NITROGEN ISOTOPIC RATIO OF COMETARY AMMONIA FROM HIGH-RESOLUTION OPTICAL SPECTROSCOPIC OBSERVATIONS OF C/2014 Q2 (LOVEJOY)
- National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan)
- Koyama Astronomical Observatory, Kyoto Sangyo University, Motoyama, Kamigamo, Kita-Ku, Kyoto 603-8555 (Japan)
The icy materials present in comets provide clues to the origin and evolution of our solar system and planetary systems. High-resolution optical spectroscopic observations of comet C/2014 Q2 (Lovejoy) were performed on 2015 January 11 (at 1.321 au pre-perihelion) with the High Dispersion Spectrograph mounted on the Subaru Telescope on Maunakea, Hawaii. We derive the {sup 14}N/{sup 15}N ratio of NH{sub 2} (126 ± 25), as well as the ortho-to-para abundance ratios (OPRs) of the H{sub 2}O{sup +} ion (2.77 ± 0.24) and NH{sub 2} (3.38 ± 0.07), which correspond to nuclear spin temperatures of >24 K (3 σ lower limit) and 27 ± 2 K, respectively. We also derive the intensity ratio of the green-to-red doublet of forbidden oxygen lines (0.107 ± 0.007). The ammonia in the comet must have formed under low-temperature conditions at ∼10 K or less to reproduce the observed {sup 14}N/{sup 15}N ratio in this molecule if it is assumed that the {sup 15}N-fractionation of ammonia occurred via ion–molecule chemical reactions. However, this temperature is inconsistent with the nuclear spin temperatures of water and ammonia estimated from the OPRs. The interpretation of the nuclear spin temperature as the temperature at molecular formation may therefore be incorrect. An isotope-selective photodissociation of molecular nitrogen by protosolar ultraviolet radiation might play an important role in the {sup 15}N-fractionation observed in cometary volatiles.
- OSTI ID:
- 22662939
- Journal Information:
- Astronomical Journal (Online), Vol. 152, Issue 5; Other Information: Country of input: International Atomic Energy Agency (IAEA); ISSN 1538-3881
- Country of Publication:
- United States
- Language:
- English
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