Spectroscopic studies of biologically active coumarin laser dye: Evaluation of dipole moments by solvatochromic shift method
Journal Article
·
· AIP Conference Proceedings
In this paper we attempted to record absorption and emission spectra of 2-acetyl-3H-benzo[f]chromen-3-one [2AHBC] laser dye in different solvents of varying polarities to investigate its solvatochromic behavior. The two electronic states dipole moments of 2AHBC are calculated using solvatochromic spectral shifts which are correlated with dielectric constant (ε) refractive index (n) of various solvents. A systematic approach is made to estimate ground and excited state dipole moments on the basis of different solvent correlation methods like Bilot-Kawski equations, Lippert-Mataga, Bakhsheiv, Kawaski-Chamma-Viallet and Reichardt methods. Dipole moments in the excited state was found to be higher than the ground state by confirming π→π* transition.
- OSTI ID:
- 22606496
- Journal Information:
- AIP Conference Proceedings, Journal Name: AIP Conference Proceedings Journal Issue: 1 Vol. 1728; ISSN APCPCS; ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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