Charge order landscape and competition with superconductivity in kagome metals

Kang, Mingu; Fang, Shiang; Yoo, Jonggyu; Ortiz, Brenden R.; Oey, Yuzki M.; Choi, Jonghyeok; Ryu, Sae Hee; Kim, Jimin; Jozwiak, Chris; Bostwick, Aaron; Rotenberg, Eli; Kaxiras, Efthimios; Checkelsky, Joseph G.; Wilson, Stephen D.; Park, Jae-Hoon; Comin, Riccardo

doi:10.1038/s41563-022-01375-2

Charge order landscape and competition with superconductivity in kagome metals

Journal Article · Thu Nov 03 00:00:00 EDT 2022 · Nature Materials

DOI:https://doi.org/10.1038/s41563-022-01375-2· OSTI ID:2278637

^[1]; ^[2]; Yoo, Jonggyu ^[3]; Ortiz, Brenden R. ^[4]; Oey, Yuzki M. ^[4]; Choi, Jonghyeok ^[3]; Ryu, Sae Hee ^[5]; Kim, Jimin ^[6]; ^[5]; ^[5]; ^[5]; ^[7]; ^[2]; ^[4]; ^[3]; ^[2]

Max Planck POSTECH/Korea Research Initiative, Pohang (Korea, Republic of); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Max Planck POSTECH/Korea Research Initiative, Pohang (Korea, Republic of); Pohang University of Science and Technology, Pohang (Korea, Republic of)
University of California, Santa Barbara, CA (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Institute for Basic Science (IBS), Pohang (Korea, Republic of)
Harvard University, Cambridge, MA (United States)

In the kagome metals AV₃Sb₅ (A = K, Rb, Cs), three-dimensional charge order is the primary instability that sets the stage for other collective orders to emerge, including unidirectional stripe order, orbital flux order, electronic nematicity and superconductivity. In this report we use high-resolution angle-resolved photoemission spectroscopy to determine the microscopic structure of three-dimensional charge order in AV₃Sb₅ and its interplay with superconductivity. Our approach is based on identifying an unusual splitting of kagome bands induced by three-dimensional charge order, which provides a sensitive way to refine the spatial charge patterns in neighbouring kagome planes. Here we found a marked dependence of the three-dimensional charge order structure on composition and doping. The observed difference between CsV₃Sb₅ and the other compounds potentially underpins the double-dome superconductivity in CsV₃(Sb,Sn)₅ and the suppression of T_c in KV₃Sb₅ and RbV₃Sb₅. Our results provide fresh insights into the rich phase diagram of AV₃Sb₅.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Air Force Office of Scientific Research (AFOSR); National Science Foundation (NSF); Gordon and Betty Moore Foundation; National Research Foundation of Korea

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2278637

Journal Information:: Nature Materials, Journal Name: Nature Materials Journal Issue: 2 Vol. 22; ISSN 1476-1122

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

References (49)

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Topological surface states and flat bands in the kagome superconductor CsV3Sb5 Hu, Yong; Teicher, Samuel M. L.; Ortiz, Brenden R. Science Bulletin, Vol. 67, Issue 5 https://doi.org/10.1016/j.scib.2021.11.026	journal	March 2022
First principles phonon calculations in materials science Togo, Atsushi; Tanaka, Isao Scripta Materialia, Vol. 108 https://doi.org/10.1016/j.scriptamat.2015.07.021	journal	November 2015
High-temperature superconductivity in iron pnictides and chalcogenides Si, Qimiao; Yu, Rong; Abrahams, Elihu Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.17	journal	March 2016
From quantum matter to high-temperature superconductivity in copper oxides Keimer, B.; Kivelson, S. A.; Norman, M. R. Nature, Vol. 518, Issue 7538 https://doi.org/10.1038/nature14165	journal	February 2015
Unconventional superconductivity in magic-angle graphene superlattices Cao, Yuan; Fatemi, Valla; Fang, Shiang Nature, Vol. 556, Issue 7699 https://doi.org/10.1038/nature26160	journal	March 2018
Nanoscale decoupling of electronic nematicity and structural anisotropy in FeSe thin films Ren, Zheng; Li, Hong; Zhao, He Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20150-y	journal	January 2021
Twofold symmetry of c-axis resistivity in topological kagome superconductor CsV3Sb5 with in-plane rotating magnetic field Xiang, Ying; Li, Qing; Li, Yongkai Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27084-z	journal	November 2021
Electronic nature of charge density wave and electron-phonon coupling in kagome superconductor KV3Sb5 Luo, Hailan; Gao, Qiang; Liu, Hongxiong Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-021-27946-6	journal	January 2022
Rich nature of Van Hove singularities in Kagome superconductor CsV3Sb5 Hu, Yong; Wu, Xianxin; Ortiz, Brenden R. Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29828-x	journal	April 2022
Possible star-of-David pattern charge density wave with additional modulation in the kagome superconductor CsV3Sb5 Luo, J.; Zhao, Z.; Zhou, Y. Z. npj Quantum Materials, Vol. 7, Issue 1 https://doi.org/10.1038/s41535-022-00437-7	journal	March 2022
Unconventional chiral charge order in kagome superconductor KV3Sb5 Jiang, Yu-Xiao; Yin, Jia-Xin; Denner, M. Michael Nature Materials https://doi.org/10.1038/s41563-021-01034-y	journal	June 2021
Twofold van Hove singularity and origin of charge order in topological kagome superconductor CsV3Sb5 Kang, Mingu; Fang, Shiang; Kim, Jeong-Kyu Nature Physics https://doi.org/10.1038/s41567-021-01451-5	journal	January 2022
Rotation symmetry breaking in the normal state of a kagome superconductor KV3Sb5 Li, Hong; Zhao, He; Ortiz, Brenden R. Nature Physics https://doi.org/10.1038/s41567-021-01479-7	journal	January 2022
Cascade of correlated electron states in the kagome superconductor CsV3Sb5 Zhao, He; Li, Hong; Ortiz, Brenden R. Nature, Vol. 599, Issue 7884 https://doi.org/10.1038/s41586-021-03946-w	journal	September 2021
Superconductivity and Normal-State Properties of Kagome Metal RbV ₃ Sb ₅ Single Crystals Yin, Qiangwei; Tu, Zhijun; Gong, Chunsheng Chinese Physics Letters, Vol. 38, Issue 3 https://doi.org/10.1088/0256-307X/38/3/037403	journal	March 2021
On the origin of charge-density waves in select layered transition-metal dichalcogenides Rossnagel, K. Journal of Physics: Condensed Matter, Vol. 23, Issue 21 https://doi.org/10.1088/0953-8984/23/21/213001	journal	May 2011
Pressure-induced double superconducting domes and charge instability in the kagome metal KV 3 Sb 5 Du, Feng; Luo, Shuaishuai; Ortiz, Brenden R. Physical Review B, Vol. 103, Issue 22 https://doi.org/10.1103/PhysRevB.103.L220504	journal	June 2021
Intrinsic nature of chiral charge order in the kagome superconductor Rb V 3 Sb 5 Shumiya, Nana; Hossain, Md. Shafayat; Yin, Jia-Xin Physical Review B, Vol. 104, Issue 3 https://doi.org/10.1103/PhysRevB.104.035131	journal	July 2021
Theory of the charge density wave in A V 3 Sb 5 kagome metals Christensen, Morten H.; Birol, Turan; Andersen, Brian M. Physical Review B, Vol. 104, Issue 21 https://doi.org/10.1103/PhysRevB.104.214513	journal	December 2021
Origin of charge density wave in the kagome metal CsV 3 Sb 5 as revealed by optical spectroscopy Zhou, Xiaoxiang; Li, Yongkai; Fan, Xinwei Physical Review B, Vol. 104, Issue 4 https://doi.org/10.1103/PhysRevB.104.L041101	journal	July 2021
Multiple energy scales and anisotropic energy gap in the charge-density-wave phase of the kagome superconductor CsV 3 Sb 5 Nakayama, Kosuke; Li, Yongkai; Kato, Takemi Physical Review B, Vol. 104, Issue 16 https://doi.org/10.1103/PhysRevB.104.L161112	journal	October 2021
Double-dome superconductivity under pressure in the V-based kagome metals AV3Sb5 ( A=Rb and K) Zhu, C. C.; Yang, X. F.; Xia, W. Physical Review B, Vol. 105, Issue 9 https://doi.org/10.1103/PhysRevB.105.094507	journal	March 2022
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Angle-resolved photoemission study of the evolution of band structure and charge density wave properties in R Te 3 ( R = Y , La, Ce, Sm, Gd, Tb, and Dy) Brouet, V.; Yang, W. L.; Zhou, X. J. Physical Review B, Vol. 77, Issue 23 https://doi.org/10.1103/PhysRevB.77.235104	journal	June 2008
Topological insulator on the kagome lattice Guo, H. -M.; Franz, M. Physical Review B, Vol. 80, Issue 11 https://doi.org/10.1103/PhysRevB.80.113102	journal	September 2009
Chiral superconducting phase and chiral spin-density-wave phase in a Hubbard model on the kagome lattice Yu, Shun-Li; Li, Jian-Xin Physical Review B, Vol. 85, Issue 14 https://doi.org/10.1103/PhysRevB.85.144402	journal	April 2012
Competing electronic orders on kagome lattices at van Hove filling Wang, Wan-Sheng; Li, Zheng-Zhao; Xiang, Yuan-Yuan Physical Review B, Vol. 87, Issue 11 https://doi.org/10.1103/PhysRevB.87.115135	journal	March 2013
High-Temperature Fractional Quantum Hall States Tang, Evelyn; Mei, Jia-Wei; Wen, Xiao-Gang Physical Review Letters, Vol. 106, Issue 23 https://doi.org/10.1103/PhysRevLett.106.236802	journal	June 2011
Unconventional Fermi Surface Instabilities in the Kagome Hubbard Model Kiesel, Maximilian L.; Platt, Christian; Thomale, Ronny Physical Review Letters, Vol. 110, Issue 12 https://doi.org/10.1103/PhysRevLett.110.126405	journal	March 2013
Intrinsic Quantum Anomalous Hall Effect in the Kagome Lattice Cs 2 LiMn 3 F 12 Xu, Gang; Lian, Biao; Zhang, Shou-Cheng Physical Review Letters, Vol. 115, Issue 18 https://doi.org/10.1103/PhysRevLett.115.186802	journal	October 2015
Cs V 3 Sb 5 : A Z 2 Topological Kagome Metal with a Superconducting Ground State Ortiz, Brenden R.; Teicher, Samuel M. L.; Hu, Yong Physical Review Letters, Vol. 125, Issue 24 https://doi.org/10.1103/PhysRevLett.125.247002	journal	December 2020
Double Superconducting Dome and Triple Enhancement of T c in the Kagome Superconductor CsV 3 Sb 5 under High Pressure Chen, K. Y.; Wang, N. N.; Yin, Q. W. Physical Review Letters, Vol. 126, Issue 24 https://doi.org/10.1103/PhysRevLett.126.247001	journal	June 2021
Charge Density Waves and Electronic Properties of Superconducting Kagome Metals Tan, Hengxin; Liu, Yizhou; Wang, Ziqiang Physical Review Letters, Vol. 127, Issue 4 https://doi.org/10.1103/PhysRevLett.127.046401	journal	July 2021
Nature of Unconventional Pairing in the Kagome Superconductors A V 3 Sb 5 ( A = K , Rb , Cs ) Wu, Xianxin; Schwemmer, Tilman; Müller, Tobias Physical Review Letters, Vol. 127, Issue 17 https://doi.org/10.1103/PhysRevLett.127.177001	journal	October 2021
Emergence of New van Hove Singularities in the Charge Density Wave State of a Topological Kagome Metal RbV 3 Sb 5 Cho, Soohyun; Ma, Haiyang; Xia, Wei Physical Review Letters, Vol. 127, Issue 23 https://doi.org/10.1103/PhysRevLett.127.236401	journal	December 2021
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
New kagome prototype materials: discovery of KV 3 Sb 5 , RbV 3 Sb 5 , and CsV 3 Sb 5 Ortiz, Brenden R.; Gomes, Lídia C.; Morey, Jennifer R. Physical Review Materials, Vol. 3, Issue 9 https://doi.org/10.1103/PhysRevMaterials.3.094407	journal	September 2019
Coherent phonon spectroscopy and interlayer modulation of charge density wave order in the kagome metal CsV 3 Sb 5 Ratcliff, Noah; Hallett, Lily; Ortiz, Brenden R. Physical Review Materials, Vol. 5, Issue 11 https://doi.org/10.1103/PhysRevMaterials.5.L111801	journal	November 2021
Hexagonal-to-base-centered-orthorhombic 4 Q charge density wave order in kagome metals KV 3 Sb 5 , RbV 3 Sb 5 , and CsV 3 Sb 5 Subedi, Alaska Physical Review Materials, Vol. 6, Issue 1 https://doi.org/10.1103/PhysRevMaterials.6.015001	journal	January 2022
Fermi level tuning and double-dome superconductivity in the kagome metal CsV3Sb5−xSnx Oey, Yuzki M.; Ortiz, Brenden R.; Kaboudvand, Farnaz Physical Review Materials, Vol. 6, Issue 4 https://doi.org/10.1103/PhysRevMaterials.6.L041801	journal	April 2022
Fermi Surface Mapping and the Nature of Charge-Density-Wave Order in the Kagome Superconductor CsV 3 Sb 5 Ortiz, Brenden R.; Teicher, Samuel M. L.; Kautzsch, Linus Physical Review X, Vol. 11, Issue 4 https://doi.org/10.1103/PhysRevX.11.041030	journal	November 2021
Mechanism of exotic density-wave and beyond-Migdal unconventional superconductivity in kagome metal AV₃Sb₅(A = K, Rb, Cs) Tazai, Rina; Yamakawa, Youichi; Onari, Seiichiro Science Advances, Vol. 8, Issue 13 https://doi.org/10.1126/sciadv.abl4108	journal	April 2022
Evidence of a hidden flux phase in the topological kagome metal CsV$_3$Sb$_5$ Yu, Li; Wang, Chennan; Zhang, Yuhang arXiv https://doi.org/10.48550/arXiv.2107.10714	preprint	January 2021
Spatial symmetry constraint of charge-ordered kagome superconductor CsV$_3$Sb$_5$ Li, Haoxiang; Jiang, Yu-Xiao; Yin, J. X. arXiv https://doi.org/10.48550/arXiv.2109.03418	text	January 2021
Structural instability and charge modulations in the Kagome superconductor $A$V$_3$Sb$_5$ Ye, Zijin; Luo, Aiyun; Yin, Jia-Xin arXiv https://doi.org/10.48550/arXiv.2111.07314	text	January 2021
Coexistence of Tri-Hexagonal and Star-of-David Pattern in the Charge Density Wave of the Kagome Superconductor AV$_3$Sb$_5$ Hu, Yong; Wu, Xianxin; Ortiz, Brenden R. arXiv https://doi.org/10.48550/arXiv.2201.06477	text	January 2022
Tuning charge-density wave order and superconductivity in the kagome metals KV$_3$Sb$_{5-x}$Sn$_x$ and RbV$_3$Sb$_{5-x}$Sn$_x$ Oey, Yuzki M.; Kaboudvand, Farnaz; Ortiz, Brenden R. arXiv https://doi.org/10.48550/arXiv.2205.06317	text	January 2022

Similar Records

Incommensurate charge-stripe correlations in the kagome superconductor CsV₃Sb_5–xSn_x

Journal Article · Tue Jul 25 00:00:00 EDT 2023 · npj Quantum Materials · OSTI ID:2419535

Impact of charge-density-wave pattern on the superconducting gap in Vanadium-based kagome superconductors

Journal Article · Fri Jul 18 00:00:00 EDT 2025 · Communications Physics · OSTI ID:2572982

Evidence for an odd-parity nematic phase above the charge-density-wave transition in a kagome metal

Journal Article · Wed Jan 03 23:00:00 EST 2024 · Nature Physics · OSTI ID:2282940

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Charge order landscape and competition with superconductivity in kagome metals

Citation Formats

References (49)

Similar Records

Related Subjects