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Title: A microporous metal–organic framework for selective C{sub 2}H{sub 2} and CO{sub 2} separation

Abstract

A quartzlike metal–organic framework with interesting one dimensional channel has been synthesized. It exhibits considerable acetylene and carbon dioxide uptake of 41.5 and 24.6 cm{sup 3} g{sup −1}, respectively, and relatively high selectivity for separation of C{sub 2}H{sub 2}/C{sub 2}H{sub 4}, C{sub 2}H{sub 2}/CH{sub 4}, CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} at ambient condition. - Graphical abstract: A quartzlike topology metal−organic framework exhibits relatively high selectivity for separation of C{sub 2}H{sub 2}/C{sub 2}H{sub 4}, C{sub 2}H{sub 2}/CH{sub 4}, CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} at ambient condition. Display Omitted - Highlights: • We firstly explored the selective adsorption of C{sub 2}H{sub 2} and CO{sub 2} over other gases in QMOF-1. • QMOF-1 shows considerable adsorption capacity for C{sub 2}H{sub 2} and CO{sub 2}. • Selectivity for C{sub 2}H{sub 2}/C{sub 2}H{sub 4}, C{sub 2}H{sub 2}/CH{sub 4}, CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} mixtures were evaluated.

Authors:
 [1];  [2];  [3];  [3]
  1. College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002 (China)
  2. (United States)
  3. Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698 (United States)
Publication Date:
OSTI Identifier:
22742022
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 252; Other Information: Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACETYLENE; CARBON DIOXIDE; ETHYLENE; ONE-DIMENSIONAL CALCULATIONS; ORGANOMETALLIC COMPOUNDS

Citation Formats

Lin, Rong-Guang, Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698, Lin, Rui-Biao, and Chen, Banglin. A microporous metal–organic framework for selective C{sub 2}H{sub 2} and CO{sub 2} separation. United States: N. p., 2017. Web. doi:10.1016/J.JSSC.2017.05.013.
Lin, Rong-Guang, Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698, Lin, Rui-Biao, & Chen, Banglin. A microporous metal–organic framework for selective C{sub 2}H{sub 2} and CO{sub 2} separation. United States. doi:10.1016/J.JSSC.2017.05.013.
Lin, Rong-Guang, Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698, Lin, Rui-Biao, and Chen, Banglin. Tue . "A microporous metal–organic framework for selective C{sub 2}H{sub 2} and CO{sub 2} separation". United States. doi:10.1016/J.JSSC.2017.05.013.
@article{osti_22742022,
title = {A microporous metal–organic framework for selective C{sub 2}H{sub 2} and CO{sub 2} separation},
author = {Lin, Rong-Guang and Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698 and Lin, Rui-Biao and Chen, Banglin},
abstractNote = {A quartzlike metal–organic framework with interesting one dimensional channel has been synthesized. It exhibits considerable acetylene and carbon dioxide uptake of 41.5 and 24.6 cm{sup 3} g{sup −1}, respectively, and relatively high selectivity for separation of C{sub 2}H{sub 2}/C{sub 2}H{sub 4}, C{sub 2}H{sub 2}/CH{sub 4}, CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} at ambient condition. - Graphical abstract: A quartzlike topology metal−organic framework exhibits relatively high selectivity for separation of C{sub 2}H{sub 2}/C{sub 2}H{sub 4}, C{sub 2}H{sub 2}/CH{sub 4}, CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} at ambient condition. Display Omitted - Highlights: • We firstly explored the selective adsorption of C{sub 2}H{sub 2} and CO{sub 2} over other gases in QMOF-1. • QMOF-1 shows considerable adsorption capacity for C{sub 2}H{sub 2} and CO{sub 2}. • Selectivity for C{sub 2}H{sub 2}/C{sub 2}H{sub 4}, C{sub 2}H{sub 2}/CH{sub 4}, CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} mixtures were evaluated.},
doi = {10.1016/J.JSSC.2017.05.013},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 252,
place = {United States},
year = {2017},
month = {8}
}