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Title: High-Resolution Characterization of Comingled Contaminants in the Deep Vadose Zone, Hanford Site, Washington - 17387

Conference ·
OSTI ID:22802403
; ;  [1];  [2]
  1. CH2M Plateau Remediation Company, Richland, WA (United States)
  2. Department of Energy, Richland Operations Office (United States)

The contaminated deep vadose zone in the Central Plateau of the Hanford Site in Washington state presents a unique challenge to remediation. The Comprehensive Environmental Response, Compensation, and Liability Act, commonly known as the CERCLA project responsible for addressing these deep contaminants is designated as the 200-Deep Vadose Zone Operable Unit (DV-1 project). The vadose zone is 55-82 meters (180-270 feet) thick and is contaminated with both radiological and chemical contaminants from multiple historical waste streams. The mobile contaminants from this waste are still present in the deep vadose zone and pose a potential threat to the groundwater. Characterizing the nature and extent of the comingled mobile contaminants is an important step before assessing possible remedial alternatives. One factor controlling the migration and distribution of subsurface contaminants is the lithologic heterogeneity of the vadose zone sediments. A sampling plan for the DV-1 project includes continuous sediment core collection and analysis to identify key lithologic factors (i.e., small-scale bedding and structural features) that act as barriers, preferential pathways or conduits for mobile contaminants migrating through the vadose zone. Over six hundred meters (2,000 feet) of intact sediment core from 26 boreholes were collected in 1.5 meters (5 feet) long, 10 centimeter (4-inch) diameter segments. These intact sediment samples provide significant improvement in the level of detail and understanding of mechanisms and features controlling contaminant distribution that is not possible with traditional homogenized drill cuttings or conventional split-spoon samples. Detailed geological descriptions and photographs of the intact core are correlated to high-resolution geophysical logs which aid in the development of a comprehensive contaminant distribution profile of the borehole. These lithologic interpretations are used to define specific depth intervals for sampling based on changes in moisture, lithology, and elevated gamma radiation. The selected samples are analyzed for contaminants of concern, geochemical parameters, and hydraulic properties. Significant lithologic features observed in the intact cores include sharp contact boundaries to graded bedding, iron-oxide and carbonate cementation, silty laminations, clastic dike intrusions, and soft sediment deformation. Preliminary geologic logs integrated with the sample analysis indicate features that correlate to the variable distribution of contaminants both laterally and vertically. Integration of measured hydraulic parameters to lithologic units in individual borehole profiles provide key inputs for more precise geo-framework and vadose zone flux models supporting the DV-1 project. (authors)

Research Organization:
WM Symposia, Inc., PO Box 27646, 85285-7646 Tempe, AZ (United States)
OSTI ID:
22802403
Report Number(s):
INIS-US-19-WM-17387; TRN: US19V0414046797
Resource Relation:
Conference: WM2017: 43. Annual Waste Management Symposium, Phoenix, AZ (United States), 5-9 Mar 2017; Other Information: Country of input: France; 5 refs.; available online at: http://archive.wmsym.org/2017/index.html
Country of Publication:
United States
Language:
English