C@SnS2 core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

Jin, Changqing; Wei, Yongxing; Nan, Ruihua; Jian, Zengyun; Ding, Qingping

doi:10.1016/j.electacta.2023.143747

C@SnS₂ core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

Journal Article · Fri Dec 29 23:00:00 EST 2023 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2023.143747· OSTI ID:2278837

^[1]; Wei, Yongxing ^[1]; Nan, Ruihua ^[1]; Jian, Zengyun ^[1]; ^[2]

Xi'an Univ. of Technology, Xi'an, Shaanxi (China)
Ames Lab., and Iowa State Univ., Ames, IA (United States)

C@SnS₂ core-shell 0D/2D nanocomposite was successfully prepared by a one-step hydrothermal method. The SnS₂ nanosheets were heterogeneously nucleated and grown on the surface of carbon spheres. As an anode for lithium-ion batteries, the electrochemical performance of the C@SnS₂ composite outperforms that of SnS₂ nanoflowers. After 100 cycles, the reversible discharge specific capacity reaches an impressive value of 802 mAh g^-1 at a current density of 100 mA g^-1. Even after 600 cycles, the discharge specific capacity remains a value of 442 mAh g^-1, under a high current density of 1 A g^-1. Further, this remarkable lithium-ion storage performance can be attributed to the unique core-shell nanostructure and the synergy between SnS₂ nanosheets and carbon spheres. This study advances our understanding of the vital role of carbon in fabricating nano-heterojunction or composite electrodes and provides a feasible route to significantly improve the electrochemical properties of SnS₂ and other metal sulfides.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2278837

Alternate ID(s):: OSTI ID: 2274841

Report Number(s):: IS-J--11,229

Journal Information:: Electrochimica Acta, Journal Name: Electrochimica Acta Vol. 476; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

A Simple One-Pot Strategy for Synthesizing Ultrafine SnS ₂ Nanoparticle/Graphene Composites as Anodes for Lithium/Sodium-Ion Batteries Li, Xin; Sun, Xiaohong; Gao, Zhiwen ChemSusChem, Vol. 11, Issue 9 https://doi.org/10.1002/cssc.201800073	journal	April 2018
MOF‐Derived CuS@Cu‐BTC Composites as High‐Performance Anodes for Lithium‐Ion Batteries Wang, Ping; Shen, Mengqi; Zhou, Hu Small, Vol. 15, Issue 47 https://doi.org/10.1002/smll.201903522	journal	October 2019
Controllable synthesis of SnS2 nanoflakes as high-performance anode for lithium-ion batteries Yin, Lixiong; Li, Huimin; Cheng, Ruliang Journal of Materials Science: Materials in Electronics, Vol. 32, Issue 1 https://doi.org/10.1007/s10854-020-04753-1	journal	January 2021
Carbon@SnS2 core-shell microspheres for lithium-ion battery anode materials Yu, Guoyun; Chen, Xiujuan; Wang, Ansong Ionics, Vol. 24, Issue 10 https://doi.org/10.1007/s11581-018-2596-1	journal	June 2018
Nanoplates-assembled SnS2 nanoflowers with carbon coating anchored on reduced graphene oxide for high performance Li-ion batteries Wu, Ya-Qian; Zhao, Yi-Song; Meng, Wen-Jie Applied Surface Science, Vol. 539 https://doi.org/10.1016/j.apsusc.2020.148283	journal	February 2021
In-situ liquid-phase transformation of SnS2/CNTs composite from SnO2/CNTs for high performance lithium-ion battery anode Cheng, Yayi; Xie, Hui; Zhou, Lei Applied Surface Science, Vol. 566 https://doi.org/10.1016/j.apsusc.2021.150645	journal	November 2021
SnS 2 /graphene nanocomposite: A high rate anode material for lithium ion battery Wei, Wei; Jia, Fang-Fang; Wang, Ke-Feng Chinese Chemical Letters, Vol. 28, Issue 2 https://doi.org/10.1016/j.cclet.2016.09.003	journal	February 2017
Synthesis and high-performance of carbonaceous polypyrrole nanotubes coated with SnS2 nanosheets anode materials for lithium ion batteries Chen, Xuefang; Huang, Ying; Zhang, Kaichuang Chemical Engineering Journal, Vol. 330 https://doi.org/10.1016/j.cej.2017.07.180	journal	December 2017
Realizing high reversible capacity: 3D intertwined CNTs inherently conductive network for CuS as an anode for lithium ion batteries Wang, Yunhui; Zhang, Yiyong; Li, He Chemical Engineering Journal, Vol. 332 https://doi.org/10.1016/j.cej.2017.09.070	journal	January 2018
The positive effect of 3D interpenetrating network porous structure by carbon membranes on alleviating the volume expansion of SnS2 nanosheets for enhancing lithium and sodium storage Liu, Hao; Wei, Chengbiao; Ai, Zhiquan Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 610 https://doi.org/10.1016/j.colsurfa.2020.125937	journal	February 2021
Fabrication of rGO/g-C3N4@SnS2 and its rate-performance enhancement Shi, Xiaorong; Zhou, Zhaoyang; Yin, Jinpeng Chemical Physics Letters, Vol. 746 https://doi.org/10.1016/j.cplett.2020.137296	journal	May 2020
Mesoporous carbon anchored with SnS2 nanosheets as an advanced anode for lithium-ion batteries Li, Jianping; Wu, Ping; Lou, Feijian Electrochimica Acta, Vol. 111 https://doi.org/10.1016/j.electacta.2013.08.104	journal	November 2013
Preparation of hierarchical SnS 2 /SnO 2 anode with enhanced electrochemical performances for lithium-ion battery Yin, Lixiong; Chai, Simin; Huang, Jianfeng Electrochimica Acta, Vol. 238 https://doi.org/10.1016/j.electacta.2017.03.183	journal	June 2017
Layer-by-layered SnS2/graphene hybrid nanosheets via ball-milling as promising anode materials for lithium ion batteries Xia, Jing; Liu, Li; Xie, Jianjun Electrochimica Acta, Vol. 269 https://doi.org/10.1016/j.electacta.2018.03.022	journal	April 2018
Construction of nanoflower SnS2 anchored on g-C3N4 nanosheets composite as highly efficient anode for lithium ion batteries Yin, Lixiong; Cheng, Ruliang; Song, Qiang Electrochimica Acta, Vol. 293 https://doi.org/10.1016/j.electacta.2018.10.020	journal	January 2019
Elaborate interface design of SnS2/SnO2@C/rGO nanocomposite as a high-performance anode for lithium-ion batteries Jin, Shuangling; Gu, Feijiao; Wang, Jitong Electrochimica Acta, Vol. 405 https://doi.org/10.1016/j.electacta.2021.139799	journal	February 2022
Binder-free SnS2 sheet array with high sulfur vacancy concentration for enhanced lithium storage performance Huang, Yu; Ding, Shengqi; Xu, Sunjie Electrochimica Acta, Vol. 409 https://doi.org/10.1016/j.electacta.2022.139979	journal	March 2022
Binder-free ultrathin SnS2 with superior reversibility of conversion reaction for high-rate lithium ion batteries Chen, Xin; Jiang, Heng; Pei, Yaxi Journal of Alloys and Compounds, Vol. 873 https://doi.org/10.1016/j.jallcom.2021.159623	journal	August 2021
Hierarchical microspheres constructed by SnS2 nanosheets and S-doped graphene for high performance lithium/sodium-ion batteries He, Cun-Jian; Wang, Yu-Qian; Meng, Wen-Jie Journal of Alloys and Compounds, Vol. 889 https://doi.org/10.1016/j.jallcom.2021.161648	journal	December 2021
High stability and superior rate capability of three-dimensional hierarchical SnS2 microspheres as anode material in lithium ion batteries Zai, Jiantao; Wang, Kaixue; Su, Yuezeng Journal of Power Sources, Vol. 196, Issue 7 https://doi.org/10.1016/j.jpowsour.2010.12.057	journal	April 2011
Few-layer SnS2/graphene hybrid with exceptional electrochemical performance as lithium-ion battery anode Chang, Kun; Wang, Zhen; Huang, Guochuang Journal of Power Sources, Vol. 201 https://doi.org/10.1016/j.jpowsour.2011.10.132	journal	March 2012
One-pot synthesis of three-dimensional SnS2 hierarchitectures as anode material for lithium-ion batteries Wu, Qiong; Jiao, Lifang; Du, Juan Journal of Power Sources, Vol. 239 https://doi.org/10.1016/j.jpowsour.2013.03.062	journal	October 2013
Template-free synthesis of novel SnS2 array and its superior performances for lithium ion battery Zhu, Anquan; Qiao, Lulu; Tan, Pengfei Journal of Solid State Chemistry, Vol. 261 https://doi.org/10.1016/j.jssc.2018.02.004	journal	May 2018
An ionic liquid-assisted route towards SnS2 nanoparticles anchored on reduced graphene oxide for lithium-ion battery anode Cheng, Min; Hu, Qianqian; Du, Chengfeng Journal of Solid State Chemistry, Vol. 296 https://doi.org/10.1016/j.jssc.2021.122022	journal	April 2021
Microwave synthesis of SnS2 nanoflakes anchored graphene foam for flexible lithium-ion battery anodes with long cycling life Ren, Yuduo; Lv, Weiming; Wen, Fusheng Materials Letters, Vol. 174 https://doi.org/10.1016/j.matlet.2016.03.075	journal	July 2016
SnS2–graphene nanocomposites as anodes of lithium-ion batteries Wang, Qi; Nie, Yu-Xin; He, Bin Solid State Sciences, Vol. 31 https://doi.org/10.1016/j.solidstatesciences.2014.03.001	journal	May 2014
Bimetallic Sulfide SnS₂/FeS₂ Nanosheets as High-Performance Anode Materials for Sodium-Ion Batteries Chen, Yun; Liu, Hongbin; Guo, Xiaolin ACS Applied Materials & Interfaces, Vol. 13, Issue 33 https://doi.org/10.1021/acsami.1c08801	journal	August 2021
Vanadium Nitride Nanowire Supported SnS₂ Nanosheets with High Reversible Capacity as Anode Material for Lithium Ion Batteries Balogun, Muhammad-Sadeeq; Qiu, Weitao; Jian, Junhua ACS Applied Materials & Interfaces, Vol. 7, Issue 41 https://doi.org/10.1021/acsami.5b07044	journal	October 2015
Tin Disulfide Nanoplates on Graphene Nanoribbons for Full Lithium Ion Batteries Gao, Caitian; Li, Lei; Raji, Abdul-Rahman O. ACS Applied Materials & Interfaces, Vol. 7, Issue 48 https://doi.org/10.1021/acsami.5b07768	journal	November 2015
Rationally Incorporated MoS ₂ /SnS ₂ Nanoparticles on Graphene Sheets for Lithium-Ion and Sodium-Ion Batteries Jiang, Yong; Guo, Yibo; Lu, Wenjun ACS Applied Materials & Interfaces, Vol. 9, Issue 33 https://doi.org/10.1021/acsami.7b06572	journal	August 2017
Inverse Capacity Growth and Pocket Effect in SnS₂ Semifilled Carbon Nanotube Anode Jin, Xiaozhe; Huang, Hao; Wu, Aimin ACS Nano, Vol. 12, Issue 8 https://doi.org/10.1021/acsnano.8b02861	journal	July 2018
Multiwalled Carbon Nanotubes Anchored with SnS₂ Nanosheets as High-Performance Anode Materials of Lithium-Ion Batteries Zhai, Chuanxin; Du, Ning; Zhang, Hui ACS Applied Materials & Interfaces, Vol. 3, Issue 10 https://doi.org/10.1021/am200933m	journal	September 2011
Preferential c -Axis Orientation of Ultrathin SnS ₂ Nanoplates on Graphene as High-Performance Anode for Li-Ion Batteries Liu, Shuangyu; Lu, Xiang; Xie, Jian ACS Applied Materials & Interfaces, Vol. 5, Issue 5 https://doi.org/10.1021/am302124f	journal	February 2013
Plate-like SnS₂nanostructures: Hydrothermal preparation, growth mechanism and excellent electrochemical properties Ma, Jianmin; Lei, Danni; Mei, Lin CrystEngComm, Vol. 14, Issue 3 https://doi.org/10.1039/C1CE05831B	journal	January 2012
p-Type SnO thin layers on n-type SnS ₂ nanosheets with enriched surface defects and embedded charge transfer for lithium ion batteries Zhang, Yiqiong; Ma, Zhaoling; Liu, Dongdong Journal of Materials Chemistry A, Vol. 5, Issue 2 https://doi.org/10.1039/C6TA09748K	journal	January 2017
Engineering SnS ₂ nanosheet assemblies for enhanced electrochemical lithium and sodium ion storage Wang, Yeyun; Zhou, Junhua; Wu, Jinghua Journal of Materials Chemistry A, Vol. 5, Issue 48 https://doi.org/10.1039/C7TA08056E	journal	January 2017
SnS2@reduced graphene oxide nanocomposites as anode materials with high capacity for rechargeable lithium ion batteries Yin, Jiefu; Cao, Huaqiang; Zhou, Zhongfu Journal of Materials Chemistry, Vol. 22, Issue 45 https://doi.org/10.1039/c2jm35137d	journal	January 2012
Preparation of Core-shell Structure Carbon@SnM2 (M=S, O) Microspheres Composites and Application in Lithium-ion Batteries Wang, Ansong; Zhang, Penglin; Chen, Xiujuan International Journal of Electrochemical Science, Vol. 14, Issue 4 https://doi.org/10.20964/2019.04.46	journal	April 2019
In-situ Grown SnS2 Nanosheets on rGO as an Advanced Anode Material for Lithium and Sodium Ion Batteries Chen, Hezhang; Zhang, Bao; Zhang, Jiafeng Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00629	journal	December 2018

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C@SnS2 core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

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C@SnS₂ core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode