Preparation of morphology-controlled TiO{sub 2} nanocrystals for the excellent photocatalytic activity under simulated solar irradiation
Journal Article
·
· Materials Research Bulletin
- Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China)
- Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000 (China)
Graphical abstract: Morphology-controlled TiO{sub 2} nanocrystals with excellent photocatalytic activity under simulated solar irradiation were successfully synthesized. - Highlights: • TiO{sub 2} nanocrystals (NCs) with different morphologies were synthesized. • The growth mechanism of morphology-controlled TiO{sub 2} NCs was proposed. • The core-shell structured TiO{sub 2} NCs (co-TiO{sub 2}) had a narrow band gap (2.67 eV). • The co-TiO{sub 2} NCs possessed excellent photocatalytic activity and recyclability. - Abstract: A simple synthetic approach based on solvothermal technique and hydrogenation was developed for preparation of TiO{sub 2} nanocrystals with different morphologies such as elongated rhombic, dog-bone, oval and core-shell structured oval. The effect of oleic acid (OA) and oleylamine (OM) as two capping surfactants on the growth of TiO{sub 2} nanocrystals was investigated. The physicochemical properties of the obtained samples were characterized by various techniques including TEM, XRD, UV–vis absorption, Raman, XPS, BET, PL and photocurrent measurement. In photodegradation of RhB under simulated solar irradiation, the oval-shaped TiO{sub 2} nanocrystals with core-shell structure (co-TiO{sub 2}) was superior to other TiO{sub 2} nanocrystals in catalytic activity. Moreover, the co-TiO{sub 2} nanocrystals exhibited well recyclability during multiple photocatalytic tests. These excellent properties of co-TiO{sub 2} were attributed to its special structure, including lattice-disordered surface layer and well-crystallized lattice core, and narrow band gap (2.67 eV).
- OSTI ID:
- 22730404
- Journal Information:
- Materials Research Bulletin, Journal Name: Materials Research Bulletin Vol. 94; ISSN MRBUAC; ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
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