RESINS
SPENT FUELS
WASTE DISPOSAL
WATER
WATER CHEMISTRY
ZINC