A Novel Coordination Polymer Constructed by Hetero−Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa{sub 2}(PDC){sub 2}(μ-H{sub 2}O)(H{sub 2}O){sub 2}]{sub n}
Journal Article
·
· Crystallography Reports
- Liaocheng University, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering (China)
A novel coordination polymer containing hetero-metal ions, [NiNa{sub 2}(PDC){sub 2}(μ-H{sub 2}O)(H{sub 2}O){sub 2}]{sub n}, where PDC is 2,3-pyridine dicarboxylate ion, has been synthesized. In the structure, the PDC ligand chelates and bridges two Ni(II) and two Na(I) centers. Two kinds of metal centers are connected by μ{sup 4}-PDC and μ{sup 2}-H{sub 2}O to form 2D coordination layers. Hydrogen bonds between coordination water molecules and carboxylate oxygen atoms further link these 2D coordination layers to form 3D supramolecular network.
- OSTI ID:
- 22758307
- Journal Information:
- Crystallography Reports, Vol. 62, Issue 7; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
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