A one-dimensional stochastic approach to the study of cyclic voltammetry with adsorption effects
- The Department of Mechanical and Aerospace Engineering, The Ohio State University, 201 W 19"t"h Avenue, Columbus, Ohio 43210 (United States)
In this study, a one-dimensional stochastic model based on the random walk approach is used to simulate cyclic voltammetry. The model takes into account mass transport, kinetics of the redox reactions, adsorption effects and changes in the morphology of the electrode. The model is shown to display the expected behavior. Furthermore, the model shows consistent qualitative agreement with a finite difference solution. This approach allows for an understanding of phenomena on a microscopic level and may be useful for analyzing qualitative features observed in experimentally recorded signals.
- OSTI ID:
- 22611700
- Journal Information:
- AIP Advances, Vol. 6, Issue 5; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 2158-3226
- Country of Publication:
- United States
- Language:
- English
Similar Records
The effects of surface energetics and surface oxide layers on the cyclic voltammetry of metallocenes at nonilluminated p-InP electrodes
Cyclic voltammetry of aquocobalamin on clay-modified electrodes
Part I. Carbon and mercury-carbon optically transparent electrodes. Part II. Investigation of redox properties of technetium by cyclic voltammetry and thin layer spectroelectrochemistry
Journal Article
·
Fri Mar 01 00:00:00 EST 1985
· J. Electrochem. Soc.; (United States)
·
OSTI ID:22611700
+1 more
Cyclic voltammetry of aquocobalamin on clay-modified electrodes
Journal Article
·
Wed Jul 15 00:00:00 EDT 1998
· Environmental Science and Technology
·
OSTI ID:22611700
Part I. Carbon and mercury-carbon optically transparent electrodes. Part II. Investigation of redox properties of technetium by cyclic voltammetry and thin layer spectroelectrochemistry
Thesis/Dissertation
·
Tue Jan 01 00:00:00 EST 1980
·
OSTI ID:22611700