Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

Anantharaman, Surendra B.; Lynch, Jason; Stevens, Christopher E.; Munley, Christopher; Li, Chentao; Hou, Jin; Zhang, Hao; Torma, Andrew; Darlington, Thomas; Coen, Francis; Li, Kevin; Majumdar, Arka; Schuck, P. James; Mohite, Aditya; Harutyunyan, Hayk; Hendrickson, Joshua R.; Jariwala, Deep

doi:10.1038/s41377-023-01334-9

Title: Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

Journal Article · Mon Jan 01 00:00:00 EST 2024 · Light, Science & Applications

DOI:https://doi.org/10.1038/s41377-023-01334-9· OSTI ID:2274717

Anantharaman, Surendra B.; Lynch, Jason;

; Munley, Christopher;

;

; Zhang, Hao; Torma, Andrew;

; Coen, Francis; Li, Kevin;

; Schuck, P. James; Mohite, Aditya; Harutyunyan, Hayk;

;

Abstract Excitons, bound electron–hole pairs, in two-dimensional hybrid organic inorganic perovskites (2D HOIPs) are capable of forming hybrid light-matter states known as exciton-polaritons (E–Ps) when the excitonic medium is confined in an optical cavity. In the case of 2D HOIPs, they can self-hybridize into E–Ps at specific thicknesses of the HOIP crystals that form a resonant optical cavity with the excitons. However, the fundamental properties of these self-hybridized E–Ps in 2D HOIPs, including their role in ultrafast energy and/or charge transfer at interfaces, remain unclear. Here, we demonstrate that >0.5 µm thick 2D HOIP crystals on Au substrates are capable of supporting multiple-orders of self-hybridized E–P modes. These E–Ps have high Q factors (>100) and modulate the optical dispersion for the crystal to enhance sub-gap absorption and emission. Through varying excitation energy and ultrafast measurements, we also confirm energy transfer from higher energy E–Ps to lower energy E–Ps. Finally, we also demonstrate that E–Ps are capable of charge transport and transfer at interfaces. Our findings provide new insights into charge and energy transfer in E–Ps opening new opportunities towards their manipulation for polaritonic devices.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 2274717

Journal Information:: Light, Science & Applications, Journal Name: Light, Science & Applications Vol. 13 Journal Issue: 1; ISSN 2047-7538

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (46)

Intriguing Optoelectronic Properties of Metal Halide Perovskites Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V. Chemical Reviews, Vol. 116, Issue 21 https://doi.org/10.1021/acs.chemrev.6b00136	journal	June 2016
Hybrid organic-inorganic exciton-polaritons in a strongly coupled microcavity Wenus, J.; Parashkov, R.; Ceccarelli, S. Physical Review B, Vol. 74, Issue 23 https://doi.org/10.1103/PhysRevB.74.235212	journal	December 2006
Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites Blancon, J. -C.; Tsai, H.; Nie, W. Science, Vol. 355, Issue 6331 https://doi.org/10.1126/science.aal4211	journal	March 2017
Synthesis of 2D perovskite crystals via progressive transformation of quantum well thickness Hou, Jin; Li, Wenbin; Zhang, Hao Nature Synthesis https://doi.org/10.1038/s44160-023-00422-3	journal	October 2023
Tunable Out-of-Plane Excitons in 2D Single-Crystal Perovskites Fieramosca, Antonio; De Marco, Luisa; Passoni, Marco ACS Photonics, Vol. 5, Issue 10 https://doi.org/10.1021/acsphotonics.8b00984	journal	September 2018
Exciton–Photonics: From Fundamental Science to Applications Anantharaman, Surendra B.; Jo, Kiyoung; Jariwala, Deep ACS Nano, Vol. 15, Issue 8 https://doi.org/10.1021/acsnano.1c02204	journal	July 2021
Organic and inorganic quantum wells in a microcavity: Frenkel-Wannier-Mott excitons hybridization and energy transformation Agranovich, V.; Benisty, H.; Weisbuch, C. Solid State Communications, Vol. 102, Issue 8 https://doi.org/10.1016/S0038-1098(96)00433-4	journal	May 1997
Deterministic fabrication of 3D/2D perovskite bilayer stacks for durable and efficient solar cells Sidhik, Siraj; Wang, Yafei; De Siena, Michael Science, Vol. 377, Issue 6613 https://doi.org/10.1126/science.abq7652	journal	September 2022
Tailoring Dispersion of Room-Temperature Exciton-Polaritons with Perovskite-Based Subwavelength Metasurfaces Dang, Nguyen Ha My; Gerace, Dario; Drouard, Emmanuel Nano Letters, Vol. 20, Issue 3 https://doi.org/10.1021/acs.nanolett.0c00125	journal	February 2020
Two-dimensional hybrid perovskites sustaining strong polariton interactions at room temperature Fieramosca, A.; Polimeno, L.; Ardizzone, V. Science Advances, Vol. 5, Issue 5 https://doi.org/10.1126/sciadv.aav9967	journal	May 2019
Hybrid Dion–Jacobson 2D Lead Iodide Perovskites Mao, Lingling; Ke, Weijun; Pedesseau, Laurent Journal of the American Chemical Society, Vol. 140, Issue 10 https://doi.org/10.1021/jacs.8b00542	journal	February 2018
Highly Luminescent Phase-Stable CsPbI ₃ Perovskite Quantum Dots Achieving Near 100% Absolute Photoluminescence Quantum Yield Liu, Feng; Zhang, Yaohong; Ding, Chao ACS Nano, Vol. 11, Issue 10 https://doi.org/10.1021/acsnano.7b05442	journal	September 2017
Compact layer free mixed-cation lead mixed-halide perovskite solar cells Hu, Zhelu; Xiang, Hengyang; Schoenauer Sebag, Mathilde Chemical Communications, Vol. 54, Issue 21 https://doi.org/10.1039/C7CC06183H	journal	January 2018
Author Correction: Manipulating polariton condensates by Rashba-Dresselhaus coupling at room temperature Li, Yao; Ma, Xuekai; Zhai, Xiaokun Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-32032-6	journal	July 2022
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017
Surface Plasmon Enhanced Strong Exciton–Photon Coupling in Hybrid Inorganic–Organic Perovskite Nanowires Shang, Qiuyu; Zhang, Shuai; Liu, Zhen Nano Letters, Vol. 18, Issue 6 https://doi.org/10.1021/acs.nanolett.7b04847	journal	May 2018
Spontaneously coherent orbital coupling of counterrotating exciton polaritons in annular perovskite microcavities Wang, Jun; Xu, Huawen; Su, Rui Light: Science & Applications, Vol. 10, Issue 1 https://doi.org/10.1038/s41377-021-00478-w	journal	March 2021
Room Temperature Coherently Coupled Exciton–Polaritons in Two-Dimensional Organic–Inorganic Perovskite Wang, Jun; Su, Rui; Xing, Jun ACS Nano, Vol. 12, Issue 8 https://doi.org/10.1021/acsnano.8b03737	journal	July 2018
Formation of Long-Lived Color Centers for Broadband Visible Light Emission in Low-Dimensional Layered Perovskites Booker, Edward P.; Thomas, Tudor H.; Quarti, Claudio Journal of the American Chemical Society, Vol. 139, Issue 51 https://doi.org/10.1021/jacs.7b10223	journal	December 2017
Perovskite semiconductors for room-temperature exciton-polaritonics Su, Rui; Fieramosca, Antonio; Zhang, Qing Nature Materials, Vol. 20, Issue 10 https://doi.org/10.1038/s41563-021-01035-x	journal	July 2021
The Origin of Broad Emission in ⟨100⟩ Two-Dimensional Perovskites: Extrinsic vs Intrinsic Processes Kahmann, Simon; Meggiolaro, Daniele; Gregori, Luca ACS Energy Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acsenergylett.2c02123	journal	October 2022
Revealing the output power potential of bifacial monolithic all-perovskite tandem solar cells Li, Hongjiang; Wang, Yurui; Gao, Han eLight, Vol. 2, Issue 1 https://doi.org/10.1186/s43593-022-00028-w	journal	October 2022
Efficient ambient-air-stable solar cells with 2D–3D heterostructured butylammonium-caesium-formamidinium lead halide perovskites Wang, Zhiping; Lin, Qianqian; Chmiel, Francis P. Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.135	journal	August 2017
Tuning the Luminescence of Layered Halide Perovskites Smith, Matthew D.; Connor, Bridget A.; Karunadasa, Hemamala I. Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00477	journal	January 2019
Perovskite Anion Exchange: A Microdynamics Model and a Polar Adsorption Strategy for Precise Control of Luminescence Color Zhou, Yihui; Fang, Tao; Liu, Gaoyu Advanced Functional Materials, Vol. 31, Issue 51 https://doi.org/10.1002/adfm.202106871	journal	September 2021
How Stable Is the 2D/3D Interface of Metal Halide Perovskite under Light and Heat? Chakkamalayath, Jishnudas; Hiott, Nathaniel; Kamat, Prashant V. ACS Energy Letters, Vol. 8, Issue 1 https://doi.org/10.1021/acsenergylett.2c02408	journal	November 2022
Photoluminescence quantum yield exceeding 80% in low dimensional perovskite thin-films via passivation control La-Placa, Maria-Grazia; Longo, Giulia; Babaei, Azin Chemical Communications, Vol. 53, Issue 62 https://doi.org/10.1039/C7CC04149G	journal	January 2017
Halide Perovskite Photovoltaics: Background, Status, and Future Prospects Jena, Ajay Kumar; Kulkarni, Ashish; Miyasaka, Tsutomu Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00539	journal	March 2019
Efficient and stable emission of warm-white light from lead-free halide double perovskites Luo, Jiajun; Wang, Xiaoming; Li, Shunran Nature, Vol. 563, Issue 7732 https://doi.org/10.1038/s41586-018-0691-0	journal	November 2018
Enhanced Performance and Stability of 3D/2D Tin Perovskite Solar Cells Fabricated with a Sequential Solution Deposition Jokar, Efat; Cheng, Po-Yuan; Lin, Chia-Yi ACS Energy Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsenergylett.0c02305	journal	January 2021
Room-Temperature Cavity Polaritons with 3D Hybrid Perovskite: Toward Large-Surface Polaritonic Devices Bouteyre, Paul; Nguyen, Hai Son; Lauret, Jean-Sébastien ACS Photonics, Vol. 6, Issue 7 https://doi.org/10.1021/acsphotonics.9b00625	journal	June 2019
Oriented Growth of Ultrathin Single Crystals of 2D Ruddlesden–Popper Hybrid Lead Iodide Perovskites for High-Performance Photodetectors He, Xianxiong; Wang, Yaguang; Li, Kun ACS Applied Materials & Interfaces, Vol. 11, Issue 17 https://doi.org/10.1021/acsami.9b01825	journal	April 2019
Determination of Dielectric Functions and Exciton Oscillator Strength of Two-Dimensional Hybrid Perovskites Song, Baokun; Hou, Jin; Wang, Haonan ACS Materials Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsmaterialslett.0c00505	journal	December 2020
Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes Min, Hanul; Lee, Do Yoon; Kim, Junu Nature, Vol. 598, Issue 7881 https://doi.org/10.1038/s41586-021-03964-8	journal	October 2021
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices Park, Jeong-Eun; López-Arteaga, Rafael; Sample, Alexander D. ACS Nano, Vol. 16, Issue 3 https://doi.org/10.1021/acsnano.1c09296	journal	March 2022
Self-Hybridized Polaritonic Emission from Layered Perovskites Anantharaman, Surendra B.; Stevens, Christopher E.; Lynch, Jason Nano Letters, Vol. 21, Issue 14 https://doi.org/10.1021/acs.nanolett.1c02058	journal	July 2021
Urbach tail of anatase ${TiO}_{2}$ Tang, H.; Lévy, F.; Berger, H. Physical Review B, Vol. 52, Issue 11 https://doi.org/10.1103/PhysRevB.52.7771	journal	September 1995
Minimizing Energy Barrier in Intermediate Connection Layer for Monolithic Tandem WPeLEDs with Wide Color Gamut Wang, Run; Xiang, Hengyang; Li, Yan Advanced Functional Materials, Vol. 33, Issue 21 https://doi.org/10.1002/adfm.202215189	journal	February 2023
Extrinsic nature of the broad photoluminescence in lead iodide-based Ruddlesden–Popper perovskites Kahmann, Simon; Tekelenburg, Eelco K.; Duim, Herman Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15970-x	journal	May 2020
Experimental study of light emission from strongly coupled organic semiconductor microcavities following nonresonant laser excitation Lidzey, D. G.; Fox, A. M.; Rahn, M. D. Physical Review B, Vol. 65, Issue 19 https://doi.org/10.1103/PhysRevB.65.195312	journal	May 2002
Modeling photocurrent action spectra of photovoltaic devices based on organic thin films Pettersson, Leif A. A.; Roman, Lucimara S.; Inganäs, Olle Journal of Applied Physics, Vol. 86, Issue 1, p. 487-496 https://doi.org/10.1063/1.370757	journal	July 1999
Metal Halide Perovskite for next-generation optoelectronics: progresses and prospects Dong, He; Ran, Chenxin; Gao, Weiyin eLight, Vol. 3, Issue 1 https://doi.org/10.1186/s43593-022-00033-z	journal	January 2023
Electrically Pumped Polarized Exciton-Polaritons in a Halide Perovskite Microcavity Wang, Tingting; Zang, Zhihao; Gao, Yuchen Nano Letters, Vol. 22, Issue 13 https://doi.org/10.1021/acs.nanolett.2c00906	journal	June 2022
Observation of Defect Luminescence in 2D Dion–Jacobson Perovskites Hu, Hao; Liu, Yingmeng; Xie, Zuoxiang Advanced Optical Materials, Vol. 9, Issue 24 https://doi.org/10.1002/adom.202101423	journal	October 2021
Edge States Drive Exciton Dissociation in Ruddlesden–Popper Lead Halide Perovskite Thin Films Kinigstein, Eli D.; Tsai, Hsinhan; Nie, Wanyi ACS Materials Letters, Vol. 2, Issue 10 https://doi.org/10.1021/acsmaterialslett.0c00333	journal	September 2020

Similar Records

Radiative pumping of exciton-polaritons in 2D hybrid perovskites

Journal Article · Fri May 12 00:00:00 EDT 2023 · Optical Materials Express · OSTI ID:2274717

Deshmukh, Prathmesh; Zhao, Lianfeng; Satapathy, Sitakanta; +4 more

Ultralong‐Range Energy Transport in a Disordered Organic Semiconductor at Room Temperature Via Coherent Exciton‐Polariton Propagation

Journal Article · Tue Jun 02 00:00:00 EDT 2020 · Advanced Materials · OSTI ID:2274717

Hou, Shaocong; Khatoniar, Mandeep; Ding, Kan; +4 more

Ultrafast Charge Transfer and Hybrid Exciton Formation in 2D/0D Heterostructures

Journal Article · Tue Oct 18 00:00:00 EDT 2016 · Journal of the American Chemical Society · OSTI ID:2274717

Boulesbaa, Abdelaziz; Wang, Kai; Mahjouri-Samani, Masoud; +7 more

Title: Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

Citation Formats

References (46)

Similar Records

Related Subjects