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Title: Crystal structure and optoelectronic properties of antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm]perylene

Abstract

An antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm] perylene, was synthesized by a coupling reaction. Its crystal structure was determined by X-ray diffraction. Crystal structures shows that the antiaromatic compounds are aggregated to J-aggregation materials. It further results ultrafast charge separation at organic interface and electron transfer in the aggregation materials. UV-vis spectrum shows that title compound has a broad UV-vis light absorbance at the wavelength range from 250 to 470 nm and a 2.67 eV energy gap value between the highest occupied and the lowest unoccupied molecular orbital energy levels.

Authors:
; ; ; ; ;  [1]
  1. Nanjing University of Information Science and Technology, School of Environmental Science and Engineering (China)
Publication Date:
OSTI Identifier:
22758326
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 62; Journal Issue: 6; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; AGGLOMERATION; CRYSTAL STRUCTURE; ELECTRON TRANSFER; ENERGY GAP; ENERGY LEVELS; MOLECULAR ORBITAL METHOD; PERYLENE; ULTRAVIOLET SPECTRA; WAVELENGTHS; X-RAY DIFFRACTION

Citation Formats

Li, T., Zhang, C.-Z., E-mail: chzhzhang@sohu.com, Su, Y. -X., Niu, M. -X., Gu, C. -Y., and Song, M. X. Crystal structure and optoelectronic properties of antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm]perylene. United States: N. p., 2017. Web. doi:10.1134/S1063774517060165.
Li, T., Zhang, C.-Z., E-mail: chzhzhang@sohu.com, Su, Y. -X., Niu, M. -X., Gu, C. -Y., & Song, M. X. Crystal structure and optoelectronic properties of antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm]perylene. United States. doi:10.1134/S1063774517060165.
Li, T., Zhang, C.-Z., E-mail: chzhzhang@sohu.com, Su, Y. -X., Niu, M. -X., Gu, C. -Y., and Song, M. X. Wed . "Crystal structure and optoelectronic properties of antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm]perylene". United States. doi:10.1134/S1063774517060165.
@article{osti_22758326,
title = {Crystal structure and optoelectronic properties of antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm]perylene},
author = {Li, T. and Zhang, C.-Z., E-mail: chzhzhang@sohu.com and Su, Y. -X. and Niu, M. -X. and Gu, C. -Y. and Song, M. X.},
abstractNote = {An antiaromatic compound 3,4,9,10-tetrahydrodicyclopenta[cd,lm] perylene, was synthesized by a coupling reaction. Its crystal structure was determined by X-ray diffraction. Crystal structures shows that the antiaromatic compounds are aggregated to J-aggregation materials. It further results ultrafast charge separation at organic interface and electron transfer in the aggregation materials. UV-vis spectrum shows that title compound has a broad UV-vis light absorbance at the wavelength range from 250 to 470 nm and a 2.67 eV energy gap value between the highest occupied and the lowest unoccupied molecular orbital energy levels.},
doi = {10.1134/S1063774517060165},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 6,
volume = 62,
place = {United States},
year = {2017},
month = {11}
}