Single Crystal X-ray Study of 6-Phenyl-4-(p-tolyl)pyridin-2(1H)-one

Journal Article · Fri Dec 15 04:00:00 EST 2017 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774517070227· OSTI ID:22758291

Khajuria, Rajni ^[1]; Sharma, Suresh ^[2]

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1. University of Jammu, Department of Chemistry (India)
2. University of Jammu, X-ray Crystallography Laboratory, Department of Physics and Electronics (India)

The title compound 6-phenyl-4-(p-tolyl)pyridin-2(1H)-one was synthesized via one-pot, three component reaction of (E)-1-phenyl-3-(p-tolyl)-2-propen-1-one, ethyl 2-nitroacetate and ammonium acetate in refluxing ethanol, as a shiny green crystalline solid in 83% yield. Its structure was characterized by spectral studies and unambiguously corroborated by X-ray diffraction crystallography. The crystals of title compound are monoclinic, sp. gr. P2{sub 1}/n, a = 11.8346(7) Å, b = 13.4413(9) Å, c = 17.7626(10) Å, β = 99.479(5)°, and Z = 8. All the rings in molecule of the title compound are planar. Hydrogen interactions play significant role in stabilizing the crystal structure and the supramolecular aggregate of molecules is facilitated by strong N–H···O and C–H···O type of hydrogen interactions.

• OSTI ID: 22758291
• Journal Information: Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 7 Vol. 62; ISSN CYSTE3; ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ACETATES
CRYSTALLOGRAPHY
ETHANOL
HYDROGEN
HYDROGEN 1
INTERACTIONS
MOLECULES
MONOCLINIC LATTICES
MONOCRYSTALS
RINGS
SOLIDS
X-RAY DIFFRACTION
YIELDS