Hydrothermal Synthesis and Characterization of a New Strandberg-type Diphosphopentamolybdate (C{sub 6}N{sub 3}H{sub 18}){sub 2}[P{sub 2}Mo{sub 5}O{sub 23}] · 6H{sub 2}O
- University of Monastir, Department of Chemistry, Faculty of Sciences (Tunisia)
An inorganic-organic hybrid material formulated as (C{sub 6}N{sub 3}H{sub 18}){sub 2}[P{sub 2}Mo{sub 5}O{sub 23}] · 6H{sub 2}O, has been hydrothermally synthesized and characterized by single crystal X-ray diffraction technique, IR spectrum, thermogravimetric analysis and UV-visible spectroscopy. The structure consists of diphosphopentamolybdate Strandberg type polyoxoanions [P{sub 2}Mo{sub 5}O{sub 23}]{sup 6–}, protonated 1-(2-aminoethyl)piperazine cations and six crystallization water molecules. These anions are connected with the organic amine through hydrogen bonding interactions between the hydrogen atoms of the organic molecules and the oxygen atoms of the polyoxoanion and water molecules which generate a three-dimensional network.
- OSTI ID:
- 22758292
- Journal Information:
- Crystallography Reports, Vol. 62, Issue 7; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
SUPERCONDUCTIVITY AND SUPERFLUIDITY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMINES
ANIONS
ATOMS
BONDING
CATIONS
CRYSTALLIZATION
HYDROGEN
HYDROTHERMAL SYNTHESIS
INFRARED SPECTRA
INTERACTIONS
MOLECULES
MONOCRYSTALS
OXYGEN
PIPERAZINES
SPECTROSCOPY
THERMAL GRAVIMETRIC ANALYSIS
THREE-DIMENSIONAL LATTICES
ULTRAVIOLET SPECTRA
WATER
X-RAY DIFFRACTION