Chemical Sciences Division Oak Ridge National Laboratory Oak Ridge Tennessee USA
Center for Nanophase Materials Sciences Oak Ridge National Laboratory Oak Ridge Tennessee USA
Center for Nanophase Materials Sciences Oak Ridge National Laboratory Oak Ridge Tennessee USA, Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge Tennessee USA
Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge Tennessee USA
The use of block copolymers to compatibilize immiscible plastics is an important strategy for upcycling municipal plastic wastes. Multiblock copolymers (MBCPs) have been proven to be more effective compatibilizers than di‐ and tri‐block copolymers. Herein, we probe the interface structure of an effective multiblock copolymer compatibilizer and compare that with an ineffective triblock copolymer (TBCP). The interface activity of the compatibilizers is understood through a combination of small‐angle neutron and x‐ray scatterings (SANS and SAXS), by using deuterated homopolymer matrix and protonated compatibilizers. SANS analysis suggests that the MBCP forms a thicker interface layer (7–9 nm) than the TBCP (0–4 nm). In addition, SANS data seems to point to a stronger tendency for the MBCP to locate at the interface. Both factors contribute to its effectiveness at compatibilizing immiscible homopolymers.
Tang, Xiaomin, Liu, Changhao, Chen, Jihua, Kumar, Rajeev, Bowland, Christopher C., Saito, Tomonori, Dial, Brent E., Keum, Jong K., Do, Changwoo, & Chen, Xi Chelsea (2024). Probing the interface structure of block copolymer compatibilizers in semicrystalline polymer blends. Journal of Applied Polymer Science, 141(14). https://doi.org/10.1002/app.55178
@article{osti_2281608,
author = {Tang, Xiaomin and Liu, Changhao and Chen, Jihua and Kumar, Rajeev and Bowland, Christopher C. and Saito, Tomonori and Dial, Brent E. and Keum, Jong K. and Do, Changwoo and Chen, Xi Chelsea},
title = {Probing the interface structure of block copolymer compatibilizers in semicrystalline polymer blends},
annote = {Abstract The use of block copolymers to compatibilize immiscible plastics is an important strategy for upcycling municipal plastic wastes. Multiblock copolymers (MBCPs) have been proven to be more effective compatibilizers than di‐ and tri‐block copolymers. Herein, we probe the interface structure of an effective multiblock copolymer compatibilizer and compare that with an ineffective triblock copolymer (TBCP). The interface activity of the compatibilizers is understood through a combination of small‐angle neutron and x‐ray scatterings (SANS and SAXS), by using deuterated homopolymer matrix and protonated compatibilizers. SANS analysis suggests that the MBCP forms a thicker interface layer (7–9 nm) than the TBCP (0–4 nm). In addition, SANS data seems to point to a stronger tendency for the MBCP to locate at the interface. Both factors contribute to its effectiveness at compatibilizing immiscible homopolymers.},
doi = {10.1002/app.55178},
url = {https://www.osti.gov/biblio/2281608},
journal = {Journal of Applied Polymer Science},
issn = {ISSN 0021-8995},
number = {14},
volume = {141},
place = {United States},
publisher = {Wiley Blackwell (John Wiley & Sons)},
year = {2024},
month = {01}}
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
2281608
Alternate ID(s):
OSTI ID: 2311240 OSTI ID: 2281609
Journal Information:
Journal of Applied Polymer Science, Journal Name: Journal of Applied Polymer Science Journal Issue: 14 Vol. 141; ISSN 0021-8995
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 764https://doi.org/10.1016/j.nima.2014.07.029