Flash Sintering of Oxide Ceramics under Microwave Heating
- Russian Academy of Sciences, Institute of Applied Physics (Russian Federation)
We report on the results of the analysis of the effect of flash sintering, which is observed upon heating compacted powder materials by high-intensity microwave radiation. Ceramic samples of Y{sub 2}O{sub 3}, MgAl{sub 2}O{sub 4}, and Yb: (LaO){sub 2}O{sub 3} were sintered to a density exceeding 98–99% of the theoretical value during 0.5–5 min without isothermal hold. The specific microwave power absorbed volumetrically in the samples was 20–400 W/cm{sup 3}. Based on the analysis of the experimental data (microwave radiation power and heating and cooling rates) and of the microstructure of the obtained materials, we propose a mechanism of flash sintering based on the evolution of the thermal instability and softening (melting) of the grain boundaries. The proposed mechanism also explains the flash sintering effect observed when a dc or a low-frequency ac voltage is applied to the samples. The microwave heating makes it possible to implement flash sintering without using electrodes for supplying energy to the articles being sintered.
- OSTI ID:
- 22783906
- Journal Information:
- Technical Physics, Vol. 63, Issue 3; Other Information: Copyright (c) 2018 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7842
- Country of Publication:
- United States
- Language:
- English
Similar Records
α‐Alumina and spinel react into single‐phase high‐alumina spinel in <3 seconds during flash sintering
Microwave sintered silicon nitride ceramics