Fast Kinetics Design for Solid‐State Battery Device

Wang, Yichao; Li, Xin

doi:10.1002/adma.202309306

Fast Kinetics Design for Solid‐State Battery Device

Journal Article · Wed Jan 17 00:00:00 EST 2024 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202309306· OSTI ID:2281741

Wang, Yichao ^[1]; ^[1]

John A. Paulson School of Engineering and Applied Sciences Harvard University Cambridge MA 02138 USA

Abstract

Fast kinetics of solid‐state batteries at the device level is not adequately explored to achieve fast charging and discharging. In this work, a leap forward is achieved for fast kinetics in full cells with high cathode loading and areal capacity. This kinetic improvement is achieved by designing a hierarchical structure of electrode composites. In the cathode, the authors’ design enables high areal capacities above 3 mAh cm ⁻² to be stably cycled at high current densities of ≈13–40 mA cm ⁻² , yielding a C‐rate from 5 to 10 C. In the anode, the authors’ design breaks the common rule of the negative correlation between critical C‐rate and the discharge voltage that is observed in most other anodes. The overall design enables the fast cycling of such batteries for over 4000 cycles at room temperature and 5 C charge‐rate. The design principles unveiled by this work help to understand critical kinetic processes in battery devices that limit the fast cycling at high cathode loading and speed up the design of high‐performance solid‐state batteries.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 2281741

Journal Information:: Advanced Materials, Journal Name: Advanced Materials; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Fast Kinetics Design for Solid‐State Battery Device

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Fast Kinetics Design for Solid‐State Battery Device

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