Synthesis and structure of 15-(1-benzyl-1H-imidazol-5-yl)-9,10-dimethoxy-12,13-dihydro-7aH,15H-naphto[1′,2′:5,6][1,3]oxazino[2,3-a]isoquinoline

Journal Article · Thu Jan 15 04:00:00 EST 2015 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774515010150· OSTI ID:22722875

Ivleva, E. A. ^[1]; Rybakov, V. B. ^[2]; Klimochkin, Yu. N. ^[1]

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1. Samara State Technical University (Russian Federation)
2. Moscow State University, Faculty of Chemistry (Russian Federation)

The synthesis and X-ray diffraction study of 15-(1-benzyl-1H-imidazol-5-yl)-9,10-dimethoxy-12,13-dihydro-7aH,15H-naphto[1′,2′:5,6][1,3]oxazino[2,3-a]isoquinoline C{sub 32}H{sub 29}N{sub 3}O{sub 3} are performed: triclinic crystal system, space group P1̄, a = 7.0319(2) Å, b = 12.2989(6) Å, c = 14.8284(7) Å, α = 84.606(4)°, β = 88.741(3)°, and γ = 86.227(3)°, Z = 2, V = 1273.82(9) Å{sup 3}, ρ{sub calcd} = 1.313 g/cm{sup 3} [T = 100(2) K]. In the molecule, the oxazine ring adopts a half-chair conformation. The positions of two tertiary hydrogen atoms are found, and it is shown that the compound is a trans isomer. The bond lengths and angles in the molecule are standard for this class of compounds.

• OSTI ID: 22722875
• Journal Information: Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 1 Vol. 60; ISSN CYSTE3; ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
BOND LENGTHS
CRYSTALS
HYDROGEN
ISOMERS
MOLECULES
SPACE GROUPS
SYNTHESIS
TRICLINIC LATTICES
X-RAY DIFFRACTION