C@SnS2 core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

Jin, Changqing; Wei, Yongxing; Nan, Ruihua; Jian, Zengyun; Ding, Qingping

doi:10.1016/j.electacta.2023.143747

C@SnS₂ core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

Journal Article · Sat Dec 30 00:00:00 EST 2023 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2023.143747· OSTI ID:2278837

^[1]; Wei, Yongxing ^[1]; Nan, Ruihua ^[1]; Jian, Zengyun ^[1]; ^[2]

Xi'an Univ. of Technology, Xi'an, Shaanxi (China)
Ames Lab., and Iowa State Univ., Ames, IA (United States)

C@SnS₂ core-shell 0D/2D nanocomposite was successfully prepared by a one-step hydrothermal method. The SnS₂ nanosheets were heterogeneously nucleated and grown on the surface of carbon spheres. As an anode for lithium-ion batteries, the electrochemical performance of the C@SnS₂ composite outperforms that of SnS₂ nanoflowers. After 100 cycles, the reversible discharge specific capacity reaches an impressive value of 802 mAh g^-1 at a current density of 100 mA g^-1. Even after 600 cycles, the discharge specific capacity remains a value of 442 mAh g^-1, under a high current density of 1 A g^-1. Further, this remarkable lithium-ion storage performance can be attributed to the unique core-shell nanostructure and the synergy between SnS₂ nanosheets and carbon spheres. This study advances our understanding of the vital role of carbon in fabricating nano-heterojunction or composite electrodes and provides a feasible route to significantly improve the electrochemical properties of SnS₂ and other metal sulfides.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2278837

Alternate ID(s):: OSTI ID: 2274841

Report Number(s):: IS-J--11,229

Journal Information:: Electrochimica Acta, Journal Name: Electrochimica Acta Vol. 476; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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C@SnS2 core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

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C@SnS₂ core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode