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Dislocation structures and electrical conduction properties of low angle tilt grain boundaries in LiNbO{sub 3}

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4961706· OSTI ID:22597635
; ;  [1];  [2];  [2];  [1]
  1. Department of Materials Science and Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)
  2. Institute of Engineering Innovation, The University of Tokyo, 2-11-16, Yayoi, Bunkyo-ku, Tokyo 113-8656 (Japan)

Dislocations in crystalline materials constitute unique, atomic-scale, one-dimensional structure and have a potential to induce peculiar physical properties that are not found in the bulk. In this study, we fabricated LiNbO{sub 3} bicrystals with low angle tilt grain boundaries and investigated the relationship between the atomic structure of the boundary dislocations and their electrical conduction properties. Observations by using transmission electron microscopy revealed that dislocation structures at the (0001) low angle tilt grain boundaries depend on the tilt angle of the boundaries. Specifically, the characteristic dislocation structures with a large Burgers vector were formed in the boundary with the tilt angle of 2°. It is noteworthy that only the grain boundary of 2° exhibits distinct electrical conductivity after reduction treatment, although LiNbO{sub 3} is originally insulating. This unique electrical conductivity is suggested to be due to the characteristic dislocation structures with a large Burgers vector.

OSTI ID:
22597635
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 14 Vol. 120; ISSN JAPIAU; ISSN 0021-8979
Country of Publication:
United States
Language:
English