Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer
Journal Article
·
· Crystallography Reports
- Université de Sfax, Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences (Tunisia)
A new mixed-valence coordination polymer [Cu{sub 3}(SCN){sub 4}(DMSO){sub 2}]{sub n} (SCN{sup –} = thiocyanato and DMSO = dimethyl sulfoxide) was prepared and characterized by single crystal X-ray diffraction method. The in situ formation of thiocyanate during the synthesis induces reduction of a part of Cu(II) to Cu(I). The three-dimensional structure of the binuclear thiocyanato bridged compound provided an example of pseudohalide materials containing two different environments for both copper centers.
- OSTI ID:
- 22758289
- Journal Information:
- Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 7 Vol. 62; ISSN 1063-7745; ISSN CYSTE3
- Country of Publication:
- United States
- Language:
- English
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