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Title: TiO2∙rGO nanocomposite as a photo catalyst for the reduction of Cr6+

Journal Article · · Materials Research Bulletin
 [1];  [1];  [2];  [1]
  1. Department of Physics, Faculty of Science, Kasetsart University, Bangkok 10900 (Thailand)
  2. Computational Applied Science for Smart Innovation Cluster (CLASSIC), Faculty of Science, King Mongkut’s University of Technology Thonburi, Bangkok 10149 (Thailand)

Highlights: • Titania decorated reduced graphene oxide was fabricated by hydrothermal process. • TiO{sub 2} nanoparticles attached to the surfaces of the rGO are anatase. • rGO surfaces were covered with TiO{sub 2} nanoparticles whose average sizes. • Photocatalytic reduction of toxic Cr{sup 6+} is increased as x is increased. - Abstract: Titania decorated reduced graphene oxide (TiO{sub 2}∙x%rGO (x = 0, 1, 05, 10, 15, 20 and 25) nanocomposites (NC’s) were fabricated using a hydrothermal process. Scanning electron microscope (SEM) images show that the rGO surfaces were covered with TiO{sub 2} nanoparticles whose average sizes increased as x is increased. X Ray Diffraction (XRD) of all the NP’s exhibits the diffractions peaks of the anatase phase of the TiO{sub 2}. The Fourier-Transform Infrared (FT-IR) spectra of these NC’s indicate an increase in the Ti-O-C interfacial chemical bond vibration signals as x increases. A decrease in the energy of the band (energy) gap as the amount of rGO is increased is determined from the UV–vis light absorption spectra. The use of these TiO{sub 2}∙x%rGO NC’s to reduce toxic Cr{sup 6+} ions to nontoxic Cr{sup 3+} ions is studied. The photo-catalytic reduction of the toxic Cr{sup 6+} is seen in general to increase as x is increased.

OSTI ID:
22805274
Journal Information:
Materials Research Bulletin, Vol. 107; Other Information: Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English