Studies on electronic spectral parameters of doped Nd(III) ion with therapeutically important ligands in dioxane solvent

Journal Article · Fri May 06 00:00:00 EDT 2016 · AIP Conference Proceedings

DOI:https://doi.org/10.1063/1.4946657· OSTI ID:22606630

Bajaj, Annu ^[1]; Jain, Sushma ^[2]

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1. Department of Chemistry, Marudhar Engineering College, Bikaner, Raj. 334001 India (India)
2. Department of Chemistry, Govt. Dungar College, Bikaner, Raj. 334001 India (India)

The present investigation is concerened with the studies on electronic spectral parameters viz. Oscillator strength (P), Judd-Ofelt T{sub λ} (λ=2,4,6), Slater-Condon(F{sub K}),Lande(ζ{sub 4F}),Nephelauxetic ratio(β), Bonding parameter (b{sup 1/2}) and Percent covalency parameter (δ%) for Nd(III) ion complexes with the ligands having Nitrogen,Oxygen Sulphur donor sites.The variation in the values of oscillator strength explicitly shows the relative sensitivities of the 4f-4f transition as well as the specific correlation between ligand structures and nature of Nd(III) ligand interaction.

• OSTI ID: 22606630
• Journal Information: AIP Conference Proceedings, Vol. 1728, Issue 1; Conference: ICC 2015: International conference on condensed matter and applied physics, Bikaner (India), 30-31 Oct 2015; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
BONDING
CORRELATIONS
COVALENCE
DIOXANE
DOPED MATERIALS
ENERGY-LEVEL TRANSITIONS
INTERACTIONS
IONS
LIGANDS
NEODYMIUM ADDITIONS
NITROGEN
OSCILLATOR STRENGTHS
OSCILLATORS
OXYGEN
SENSITIVITY
VARIATIONS