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Title: Design and construction of diverse structures of coordination polymers: Photocatalytic properties

Abstract

The reaction of Cu(NO{sub 3}){sub 2}·3H{sub 2}O/Ni(NO{sub 3}){sub 2}·6H{sub 2}O with 4′-(4-(3,5-dicarboxylphenoxy)phenyl)-4,2′:6′,4′′-terpyridine (H{sub 2}dbp) gave [Cu{sub 0.5}(Hdbp)]{sub n} (1) and [Ni(dbp)(H{sub 2}O)]{sub n} (2), while the reactions of Co(NO{sub 3}){sub 2}·6H{sub 2}O with H{sub 2}dbp in the presence of 4,4′-bipy and 2,2′-bpy generated [Co(dbp)(4,4′-bipy)]{sub n} (3) and ([Co(dbp)(2,2′-bipy)]{sub n}·H{sub 2}O) (4), respectively (4,4′-bipy=4.4′-pyridine and 2,2′-bipy=2,2′-bipyridine). X-Ray single-crystal analyses reveal that 1 contains a 1D double chain. 2 possesses a 3D architecture with (4.6{sup 2}0.8{sup 3}){sub 2} topology that is interpenetrated with each other to form a 2-fold network. In 3, the 2D [Co(dbp)]n sheets are pillared by 4,4′-bpy to form a 3D framework with 1D open channel. Compound 4 consists of a 1D ladder-like chain. The results showed that the structural diversity of the coordination polymers resulted from the different geometries of metal ions and effect of assistant ligands. Furthermore, the photocatalytic properties of 1–4 for degradation of the methyl violet (MV) have been examined. - Graphical abstract: The photocatalytic activity and selectivity of complexes 1–4 prove that they may be good and stable photocatalysts for degradation of organic dyes.

Authors:
 [1];  [1];  [2]; ;  [1];  [3]
  1. College of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong 643000 (China)
  2. Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000 (China)
  3. School of Pharmacy, Guangdong Medical University, Dongguan 523808 (China)
Publication Date:
OSTI Identifier:
22658158
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 245; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; COBALT COMPOUNDS; DBP; EXPERIMENTAL DATA; METHYL VIOLET; MONOCRYSTALS; NITRATES; PHOTOCATALYSIS; POLYMERS

Citation Formats

Wu, Yu, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, Lu, Lu, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, Feng, Jianshen, Li, Yulong, Sun, Yanchun, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, and Ma, Aiqing. Design and construction of diverse structures of coordination polymers: Photocatalytic properties. United States: N. p., 2017. Web. doi:10.1016/J.JSSC.2016.10.021.
Wu, Yu, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, Lu, Lu, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, Feng, Jianshen, Li, Yulong, Sun, Yanchun, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, & Ma, Aiqing. Design and construction of diverse structures of coordination polymers: Photocatalytic properties. United States. doi:10.1016/J.JSSC.2016.10.021.
Wu, Yu, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, Lu, Lu, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, Feng, Jianshen, Li, Yulong, Sun, Yanchun, Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, and Ma, Aiqing. Sun . "Design and construction of diverse structures of coordination polymers: Photocatalytic properties". United States. doi:10.1016/J.JSSC.2016.10.021.
@article{osti_22658158,
title = {Design and construction of diverse structures of coordination polymers: Photocatalytic properties},
author = {Wu, Yu and Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000 and Lu, Lu and Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000 and Feng, Jianshen and Li, Yulong and Sun, Yanchun and Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000 and Ma, Aiqing},
abstractNote = {The reaction of Cu(NO{sub 3}){sub 2}·3H{sub 2}O/Ni(NO{sub 3}){sub 2}·6H{sub 2}O with 4′-(4-(3,5-dicarboxylphenoxy)phenyl)-4,2′:6′,4′′-terpyridine (H{sub 2}dbp) gave [Cu{sub 0.5}(Hdbp)]{sub n} (1) and [Ni(dbp)(H{sub 2}O)]{sub n} (2), while the reactions of Co(NO{sub 3}){sub 2}·6H{sub 2}O with H{sub 2}dbp in the presence of 4,4′-bipy and 2,2′-bpy generated [Co(dbp)(4,4′-bipy)]{sub n} (3) and ([Co(dbp)(2,2′-bipy)]{sub n}·H{sub 2}O) (4), respectively (4,4′-bipy=4.4′-pyridine and 2,2′-bipy=2,2′-bipyridine). X-Ray single-crystal analyses reveal that 1 contains a 1D double chain. 2 possesses a 3D architecture with (4.6{sup 2}0.8{sup 3}){sub 2} topology that is interpenetrated with each other to form a 2-fold network. In 3, the 2D [Co(dbp)]n sheets are pillared by 4,4′-bpy to form a 3D framework with 1D open channel. Compound 4 consists of a 1D ladder-like chain. The results showed that the structural diversity of the coordination polymers resulted from the different geometries of metal ions and effect of assistant ligands. Furthermore, the photocatalytic properties of 1–4 for degradation of the methyl violet (MV) have been examined. - Graphical abstract: The photocatalytic activity and selectivity of complexes 1–4 prove that they may be good and stable photocatalysts for degradation of organic dyes.},
doi = {10.1016/J.JSSC.2016.10.021},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 245,
place = {United States},
year = {2017},
month = {1}
}