Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Mohapatra, Aiswarya Abhisek; Yual, Waleed Kuar; Zhang, Yadong; Samoylov, Anton Aleksandrovich; Thurston, Jonathan; Davis, Casey May; McCarthy, Declan P.; Printz, Adam D.; Toney, Michael F.; Ratcliff, Erin L.; Armstrong, Neal R.; Greenaway, Ann L.; Barlow, Stephen; Marder, Seth R.

doi:10.1039/d3cc05391a

Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Journal Article · Tue Dec 19 23:00:00 EST 2023 · ChemComm

DOI:https://doi.org/10.1039/d3cc05391a· OSTI ID:2274770

^[1]; ^[2]; Zhang, Yadong ^[3]; ^[2]; ^[4]; ^[4]; ^[4]; ^[2]; ^[3]; ^[2]; ^[2]; ^[5]; ^[6]; ^[6]

University of Colorado, Boulder, CO (United States); University of Colorado-Boulder, Boulder, CO
University of Arizona, Tucson, AZ (United States)
University of Colorado, Boulder, CO (United States)
University of Colorado-Boulder, CO (United States)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
University of Colorado, Boulder, CO (United States); National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. Here, the optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

Research Organization:: University of Colorado, Boulder, CO (United States); University of Arizona, Tucson, AZ (United States); National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0023411; SC0001084; AC36-08GO28308

OSTI ID:: 2274770

Alternate ID(s):: OSTI ID: 2275021
OSTI ID: 2283657

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 8 Vol. 60; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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