Effect of chemical product yield uncertainties on reactivities of VOCs and emissions from reformulated gasolines and methanol fuels

Journal Article · Mon Apr 01 04:00:00 EST 1996 · Environmental Science and Technology

DOI:https://doi.org/10.1021/es950707z· OSTI ID:226673

Yang, Y J ^[1]; Stockwell, W R ^[2]; Milford, J B ^[3]

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1. Carnegie Mellon Univ., Pittsburgh, PA (United States)
2. Fraunhofer Inst. of Atmospheric Environmental Research, Garmisch-Partenkirchen (Germany)
3. Univ. of Colorado, Boulder, CO (United States)

To account for differences in exhaust composition that arise with the use of fuels other than conventional gasoline, California regulations apply reactivity adjustment factors (RAFs) to emissions standards for new motor vehicles. The RAFs are based on estimates of the sensitivity of ozone formation to each of the individual organic compounds in the exhaust. In this study, uncertainties have been estimated for the incremental reactivities of individual organic compounds and for RAFs for motor vehicle exhaust, accounting for uncertainties in chemical rate parameters and product yields and for variability in exhaust composition. Uncertainties (1{sigma}) in incremental reactivities of individual compounds range from about 25 to 75% of mean estimates and are typically about 10% higher than previous estimates obtained by considering independent rate parameters as the only source of uncertainty in the chemical mechanism. The incremental reactivities of relatively rapidly reacting compounds are sensitive to the peroxy radical yields in their primary oxidation reactions. RAF values of 0.87{+-}0.11(1{sigma}) and 0.42{+-}0.06, respectively, are calculated for exhaust emissions from a test gasoline with low aromatics and low olefins content, and from an 85% methanol, 15% gasoline blend. The RAF values show little sensitivity to product yield uncertainties. 8 refs., 2 figs., 6 tabs.

• OSTI ID: 226673
• Journal Information: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 4 Vol. 30; ISSN 0013-936X; ISSN ESTHAG
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
09 BIOMASS FUELS
40 CHEMISTRY
54 ENVIRONMENTAL SCIENCES
ABUNDANCE
ACTIVATION ENERGY
AIR POLLUTION CONTROL
CHEMICAL REACTION KINETICS
COMPUTERIZED SIMULATION
EXHAUST GASES
EXPERIMENTAL DATA
GASOHOL
GASOLINE
METHANOL FUELS
ORGANIC COMPOUNDS
OXIDATION
OZONE
PEROXY RADICALS
VOLATILE MATTER