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Ultrafast energy transfer in chlorosomes from the green photosynthetic bacterium Chloroflexus aurantiacus

Journal Article · · Journal of Physical Chemistry
DOI:https://doi.org/10.1021/jp953734k· OSTI ID:227710
;  [1]; ;  [2]
  1. Ames Lab., IA (United States)
  2. Arizona State Univ., Tempe, AZ (United States)

Energy transfers between the bacteriochlorophyll c and a antennae in light-harvesting chlorosomes from the green bacterium Chloroflexus aurantiacus have been studied in two-color pump-probe experiments with improved sensitivity and wavelength versatility. The BChl c {yields} BChl a energy transfers are well simulated with biexponential kinetics, with lifetimes of 2-3 and 11 ps. They do not exhibit an appreciable subpicosecond component. In the context of a kinetic model for chlorosomes, these lifetimes suggest that both internal BChl c processes and the BChl c {yields} BChl a energy-transfer step contribute materially to the empirical rod-to-baseplate energy-transfer kinetics. 11 refs., 2 figs., 1 tab.

OSTI ID:
227710
Journal Information:
Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 9 Vol. 100; ISSN JPCHAX; ISSN 0022-3654
Country of Publication:
United States
Language:
English

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