Engineering a highly dispersed core@shell structure for efficient photocatalysis: A case study of ternary novel BiOI@MIL-88A(Fe)@g-C3N4 nanocomposite
Highlights: • Novel ternary BiOI@MIL-88A(Fe)@g-C{sub 3}N{sub 4} core@shell photocatalyst is reported. • Photocatalytic degradation mechanism of organic pollutants is investigated. • It is divulged that the photodegradation is increased by BiOI supporting. • Core@shell structure of MIL-88A(Fe)@g-C{sub 3}N{sub 4} causes high activity. • Strong visible light absorption and electron transfer improve activity. - Abstract: Ternary novel BiOI@MIL-88A(Fe)@g-C{sub 3}N{sub 4} nanocomposite with core@shell structure was successfully synthesized by hydrothermal method. Fabricated photocatalysts were characterized and results confirmed the formation of MIL-88A(Fe)@g-C{sub 3}N{sub 4} core@shell structure and subsequently BiOI decoration on the surface of MIL-88A(Fe)@g-C{sub 3}N{sub 4}. Photocatalytic performances of prepared samples were investigated for degradation of Acid Blue 92 (AB92), Rhodamine B (RhB) and phenol under visible irradiation. It is clearly demonstrated that the as-prepared ternary BiOI@MIL-88A(Fe)@g-C{sub 3}N{sub 4} composites exhibits exceptional visible-light photocatalytic activities for cationic, anionic as well as neutral pollutant molecules compared to the widely accepted outstanding g-C{sub 3}N{sub 4}. It is mainly proved that the exceptional photocatalytic efficiencies are comprehensively ascribed to the porous structure of MIL-88A(Fe)@g-C{sub 3}N{sub 4}, greatly promoted charge separation and introduced catalytic functions to the carrier-related redox reactions by decorating BiOI and coupling g-C{sub 3}N{sub 4}, to modulate holes and electrons. Additionally, studies performed using radical scavengers showed the main reactive species in the photocataytic reaction for all chemical pollutant degradation.
- OSTI ID:
- 22805214
- Journal Information:
- Materials Research Bulletin, Vol. 106; Other Information: Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
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