Changes of Normal Coordinates and Geometrical Parameters of a Molecule in a Laser Field
Journal Article
·
· Optics and Spectroscopy
General formulas are derived that describe the changes in equilibrium distances, valence angles, and vibrational frequencies of a polyatomic molecule in a strong laser field. It is shown that the coordinates of normal vibrations do not change in the second order in the field strength. For a nonlinear triatomic molecule of the type of A{sub 2}B, the changes of geometrical characteristics and vibrational frequencies are obtained in an explicit form.
- OSTI ID:
- 22786579
- Journal Information:
- Optics and Spectroscopy, Journal Name: Optics and Spectroscopy Journal Issue: 1 Vol. 124; ISSN OPSUA3; ISSN 0030-400X
- Country of Publication:
- United States
- Language:
- English
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