Synthesis and Molecular Structure of 2-(4-Chlorophenyl)-3-(phenyl-amino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4H-imidazol-4-one

Journal Article · Thu Dec 14 23:00:00 EST 2017 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774517070082· OSTI ID:22758290

Sharma, Devinder K. ^[1]; Subbulakshmi, K. N.; Narayana, B. ^[2]; Sarojini, B. K. ^[3]; Anthal, Sumati

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1. X-ray Crystallography Laboratory, Department of Physics, University (India)
2. Mangalore University, Department of Chemistry (India)
3. Mangalore University, Department of Industrial Chemistry (India)

2-(4-Chlorophenyl)-3-(phenylamino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4H-imidazol-4-one, C{sub 20}H{sub 14}N{sub 3}OSCl was synthesized and its crystal structure was determined by single crystal X-ray diffraction. The crystals are triclinic, sp. gr. P1, Z = 2. All three rings are planar, and imidazole ring is almost perpendicular to the phenyl ring with the dihedral angle of 88.65(2)°. In the crystal, pairs of O–H···O hydrogen bonds link molecules into inversion dimers, featuring R{sub 22}(10) graph set motif. Crystal structure is further stabilized by π···π interactions.

• OSTI ID: 22758290
• Journal Information: Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 7 Vol. 62; ISSN 1063-7745; ISSN CYSTE3
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTAL STRUCTURE
DIMERS
HYDROGEN
IMIDAZOLES
MOLECULAR STRUCTURE
MOLECULES
MONOCRYSTALS
RINGS
SYNTHESIS
X-RAY DIFFRACTION