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Title: Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine

Abstract

Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [((2,4- (CH{sub 3}){sub 2}C{sub 6}H{sub 3}O)2PS2)2Fe(NC{sub 5}H{sub 4}(C{sub 2}H{sub 5})-4){sub 2}] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P2{sub 1}/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.

Authors:
; ;  [1]; ;  [2];  [1]
  1. University of Jammu, Department of Chemistry (India)
  2. Department of Physics and Electronics, University of Jammu, X-ray Crystallographic Laboratory (India)
Publication Date:
OSTI Identifier:
22645393
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 61; Journal Issue: 5; Other Information: Copyright (c) 2016 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ATOMS; CHELATES; INFRARED SPECTRA; IRON; LIGANDS; MAGNETIC MOMENTS; MONOCLINIC LATTICES; MONOCRYSTALS; SYNTHESIS; X RADIATION

Citation Formats

Kumar, Sandeep, Andotra, Savit, Kaur, Mandeep, Gupta, Vivek K., Kant, Rajni, and Pandey, Sushil K., E-mail: kpsushil@rediffmail.com. Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine. United States: N. p., 2016. Web. doi:10.1134/S1063774516050126.
Kumar, Sandeep, Andotra, Savit, Kaur, Mandeep, Gupta, Vivek K., Kant, Rajni, & Pandey, Sushil K., E-mail: kpsushil@rediffmail.com. Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine. United States. doi:10.1134/S1063774516050126.
Kumar, Sandeep, Andotra, Savit, Kaur, Mandeep, Gupta, Vivek K., Kant, Rajni, and Pandey, Sushil K., E-mail: kpsushil@rediffmail.com. Thu . "Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine". United States. doi:10.1134/S1063774516050126.
@article{osti_22645393,
title = {Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine},
author = {Kumar, Sandeep and Andotra, Savit and Kaur, Mandeep and Gupta, Vivek K. and Kant, Rajni and Pandey, Sushil K., E-mail: kpsushil@rediffmail.com},
abstractNote = {Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [((2,4- (CH{sub 3}){sub 2}C{sub 6}H{sub 3}O)2PS2)2Fe(NC{sub 5}H{sub 4}(C{sub 2}H{sub 5})-4){sub 2}] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P2{sub 1}/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.},
doi = {10.1134/S1063774516050126},
journal = {Crystallography Reports},
number = 5,
volume = 61,
place = {United States},
year = {Thu Sep 15 00:00:00 EDT 2016},
month = {Thu Sep 15 00:00:00 EDT 2016}
}