A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties

Journal Article · Fri Dec 15 00:00:00 EST 2017 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774517070161· OSTI ID:22758310

Tang, Z. H.; Shi, J.; Ge, H. G.; Jiang, M.; Song, J.; Jin, L. X. ^[1]

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1. Shaanxi University of Technology, Shaanxi Province Key Laboratory of Catalytic Foundation and Application, College of Chemical and Environment Science (China)

The title compound {[Co_3(μ_3-OH)(μ_2-H_2O)2(H_2O)_5(BTC)_2] · 6H_2O}{sub n} (H{sub 3}BTC is a 1,3,5-benzenetricarboxylic acid) was prepared and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric and elemental analyses. The single crystal X-ray diffraction reveals that the title compound consists of 1D infinite zigzag chains which were constructed by trinuclear cobalt cluster and BTC{sup 3–} ligand. Neighbouring above-mentioned 1D infinite zigzag chains are further linked by intermolecular hydrogen bonding to form a 3D supermolecular structure. In addition, the luminescent properties of the title compound were investigated.

• OSTI ID: 22758310
• Journal Information: Crystallography Reports, Vol. 62, Issue 7; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BONDING
CARBONATES
COBALT
FOURIER TRANSFORM SPECTROMETERS
HYDROGEN
LIGANDS
LUMINESCENCE
MONOCRYSTALS
POLYMERS
POWDERS
SYNTHESIS
THERMAL GRAVIMETRIC ANALYSIS
THREE-DIMENSIONAL LATTICES
WATER
X-RAY DIFFRACTION